Oldhamite

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Oldhamite
Oldhamite-510145.jpg
Oldhamite (field of view: 1.5 cm)
General
Category Sulfide mineral
Formula
(repeating unit)
(Ca,Mg)S
IMA symbol Old [1]
Strunz classification 2.CD.10
Crystal system Cubic
Crystal class Hexoctahedral (m3m)
H-M symbol: (4/m 3 2/m)
Space group Fm3m
Unit cell a = 5.69 Å; Z = 4
Identification
ColorPale chestnut-brown
Crystal habit Crystal nodules, anhedral grains
Cleavage Good on {001}
Mohs scale hardness4
Luster Sub-metallic
Diaphaneity Transparent
Specific gravity 2.58
Optical propertiesIsotropic
Refractive index n = 2.137
Fusibility 2450 °C
Alters toTarnishes on exposure to moist air
References [2] [3] [4]

Oldhamite is a calcium magnesium sulfide mineral with the chemical formula (Ca,Mg)S. [2] [3] Ferrous iron may also be present in the mineral resulting in the chemical formula (Ca,Mg,Fe)S. [4] It is a pale to dark brown accessory mineral in meteorites. It crystallizes in the cubic crystal system, but typically occurs as anhedral grains between other minerals.

Contents

Discovery and occurrence

It was first described in 1862 for an occurrence in the Bustee meteorite, Gorakhpur, Uttar Pradesh, India. It was named for Irish geologist Thomas Oldham (1816–1878), the Director of the Indian Geological Survey. [2] [3]

It occurs as an interstitial mineral phase between silicate minerals in enstatite chondrite and achondrite meteorites. [2] [4] It occurs in association with enstatite, augite, niningerite, osbornite, troilite, gypsum and calcite. [2] It has been reported from a variety of meteorite locations around the world including the Allan Hills 84001 meteorite of Antarctica. It has also been reported from a slag occurrence in France and a coal deposit in Poland. [3]

See also

Related Research Articles

<span class="mw-page-title-main">Hibonite</span>

Hibonite is a mineral with the chemical formula (Ca,Ce)(Al,Ti,Mg)12O19, occurring in various colours, with a hardness of 7.5–8.0 and a hexagonal crystal structure. It is rare, but is found in high-grade metamorphic rocks on Madagascar. Some presolar grains in primitive meteorites consist of hibonite. Hibonite also is a common mineral in the Ca-Al-rich inclusions found in some chondritic meteorites. Hibonite is closely related to hibonite-Fe ) an alteration mineral from the Allende meteorite. Hibonites were among the first minerals to form as the disk of gas and dust swirling around the young sun cooled.

<span class="mw-page-title-main">Chondrite</span> Class of stony meteorites made of round grains

A chondrite is a stony (non-metallic) meteorite that has not been modified, by either melting or differentiation of the parent body. They are formed when various types of dust and small grains in the early Solar System accreted to form primitive asteroids. Some such bodies that are captured in the planet's gravity well become the most common type of meteorite by arriving on a trajectory toward the planet's surface. Estimates for their contribution to the total meteorite population vary between 85.7% and 86.2%.

<span class="mw-page-title-main">Forsterite</span> Magnesium end-member of olivine, a nesosilicate mineral

Forsterite (Mg2SiO4; commonly abbreviated as Fo; also known as white olivine) is the magnesium-rich end-member of the olivine solid solution series. It is isomorphous with the iron-rich end-member, fayalite. Forsterite crystallizes in the orthorhombic system (space group Pbnm) with cell parameters a 4.75 Å (0.475 nm), b 10.20 Å (1.020 nm) and c 5.98 Å (0.598 nm).

<span class="mw-page-title-main">Enstatite</span> Pyroxene: magnesium-iron silicate with MgSiO3 and FeSiO3 end-members

Enstatite is a mineral; the magnesium endmember of the pyroxene silicate mineral series enstatite (MgSiO3) – ferrosilite (FeSiO3). The magnesium rich members of the solid solution series are common rock-forming minerals found in igneous and metamorphic rocks. The intermediate composition, (Mg,Fe)SiO
3
, has historically been known as hypersthene, although this name has been formally abandoned and replaced by orthopyroxene. When determined petrographically or chemically the composition is given as relative proportions of enstatite (En) and ferrosilite (Fs) (e.g., En80Fs20).

<span class="mw-page-title-main">Hypersthene</span>

Hypersthene is a common rock-forming inosilicate mineral belonging to the group of orthorhombic pyroxenes. Its chemical formula is (Mg,Fe)SiO3. It is found in igneous and some metamorphic rocks as well as in stony and iron meteorites. Many references have formally abandoned this term, preferring to categorise this mineral as enstatite or ferrosilite. It forms a solid solution series with the minerals enstatite and ferrosilite, being a mid-way member between the two. Pure enstatite contains no iron, while pure ferrosilite contains no magnesium; hypersthene is the name given to the mineral when a significant amount of both elements are present. Enstatite is stable at atmospheric pressure, but ferrosilite is stable only at elevated pressure, decomposing into quartz and fayalite at atmospheric pressure unless stabilized by magnesium or other impurities.

<span class="mw-page-title-main">Rhodonite</span> Single chain manganese inosilicate (MnSiO3)

Rhodonite is a manganese inosilicate, with the formula (Mn, Fe, Mg, Ca)SiO3, and member of the pyroxenoid group of minerals, crystallizing in the triclinic system. It commonly occurs as cleavable to compact masses with a rose-red color (its name comes from Ancient Greek ῥόδον (rhódon) 'rose'), often tending to brown due to surface oxidation. The rose-red hue is caused by the manganese cation (Mn2+).

<span class="mw-page-title-main">Hedenbergite</span>

Hedenbergite, CaFeSi2O6, is the iron rich end member of the pyroxene group having a monoclinic crystal system. The mineral is extremely rarely found as a pure substance, and usually has to be synthesized in a lab. It was named in 1819 after M.A. Ludwig Hedenberg, who was the first to define hedenbergite as a mineral. Contact metamorphic rocks high in iron are the primary geologic setting for hedenbergite. This mineral is unique because it can be found in chondrites and skarns (calc–silicate metamorphic rocks). Since it is a member of the pyroxene family, there is a great deal of interest in its importance to general geologic processes.

Keilite is an iron-magnesium sulfide mineral with the chemical formula (Fe,Mg)S) that is found in enstatite chondrites. Keilite is the iron-dominant analog of niningerite. Keilite is named after Klaus Keil.

Niningerite is a magnesium-iron-manganese sulfide mineral with the chemical formula MgS that is found in enstatite chondrite meteorites. Niningerite is the magnesium-dominant analog of keilite. This mineral is named after Harvey H. Nininger.

<span class="mw-page-title-main">Hectorite</span> Rare trioctahedral (Mg2+, Li+) sodium smectite, phyllosilicate mineral

Hectorite is a rare soft, greasy, white clay mineral with a chemical formula of Na0.3(Mg,Li)3Si4O10(OH)2.

<span class="mw-page-title-main">Brianite</span>

Brianite is a phosphate mineral with the chemical formula Na2CaMg(PO4)2. It was first identified in an iron meteorite. This mineral is named after Brian Harold Mason (1917–2009), a pioneer in meteoritics.

<span class="mw-page-title-main">Mackinawite</span> Iron nickel sulfide mineral

Mackinawite is an iron nickel sulfide mineral with the chemical formula (Fe,Ni)
1+x
S
. The mineral crystallizes in the tetragonal crystal system and has been described as a distorted, close packed, cubic array of S atoms with some of the gaps filled with Fe. Mackinawite occurs as opaque bronze to grey-white tabular crystals and anhedral masses. It has a Mohs hardness of 2.5 and a specific gravity of 4.17. It was first described in 1962 for an occurrence in the Mackinaw mine, Snohomish County, Washington for which it was named.

<span class="mw-page-title-main">Majorite</span> Garnet mineral

Majorite is a type of garnet mineral found in the mantle of the Earth. Its chemical formula is Mg3(MgSi)(SiO4)3. It is distinguished from other garnets in having Si in octahedral as well as tetrahedral coordination. Majorite was first described in 1970 from the Coorara Meteorite of Western Australia and has been reported from various other meteorites in which majorite is thought to result from an extraterrestrial high pressure shock event. Mantle derived xenoliths containing majorite have been reported from potassic ultramafic magmas on Malaita Island on the Ontong Java Plateau Southwest Pacific.

<span class="mw-page-title-main">Tschermakite</span> Amphibole, double chain inosilicate mineral

The endmember hornblende tschermakite (☐Ca2(Mg3Al2)(Si6Al2)O22(OH)2) is a calcium rich monoclinic amphibole mineral. It is frequently synthesized along with its ternary solid solution series members tremolite and cummingtonite so that the thermodynamic properties of its assemblage can be applied to solving other solid solution series from a variety of amphibole minerals.

Roaldite is a rare meteorite mineral containing iron, nickel and nitrogen. Its chemical formula is (Fe,Ni)4N.

Wassonite is an extremely rare titanium sulfide mineral with chemical formula TiS. Its discovery was announced in a 2011 NASA press release as a single small grain within an enstatite chondrite meteorite called "Yamato 691", which was found during a 1969 Japanese expedition to Antarctica. This grain represents the first observation in nature of the synthetic compound titanium(II) sulfide.

Silicate perovskite is either (Mg,Fe)SiO3 or CaSiO3 when arranged in a perovskite structure. Silicate perovskites are not stable at Earth's surface, and mainly exist in the lower part of Earth's mantle, between about 670 and 2,700 km depth. They are thought to form the main mineral phases, together with ferropericlase.

<span class="mw-page-title-main">Daubréelite</span>

Daubréelite is a rare sulfide mineral. It crystallizes with cubic symmetry and has chemical composition of Fe2+Cr3+2S4. It usually occurs as black platy aggregates.

<span class="mw-page-title-main">Zaklodzie meteorite</span>

The Zakłodzie meteorite is a stony-iron meteorite found in Poland in 1998. Its mass is 8.68 kilograms (19.1 lb). It is composed predominantly from enstatite and meteoric iron. Currently classified as an ungrouped enstatite achondrite its classification is still an ongoing scientific debate.

<span class="mw-page-title-main">Kosmochlor</span>

Kosmochlor is a rare chromium sodium clinopyroxene with the chemical formula NaCr3+Si2O6.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 4 5 Handbook of Mineralogy
  3. 1 2 3 4 Oldhamite on Mindat.org
  4. 1 2 3 Webmineral dat for oldhamite