Photofission

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Photofission is a process in which a nucleus, after absorbing a gamma ray, undergoes nuclear fission and splits into two or more fragments.

The reaction was discovered in 1940 by a small team of engineers and scientists operating the Westinghouse Atom Smasher at the company's Research Laboratories in Forest Hills, Pennsylvania. [1] They used a 5 MeV proton beam to bombard fluorine and generate high-energy photons, which then irradiated samples of uranium and thorium. [2]

Gamma radiation of modest energies, in the low tens of MeV, can induce fission in traditionally fissile elements such as the actinides thorium, uranium, [3] plutonium, and neptunium. [4] Experiments have been conducted with much higher energy gamma rays, finding that the photofission cross section varies little within ranges in the low GeV range. [5]

Baldwin et al made measurements of the yields of photo-fission in uranium and thorium together with a search for photo-fission in other heavy elements, using continuous x-rays from a 100-Mev betatron. Fission was detected in the presence of an intense background of x-rays by a differential ionization chamber and linear amplifier, the substance investigated being coated on an electrode of one chamber. They deduced the maximum cross section being of the order of 5×10−26 cm2 for uranium and half that for thorium. In the other elements studied, the cross section must be below 10−29 cm2. [6]

Photodisintegration

Photodisintegration (also called phototransmutation) is a similar but different physical process, in which an extremely high energy gamma ray interacts with an atomic nucleus and causes it to enter an excited state, which immediately decays by emitting a subatomic particle.

Related Research Articles

The actinide or actinoid series encompasses the 15 metallic chemical elements with atomic numbers from 89 to 103, actinium through lawrencium. The actinide series derives its name from the first element in the series, actinium. The informal chemical symbol An is used in general discussions of actinide chemistry to refer to any actinide.

<span class="mw-page-title-main">Einsteinium</span> Chemical element, symbol Es and atomic number 99

Einsteinium is a synthetic element with the symbol Es and atomic number 99. Einsteinium is a member of the actinide series and it is the seventh transuranium element. It was named in honor of Albert Einstein.

<span class="mw-page-title-main">Neutron</span> Subatomic particle with no charge

The neutron is a subatomic particle, symbol
n
or
n0
, which has a neutral charge, and a mass slightly greater than that of a proton. Protons and neutrons constitute the nuclei of atoms. Since protons and neutrons behave similarly within the nucleus, and each has a mass of approximately one atomic mass unit, they are both referred to as nucleons. Their properties and interactions are described by nuclear physics. Protons and neutrons are not elementary particles; each is composed of three quarks.

<span class="mw-page-title-main">Nuclear fission</span> Nuclear reaction splitting an atom into multiple parts

Nuclear fission is a reaction in which the nucleus of an atom splits into two or more smaller nuclei. The fission process often produces gamma photons, and releases a very large amount of energy even by the energetic standards of radioactive decay.

<span class="mw-page-title-main">Protactinium</span> Chemical element, symbol Pa and atomic number 91

Protactinium is a chemical element with the symbol Pa and atomic number 91. It is a dense, silvery-gray actinide metal which readily reacts with oxygen, water vapor and inorganic acids. It forms various chemical compounds in which protactinium is usually present in the oxidation state +5, but it can also assume +4 and even +3 or +2 states. Concentrations of protactinium in the Earth's crust are typically a few parts per trillion, but may reach up to a few parts per million in some uraninite ore deposits. Because of its scarcity, high radioactivity and high toxicity, there are currently no uses for protactinium outside scientific research, and for this purpose, protactinium is mostly extracted from spent nuclear fuel.

<span class="mw-page-title-main">Thorium</span> Chemical element, symbol Th and atomic number 90

Thorium is a weakly radioactive metallic chemical element with the symbol Th and atomic number 90. Thorium is silvery and tarnishes black when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high melting point. Thorium is an electropositive actinide whose chemistry is dominated by the +4 oxidation state; it is quite reactive and can ignite in air when finely divided.

<span class="mw-page-title-main">Nuclear isomer</span> Metastable excited state of a nuclide

A nuclear isomer is a metastable state of an atomic nucleus, in which one or more nucleons (protons or neutrons) occupy higher energy levels than in the ground state of the same nucleus. "Metastable" describes nuclei whose excited states have half-lives 100 to 1000 times longer than the half-lives of the excited nuclear states that decay with a "prompt" half life (ordinarily on the order of 10−12 seconds). The term "metastable" is usually restricted to isomers with half-lives of 10−9 seconds or longer. Some references recommend 5 × 10−9 seconds to distinguish the metastable half life from the normal "prompt" gamma-emission half-life. Occasionally the half-lives are far longer than this and can last minutes, hours, or years. For example, the 180m
73
Ta
nuclear isomer survives so long (at least 1015 years) that it has never been observed to decay spontaneously. The half-life of a nuclear isomer can even exceed that of the ground state of the same nuclide, as shown by 180m
73
Ta
as well as 192m2
77
Ir
, 210m
83
Bi
, 242m
95
Am
and multiple holmium isomers.

<span class="mw-page-title-main">Spontaneous fission</span> Form of radioactive decay that occurs randomly

Spontaneous fission (SF) is a form of radioactive decay that is found only in very heavy chemical elements. The nuclear binding energy of the elements reaches its maximum at an atomic mass number of about 56 ; spontaneous breakdown into smaller nuclei and a few isolated nuclear particles becomes possible at greater atomic mass numbers.

Unbibium, also known as element 122 or eka-thorium, is the hypothetical chemical element in the periodic table with the placeholder symbol of Ubb and atomic number 122. Unbibium and Ubb are the temporary systematic IUPAC name and symbol respectively, which are used until the element is discovered, confirmed, and a permanent name is decided upon. In the periodic table of the elements, it is expected to follow unbiunium as the second element of the superactinides and the fourth element of the 8th period. Similarly to unbiunium, it is expected to fall within the range of the island of stability, potentially conferring additional stability on some isotopes, especially 306Ubb which is expected to have a magic number of neutrons (184).

Uranium (92U) is a naturally occurring radioactive element that has no stable isotope. It has two primordial isotopes, uranium-238 and uranium-235, that have long half-lives and are found in appreciable quantity in the Earth's crust. The decay product uranium-234 is also found. Other isotopes such as uranium-233 have been produced in breeder reactors. In addition to isotopes found in nature or nuclear reactors, many isotopes with far shorter half-lives have been produced, ranging from 214U to 242U. The standard atomic weight of natural uranium is 238.02891(3).

Protactinium (91Pa) has no stable isotopes. The four naturally occurring isotopes allow a standard atomic weight to be given.

Thorium (90Th) has seven naturally occurring isotopes but none are stable. One isotope, 232Th, is relatively stable, with a half-life of 1.405×1010 years, considerably longer than the age of the Earth, and even slightly longer than the generally accepted age of the universe. This isotope makes up nearly all natural thorium, so thorium was considered to be mononuclidic. However, in 2013, IUPAC reclassified thorium as binuclidic, due to large amounts of 230Th in deep seawater. Thorium has a characteristic terrestrial isotopic composition and thus a standard atomic weight can be given.

<span class="mw-page-title-main">Thorium fuel cycle</span> Nuclear fuel cycle

The thorium fuel cycle is a nuclear fuel cycle that uses an isotope of thorium, 232
Th
, as the fertile material. In the reactor, 232
Th
is transmuted into the fissile artificial uranium isotope 233
U
which is the nuclear fuel. Unlike natural uranium, natural thorium contains only trace amounts of fissile material, which are insufficient to initiate a nuclear chain reaction. Additional fissile material or another neutron source is necessary to initiate the fuel cycle. In a thorium-fuelled reactor, 232
Th
absorbs neutrons to produce 233
U
. This parallels the process in uranium breeder reactors whereby fertile 238
U
absorbs neutrons to form fissile 239
Pu
. Depending on the design of the reactor and fuel cycle, the generated 233
U
either fissions in situ or is chemically separated from the used nuclear fuel and formed into new nuclear fuel.

Francis Goddard Slack was an American physicist. He was a physics teacher, researcher, and administrator in academia who was renowned for placing equal emphasis on teaching and on research.

G. Norris Glasoe was an American nuclear physicist. He was a member of the Columbia University team which was the first in the United States to verify the European discovery of the nuclear fission of uranium via neutron bombardment. During World War II, he worked at the MIT Radiation Laboratory. He was a physicist and administrator at the Brookhaven National Laboratory.

Giant resonance is a high-frequency collective excitation of atomic nuclei, as a property of many-body quantum systems. In the macroscopic interpretation of such an excitation in terms of an oscillation, the most prominent giant resonance is a collective oscillation of all protons against all neutrons in a nucleus.

<span class="mw-page-title-main">Nucleon pair breaking in fission</span>

Nucleon pair breaking in fission has been an important topic in nuclear physics for decades. "Nucleon pair" refers to nucleon pairing effects which strongly influence the nuclear properties of a nuclide.

<span class="mw-page-title-main">Nuclear transmutation</span> Conversion of an atom from one element to another

Nuclear transmutation is the conversion of one chemical element or an isotope into another chemical element. Nuclear transmutation occurs in any process where the number of protons or neutrons in the nucleus of an atom is changed.

<span class="mw-page-title-main">Westinghouse Atom Smasher</span> Building in Forest Hills, Pennsylvania

The Westinghouse Atom Smasher was a 5 million volt Van de Graaff electrostatic nuclear accelerator operated by the Westinghouse Electric Corporation at their Research Laboratories in Forest Hills, Pennsylvania. It was instrumental in the development in practical applications of nuclear science for energy production. In particular, it was used in 1940 to discover the photofission of uranium and thorium, and was most cited for certain nuclear physics measurements. The Westinghouse Atom Smasher was able to make precise measurements of nuclear reactions for the research in nuclear power. It was the first industrial Van de Graaff generator in the world, and marked the beginning of nuclear research for civilian applications. Built in 1937, it was a 65-foot-tall (20 m) pear-shaped tower. It went dormant in 1958. In 1985, it was named an Electrical Engineering Milestone by the Institute of Electrical and Electronics Engineers.

George Curriden Baldwin was an American theoretical and experimental physicist. He was a professor of nuclear engineering at Rensselaer Polytechnic Institute and a scientist working at the General Electric Research Laboratory and at the Los Alamos National Laboratory. He wrote a book on Nonlinear Optics and authored or co-authored over 130 technical papers.

References

  1. Walter, Marni Blake (2015-09-01). "An Unlikely Atomic Landscape: Forest Hills and the Westinghouse Atom Smasher". Western Pennsylvania History Magazine. Senator John Heinz History Center. 98 (3): 36–49. Retrieved 2019-12-03.
  2. Haxby, R.O.; Shoupp, W.E.; Stephens, W.E.; Wells, W.H. (1941-01-01). "Photo-Fission of Uranium and Thorium". Physical Review. 59 (1): 57–62. Bibcode:1941PhRv...59...57H. doi:10.1103/PhysRev.59.57.
  3. Silano, J.A.; Karwowski, H.J. (2018-11-19). "Near-barrier Photofission in 232Th and 238U". Physical Review C. 98 (5): 054609. arXiv: 1807.03900 . Bibcode:2018PhRvC..98e4609S. doi: 10.1103/PhysRevC.98.054609 .
  4. Doré, D; David, J-C; Giacri, M-L; Laborie, J-M; Ledoux, X; Petit, M; Ridikas, D; Lauwe, A Van (2006-05-01). "Delayed neutron yields and spectra from photofission of actinides with bremsstrahlung photons below 20 MeV". Journal of Physics: Conference Series. IOP Publishing. 41 (1): 241–247. Bibcode:2006JPhCS..41..241D. doi: 10.1088/1742-6596/41/1/025 . ISSN   1742-6588.
  5. Cetina, C.; Berman, B. L.; Briscoe, W. J.; Cole, P. L.; Feldman, G.; et al. (2000-06-19). "Photofission of Heavy Nuclei at Energies up to 4 GeV". Physical Review Letters. 84 (25): 5740–5743. arXiv: nucl-ex/0004004 . Bibcode:2000PhRvL..84.5740C. doi:10.1103/physrevlett.84.5740. ISSN   0031-9007. PMID   10991043. S2CID   206326581.
  6. Baldwin, G. C.; Klaiber, G. S. (1947-01-01). "Photo-Fission in Heavy Elements". Physical Review. American Physical Society (APS). 71 (1): 3–10. Bibcode:1947PhRv...71....3B. doi:10.1103/physrev.71.3. ISSN   0031-899X.