Isobar (nuclide)

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In this chart of nuclides, isobars occur along diagonal lines running from the lower right to upper left. The line of beta stability includes the observationally stable nuclides shown in black; disconnected 'islands' are a consequence of the Mattauch isobar rule. NuclideMap stitched small preview.png
In this chart of nuclides, isobars occur along diagonal lines running from the lower right to upper left. The line of beta stability includes the observationally stable nuclides shown in black; disconnected 'islands' are a consequence of the Mattauch isobar rule.

Isobars are atoms (nuclides) of different chemical elements that have the same number of nucleons. Correspondingly, isobars differ in atomic number (or number of protons) but have the same mass number. An example of a series of isobars is 40S, 40Cl, 40Ar, 40K, and 40Ca. While the nuclei of these nuclides all contain 40 nucleons, they contain varying numbers of protons and neutrons. [1]

Contents

The term "isobars" (originally "isobares") for nuclides was suggested by Alfred Walter Stewart in 1918. [2] It is derived from the Greek word isos, meaning "equal" and baros, meaning "weight". [3]

Mass

The same mass number implies neither the same mass of nuclei, nor equal atomic masses of corresponding nuclides. From the Weizsäcker formula for the mass of a nucleus:

where mass number A equals to the sum of atomic number Z and number of neutrons N, and mp, mn, aV, aS, aC, aA are constants, one can see that the mass depends on Z and N non-linearly, even for a constant mass number. For odd  A, it is admitted that δ = 0 and the mass dependence on Z is convex (or on N or NZ, it does not matter for a constant A). This explains that beta decay is energetically favorable for neutron-rich nuclides, and positron decay is favorable for strongly neutron-deficient nuclides. Both decay modes do not change the mass number, hence an original nucleus and its daughter nucleus are isobars. In both aforementioned cases, a heavier nucleus decays to its lighter isobar.

For even  A the δ term has the form:

where aP is another constant. This term, subtracted from the mass expression above, is positive for even-even nuclei and negative for odd-odd nuclei. This means that even-even nuclei, which do not have a strong neutron excess or neutron deficiency, have higher binding energy than their odd-odd isobar neighbors. It implies that even-even nuclei are (relatively) lighter and more stable. The difference is especially strong for small A. This effect is also predicted (qualitatively) by other nuclear models and has important consequences.

Stability

The Mattauch isobar rule states that if two adjacent elements on the periodic table have isotopes of the same mass number, at least one of these isobars must be a radionuclide (radioactive). In cases of three isobars of sequential elements where the first and last are stable (this is often the case for even-even nuclides, see above), branched decay of the middle isobar may occur. For instance, radioactive iodine-126 has almost equal probabilities for two decay modes: positron emission, leading to tellurium-126, and beta emission, leading to xenon-126.

No observationally stable isobars exist for mass numbers 5 (decays to helium-4 plus a proton or neutron), 8 (decays to two helium-4 nuclei), 147, 151, as well as for 209 and above. Two observationally stable isobars exist for 36, 40, 46, 50, 54, 58, 64, 70, 74, 80, 84, 86, 92, 94, 96, 98, 102, 104, 106, 108, 110, 112, 114, 120, 122, 123, 124, 126, 132, 134, 136, 138, 142, 154, 156, 158, 160, 162, 164, 168, 170, 176, 180 (including a meta state), 192, 196, 198 and 204. [4]

In theory, no two stable nuclides have the same mass number (since no two nuclides that have the same mass number are both stable to beta decay and double beta decay), and no stable nuclides exist for mass numbers 5, 8, 143–155, 160–162, and ≥ 165, since in theory, the beta-decay stable nuclides for these mass numbers can undergo alpha decay.

See also

Bibliography

Sprawls, Perry (1993). "5 – Characteristics and Structure of Matter". Physical Principles of Medical Imaging (2 ed.). Madison, WI: Medical Physics Publishing. ISBN   0-8342-0309-X . Retrieved 28 April 2010.

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<span class="mw-page-title-main">Stable nuclide</span> Nuclide that does not undergo radioactive decay

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<span class="mw-page-title-main">Island of stability</span> Predicted set of isotopes of relatively more stable superheavy elements

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<span class="mw-page-title-main">Nuclide</span> Atomic species

A nuclide is a class of atoms characterized by their number of protons, Z, their number of neutrons, N, and their nuclear energy state.

In nuclear engineering, fissile material is material that can undergo nuclear fission when struck by a neutron of low energy. A self-sustaining thermal chain reaction can only be achieved with fissile material. The predominant neutron energy in a system may be typified by either slow neutrons or fast neutrons. Fissile material can be used to fuel thermal-neutron reactors, fast-neutron reactors and nuclear explosives.

<span class="mw-page-title-main">Magic number (physics)</span> Number of protons or neutrons that make a nucleus particularly stable

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<span class="mw-page-title-main">Mass number</span> Number of heavy particles in the atomic nucleus

The mass number (symbol A, from the German word: Atomgewicht, "atomic weight"), also called atomic mass number or nucleon number, is the total number of protons and neutrons (together known as nucleons) in an atomic nucleus. It is approximately equal to the atomic (also known as isotopic) mass of the atom expressed in atomic mass units. Since protons and neutrons are both baryons, the mass number A is identical with the baryon number B of the nucleus (and also of the whole atom or ion). The mass number is different for each isotope of a given chemical element, and the difference between the mass number and the atomic number Z gives the number of neutrons (N) in the nucleus: N = AZ.

<span class="mw-page-title-main">Isotone</span>

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<span class="mw-page-title-main">Semi-empirical mass formula</span> Formula to approximate nuclear mass based on nucleon counts

In nuclear physics, the semi-empirical mass formula (SEMF) is used to approximate the mass of an atomic nucleus from its number of protons and neutrons. As the name suggests, it is based partly on theory and partly on empirical measurements. The formula represents the liquid-drop model proposed by George Gamow, which can account for most of the terms in the formula and gives rough estimates for the values of the coefficients. It was first formulated in 1935 by German physicist Carl Friedrich von Weizsäcker, and although refinements have been made to the coefficients over the years, the structure of the formula remains the same today.

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<span class="mw-page-title-main">Nuclear binding energy</span> Minimum energy required to separate particles within a nucleus

Nuclear binding energy in experimental physics is the minimum energy that is required to disassemble the nucleus of an atom into its constituent protons and neutrons, known collectively as nucleons. The binding energy for stable nuclei is always a positive number, as the nucleus must gain energy for the nucleons to move apart from each other. Nucleons are attracted to each other by the strong nuclear force. In theoretical nuclear physics, the nuclear binding energy is considered a negative number. In this context it represents the energy of the nucleus relative to the energy of the constituent nucleons when they are infinitely far apart. Both the experimental and theoretical views are equivalent, with slightly different emphasis on what the binding energy means.

<span class="mw-page-title-main">Table of nuclides</span> Graph of neutrons vs. protons in nuclides

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<span class="mw-page-title-main">Valley of stability</span> Characterization of nuclide stability

In nuclear physics, the valley of stability is a characterization of the stability of nuclides to radioactivity based on their binding energy. Nuclides are composed of protons and neutrons. The shape of the valley refers to the profile of binding energy as a function of the numbers of neutrons and protons, with the lowest part of the valley corresponding to the region of most stable nuclei. The line of stable nuclides down the center of the valley of stability is known as the line of beta stability. The sides of the valley correspond to increasing instability to beta decay. The decay of a nuclide becomes more energetically favorable the further it is from the line of beta stability. The boundaries of the valley correspond to the nuclear drip lines, where nuclides become so unstable they emit single protons or single neutrons. Regions of instability within the valley at high atomic number also include radioactive decay by alpha radiation or spontaneous fission. The shape of the valley is roughly an elongated paraboloid corresponding to the nuclide binding energies as a function of neutron and atomic numbers.

<span class="mw-page-title-main">Neutron number</span> The number of neutrons in a nuclide

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Isotopes are distinct nuclear species of the same chemical element. They have the same atomic number and position in the periodic table, but differ in nucleon numbers due to different numbers of neutrons in their nuclei. While all isotopes of a given element have almost the same chemical properties, they have different atomic masses and physical properties.

<span class="mw-page-title-main">Atomic nucleus</span> Core of an atom; composed of nucleons (protons and neutrons)

The atomic nucleus is the small, dense region consisting of protons and neutrons at the center of an atom, discovered in 1911 by Ernest Rutherford based on the 1909 Geiger–Marsden gold foil experiment. After the discovery of the neutron in 1932, models for a nucleus composed of protons and neutrons were quickly developed by Dmitri Ivanenko and Werner Heisenberg. An atom is composed of a positively charged nucleus, with a cloud of negatively charged electrons surrounding it, bound together by electrostatic force. Almost all of the mass of an atom is located in the nucleus, with a very small contribution from the electron cloud. Protons and neutrons are bound together to form a nucleus by the nuclear force.

<span class="mw-page-title-main">Beta-decay stable isobars</span> Set of nuclides that cannot undergo beta decay

Beta-decay stable isobars are the set of nuclides which cannot undergo beta decay, that is, the transformation of a neutron to a proton or a proton to a neutron within the nucleus. A subset of these nuclides are also stable with regards to double beta decay or theoretically higher simultaneous beta decay, as they have the lowest energy of all nuclides with the same mass number.

<span class="mw-page-title-main">Nuclear drip line</span> Atomic nuclei decay delimiter

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<span class="mw-page-title-main">Even and odd atomic nuclei</span> Nuclear physics classification method

In nuclear physics, properties of a nucleus depend on evenness or oddness of its atomic number Z, neutron number N and, consequently, of their sum, the mass number A. Most importantly, oddness of both Z and N tends to lower the nuclear binding energy, making odd nuclei generally less stable. This effect is not only experimentally observed, but is included in the semi-empirical mass formula and explained by some other nuclear models, such as the nuclear shell model. This difference of nuclear binding energy between neighbouring nuclei, especially of odd-A isobars, has important consequences for beta decay.

<span class="mw-page-title-main">Neutron–proton ratio</span>

The neutron–proton ratio of an atomic nucleus is the ratio of its number of neutrons to its number of protons. Among stable nuclei and naturally occurring nuclei, this ratio generally increases with increasing atomic number. This is because electrical repulsive forces between protons scale with distance differently than strong nuclear force attractions. In particular, most pairs of protons in large nuclei are not far enough apart, such that electrical repulsion dominates over the strong nuclear force, and thus proton density in stable larger nuclei must be lower than in stable smaller nuclei where more pairs of protons have appreciable short-range nuclear force attractions.

References

  1. Sprawls (1993)
  2. Brucer, Marshall (June 1978). "Nuclear Medicine Begins with a Boa Constrictor" (PDF). History. Journal of Nuclear Medicine . 19 (6): 581–598. ISSN   0161-5505. PMID   351151.
  3. Etymology Online
  4. via stable isotope; observationally stable; primordial radionuclide (some of whose radioactivity was discovered within the last two decades)