Keiko Hattori | |
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Occupation(s) | Geochemist, mineralogist and academic |
Academic background | |
Education | BSc., Geology (1972) MSc., Geology (1974) PhD., Geochemistry (1977) |
Alma mater | University of Tokyo |
Academic work | |
Institutions | University of Ottawa,Canada |
Keiko Hattori is a geochemist and mineralogist. She is Distinguished University Professor of Geochemistry and Mineral Deposits in the Department of Earth and Environmental Sciences at the University of Ottawa. [1]
Hattori is most known for her research on aspects of Earth's atmospheric and mantle evolution,as well as the formation of arc volcanoes and the generation of metal-fertile volcanic arcs. Her application of this knowledge has led to insights regarding the origins and locations of mineral deposits. Specifically,she has conducted research on the transfer of chalcophile elements (copper-like elements) from slabs to arc magmas through mantle wedges,as well as from arc magmas to mineral deposits. Additionally,her work has encompassed exploration geochemistry,where she has investigated the dispersion of metals from buried deposits including platinum and palladium in surface media. She was appointed as the 2022 International Exchange Lecturer of the Society of Economic Geologists (SEG), [2] and has been the recipient of the Island Arc Award and the Takeo Kato Gold Medal. [3]
Hattori is an elected Fellow of the Royal Society of Canada [4] and Mineralogical Society of America. [5]
Hattori was the first female undergraduate student in the Geology Department at the University of Tokyo,which was established in 1877. She completed her master's and PhD in isotope geochemistry there. [6]
Hattori began her academic career as a postdoctoral researcher at the University of Alberta in Edmonton in 1977 and participated in the International Drilling project as a Canadian delegate to study volcanic rocks and thermal alteration in Iceland. [7] In 1980,she moved to the University of Calgary as a Research Associate jointly affiliated with the Department of Physics and the Department of Geology and Geophysics. Three years later,she joined the University of Ottawa as an Assistant Professor and was promoted to Associate Professor in the Department of Geology in 1987. [6]
She was the first female Professor in earth science departments within the national capital region as well as the first female Professor of mineral deposits in Canada. In 1994 she became Full Professor in the Department of Earth and Environmental Sciences at the University of Ottawa. [8] She was awarded the title of Distinguished University Professor in 2023 for her contributions to scientific research and education. [9]
Hattori has held numerous administrative appointments throughout her career. From July 1991 to June 1994,she served as the Director of the Ottawa-Carleton Geoscience Centre. [10] In 2004,she was appointed as the department chair for Earth Sciences at the University of Ottawa,a position she held for four years. [11]
Apart from the administrative work related to universities,she has been engaged in the activities of several scientific organizations including Mineralogical Society of America, [12] Society of Economic Geologists, [13] and Royal Society of Canada. She is Director of Earth,Ocean and Atmosphere Science Division of Royal Society of Canada (2021-2024). [14]
Hattori was an appraiser of graduate-research programs at various Ontario Universities (1999-2002) and geoscience program reviewers of American University of Beirut in Lebanon (2016-17),Western University (2012) and Hiroshima University (2009). [1]
Hattori has been appointed as Visiting Professor at Universitéde Lyon (1999) and l’UniversiteéGrenoble (2016),Visiting Scientist at Japan Marine Science and Technology (2003-2004),Visiting Professor at Nagoya Institute, [15] Guest Research Scientists at Woods Hole Oceanographic Institution (1995-1996),Visiting Research Scientist at Massachusetts Institute of Technology (1989-1990). [1] [16]
Hattori has made contributions to the field of earth sciences,utilizing trace element geochemistry and stable and radiogenic isotopes to understand the earth processes. During the early stages of her career,she focused on studying active volcanoes and associated hydrothermal activity. However,a tragic accident atop a Colombian volcano,resulting in the loss of several colleagues,prompted her to shift her research focus to ancient volcanic terranes in Canada. Over the past 14 years,she has conducted research in various regions of subduction zones worldwide,where oceanic crust subducts and forms arc volcanoes and mountain belts. Her investigations involve examining rocks and collecting samples to analyze the intricate processes of subduction and the subsequent return of materials to the surface through volcanoes. Her research areas have included the Himalayas (Northern Pakistan,Northern India),Italian and French Alps,Turkey,China,Japan,Philippines,Peru,and the Dominican Republic. [6]
Hattori's contributions to the earth sciences primarily center on utilizing the abundance of redox-sensitive elements and their isotopic compositions to interpret processes from the surface to the mantle. Her discoveries include the timing of the abrupt rise in atmospheric oxygen content at around 2.2 billion years ago during Earth's evolution,the definition of osmium isotope evolution in the mantle,the identification of serpentine as the reservoir of water and fluid-mobile elements in the mantle,and the provision of evidence that oxidized mafic magmas bring base metals and sulfur from the mantle to form giant copper deposits that supply many critical metals for society. In addition,her work has contributed to the discovery of such critical metal deposits through the mobility of metals in surface waters. [17]
Hattori presented evidence in her Nature paper that,resolved the long-standing debate regarding the timing of the change in ancient Earth's surface oxidation. Her findings demonstrated that atmospheric oxygen levels were still low around 2.4 billion years ago,during the early Proterozoic,based on detailed sulfur isotope analysis of sedimentary rocks on the north shore of Lake Huron. [18] In her subsequent work published in Science,she revealed that atmospheric oxygen levels sharply rose within the sedimentary sequence at about 2.3 billion years. [19]
Hattori also highlighted the role of volcanic processes in shaping the surface redox condition,challenging the previously held belief that increased photosynthesis was solely responsible for the oxidation of Earth's surface environment. [20] Subsequent work provided further confirmation of the crystallization of oxidized magmatic sulfates during igneous crystallization, [21] as well as the presence of such sulfate minerals in ancient (2.6 billion years old) igneous rocks. [22]
Hattori defined the osmium isotope evolution of Earth's mantle,providing evidence for an accretion of chondritic meteorites after the core-mantle separation. [23]
Prior to Hattori's research,the origin of large nuggets of platinum-group metals in streams was a subject of debate,with some proposing river water formation under a tropical climate and others suggesting mechanical erosion from rocks. However,her research presented evidence supporting their formation in rocks at high temperatures,followed by erosion to streams. [24] [25] [26]
Through Hattori's research,it was also revealed that platinum grains found in streams contain oxygen,which led to initial suggestions of platinum oxide;however,using synchrotron techniques,it was demonstrated that the oxygen is combined with iron,not with platinum. [27]
Hattori argued that the prevailing view for volcano formation in arcs ic arc formation,that water is released rapidly from subducting slabs when they are metamorphosed to eclogite facies,is inconsistent with geological evidence. Instead,she proposed an alternative mechanism,suggesting that water is continuously released from slabs and stored as serpentinites (hydrated mantle rocks) and stressed that the subsequent dehydration of these serpentinites triggers the formation of arc volcanoes. Her work has established the importance and distribution of serpentinites on the major ocean floors,which control seismic activity and may potentially have played a role in the origin of life on the planet. [28] [29] [30]
Additionally,Hattori's work highlighted that heavy metals and metalloids,such as arsenic and antimony,are generally considered to be concentrated in sulphides,but under sulphur-deficient conditions,these elements behave like normal rock-forming elements. [30] [31]
Hattori and De Hoog,after considering the debate surrounding the cause of varying oxidation conditions in igneous rocks at shallow crustal levels,documented that highly oxidized conditions of rocks are an intrinsic character of the source magma in the mantle. [32] They emphasized the capability of oxidized magmas to transport large quantities of sulfur and metals as well.
In her 1995 work,Hattori provided the initial documentation of oxidized arsenic in the overall reduced mantle,as arsenic is present by replacing Si. One of her PhD students,Jian Wangm,evaluated the redox state of mantle rocks and discovered that carbon is the primary control for the oxidation conditions of the mantle in subduction zones. [33]
Hattori's research interest has also extended to porphyry-type deposits,which supply critical metals such as copper,molybdenum,and gold. Through her research,she presented evidence supporting the notion that sulfur and metals have their origin in the mantle, [34] [35] and proposed that they were extracted and transported by mafic magmas from the mantle to shallow crustal levels. This proposal was based on her earlier work on Pinatubo eruption products,where metals and sulphur are released from mafic magmas during their ascent and incorporated into overlying erupted felsic magmas. [21] Furthermore,Cees-Jan DeHoog,her post-doctoral research fellow,provided evidence that oxidized magmas are capable to transport metals and sulphur from deep in the mantle to shallow levels of crust. [32]
Hattori developed analytical methods that demonstrated the high mobility of palladium as soluble neutral to anionic complexes in surface waters. This behavior allows the metal to disperse widely from its sources,and to become incorporated into plants and organic-rich soil. [36] Her research findings have been presented at various industry-oriented workshops,including short courses associated with the International Platinum Conference in Oulu,Finland,and the Prospectors and Developers Association meeting in Toronto. In addition,her research provided a contrasting perspective to the previously assumed origin of metals in peat from the Hudson Bay Lowland. While it was previously assumed that the metals in peat originated from industrial activity far south of the northern region,she demonstrated that the compositions of ombrotrophic peat are strongly influenced by the underlying rocks,even those located as deep as 20 metres below the surface. This observation further highlighted that the composition of peat may serve as a useful indicator to locate concealed deposits,including kimberlites,which are host to diamonds. [37]
Hattori also examined sturdy minerals that can be dispersed by streams and glaciers to evaluate their usefulness in finding mineral deposits.
Ore is natural rock or sediment that contains one or more valuable minerals concentrated above background levels,typically containing metals,that can be mined,treated and sold at a profit. The grade of ore refers to the concentration of the desired material it contains. The value of the metals or minerals a rock contains must be weighed against the cost of extraction to determine whether it is of sufficiently high grade to be worth mining,and is therefore considered an ore. A complex ore is one containing more than one valuable mineral.
Geochemistry is the science that uses the tools and principles of chemistry to explain the mechanisms behind major geological systems such as the Earth's crust and its oceans. The realm of geochemistry extends beyond the Earth,encompassing the entire Solar System,and has made important contributions to the understanding of a number of processes including mantle convection,the formation of planets and the origins of granite and basalt. It is an integrated field of chemistry and geology.
Basalt is an aphanitic (fine-grained) extrusive igneous rock formed from the rapid cooling of low-viscosity lava rich in magnesium and iron exposed at or very near the surface of a rocky planet or moon. More than 90% of all volcanic rock on Earth is basalt. Rapid-cooling,fine-grained basalt is chemically equivalent to slow-cooling,coarse-grained gabbro. The eruption of basalt lava is observed by geologists at about 20 volcanoes per year. Basalt is also an important rock type on other planetary bodies in the Solar System. For example,the bulk of the plains of Venus,which cover ~80% of the surface,are basaltic;the lunar maria are plains of flood-basaltic lava flows;and basalt is a common rock on the surface of Mars.
Andesite is a volcanic rock of intermediate composition. In a general sense,it is the intermediate type between silica-poor basalt and silica-rich rhyolite. It is fine-grained (aphanitic) to porphyritic in texture,and is composed predominantly of sodium-rich plagioclase plus pyroxene or hornblende.
Anorthosite is a phaneritic,intrusive igneous rock characterized by its composition:mostly plagioclase feldspar (90–100%),with a minimal mafic component (0–10%). Pyroxene,ilmenite,magnetite,and olivine are the mafic minerals most commonly present.
Peridotite ( PERR-ih-doh-tyte,pə-RID-ə-) is a dense,coarse-grained igneous rock consisting mostly of the silicate minerals olivine and pyroxene. Peridotite is ultramafic,as the rock contains less than 45% silica. It is high in magnesium (Mg2+),reflecting the high proportions of magnesium-rich olivine,with appreciable iron. Peridotite is derived from Earth's mantle,either as solid blocks and fragments,or as crystals accumulated from magmas that formed in the mantle. The compositions of peridotites from these layered igneous complexes vary widely,reflecting the relative proportions of pyroxenes,chromite,plagioclase,and amphibole.
Oceanic crust is the uppermost layer of the oceanic portion of the tectonic plates. It is composed of the upper oceanic crust,with pillow lavas and a dike complex,and the lower oceanic crust,composed of troctolite,gabbro and ultramafic cumulates. The crust overlies the rigid uppermost layer of the mantle. The crust and the rigid upper mantle layer together constitute oceanic lithosphere.
Isotope geochemistry is an aspect of geology based upon the study of natural variations in the relative abundances of isotopes of various elements. Variations in isotopic abundance are measured by isotope ratio mass spectrometry,and can reveal information about the ages and origins of rock,air or water bodies,or processes of mixing between them.
Volcanogenic massive sulfide ore deposits,also known as VMS ore deposits,are a type of metal sulfide ore deposit,mainly copper-zinc which are associated with and created by volcanic-associated hydrothermal events in submarine environments.
Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.
A layered intrusion is a large sill-like body of igneous rock which exhibits vertical layering or differences in composition and texture. These intrusions can be many kilometres in area covering from around 100 km2 (39 sq mi) to over 50,000 km2 (19,000 sq mi) and several hundred metres to over one kilometre (3,300 ft) in thickness. While most layered intrusions are Archean to Proterozoic in age,they may be any age such as the Cenozoic Skaergaard intrusion of east Greenland or the Rum layered intrusion in Scotland. Although most are ultramafic to mafic in composition,the Ilimaussaq intrusive complex of Greenland is an alkalic intrusion.
In geology,igneous differentiation,or magmatic differentiation,is an umbrella term for the various processes by which magmas undergo bulk chemical change during the partial melting process,cooling,emplacement,or eruption. The sequence of magmas produced by igneous differentiation is known as a magma series.
In geology,a redox buffer is an assemblage of minerals or compounds that constrains oxygen fugacity as a function of temperature. Knowledge of the redox conditions (or equivalently,oxygen fugacities) at which a rock forms and evolves can be important for interpreting the rock history. Iron,sulfur,and manganese are three of the relatively abundant elements in the Earth's crust that occur in more than one oxidation state. For instance,iron,the fourth most abundant element in the crust,exists as native iron,ferrous iron (Fe2+),and ferric iron (Fe3+). The redox state of a rock affects the relative proportions of the oxidation states of these elements and hence may determine both the minerals present and their compositions. If a rock contains pure minerals that constitute a redox buffer,then the oxygen fugacity of equilibration is defined by one of the curves in the accompanying fugacity-temperature diagram.
Partial melting is the phenomenon that occurs when a rock is subjected to temperatures high enough to cause certain minerals to melt,but not all of them. Partial melting is an important part of the formation of all igneous rocks and some metamorphic rocks,as evidenced by a multitude of geochemical,geophysical and petrological studies.
Igneous rock,or magmatic rock,is one of the three main rock types,the others being sedimentary and metamorphic. Igneous rocks are formed through the cooling and solidification of magma or lava.
Terry Ann Plank is an American geochemist,volcanologist and professor of earth science at Columbia College,Columbia University,and the Lamont Doherty Earth Observatory. She is a 2012 MacArthur Fellow and member of the National Academy of Sciences. Her most prominent work involves the crystal chemistry of lava minerals in order to determine magma ages and movement,giving clues to how quickly magma can surface as lava in volcanoes. Most notably,Plank is known for her work establishing a stronger link between the subduction of ocean sediments and volcanism at ocean arcs. Her current work can be seen at her website.
Plank states that her interest in volcanoes began when her Dartmouth professor took her and other students to Arenal volcano in Costa Rica. He had them sit and have lunch while on top of a slow-moving lava flow and while watching bright red goops of lava crack out from their black casings. "It was totally cool,how could you not like that?" Plank recalled the event to State of the Planet,an Earth Institute News source at Columbia University.
A continental arc is a type of volcanic arc occurring as an "arc-shape" topographic high region along a continental margin. The continental arc is formed at an active continental margin where two tectonic plates meet,and where one plate has continental crust and the other oceanic crust along the line of plate convergence,and a subduction zone develops. The magmatism and petrogenesis of continental crust are complicated:in essence,continental arcs reflect a mixture of oceanic crust materials,mantle wedge and continental crust materials.
Sarah-Jane Barnes is a British-Canadian geologist,who is a professor at the Universitédu Québec àChicoutimi and director of LabMaTer.
Janet Margaret Hergt is an Australian geochemist. She is a Redmond Barry Distinguished Professor in the School of Geography,Earth and Atmospheric Sciences at the University of Melbourne,Victoria,Australia. The main focus of her research has been in the chemical analysis of rocks and minerals to explore the exquisite record of Earth processes preserved within them. Hergt is best known for her geochemical investigations of magmatic rocks although she has employed similar techniques in interdisciplinary projects including areas of archaeological and biological science.
The Dharwar Craton is an Archean continental crust craton formed between 3.6-2.5 billion years ago (Ga),which is located in southern India and considered as the oldest part of the Indian peninsula.