Panguite

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Panguite
General
Category Oxide mineral
Formula
(repeating unit)
(Ti4+,Sc,Al,Mg,Zr,Ca)1.8O3
IMA symbol Pgu [1]
Crystal system Orthorhombic
Crystal class Dipyramidal (mmm)
H-M symbol: (2/m 2/m 2/m)
Space group Pbca
Unit cell a = 9.781(1) Å,
b = 9.778(2) Å,
c = 9.815(1) Å; Z = 16
Identification
Crystal habit Microscopic inclusion
Specific gravity 3.746 (calculated)
References [2] [3]

Panguite is a type of titanium oxide mineral first discovered as an inclusion within the Allende meteorite, and first described in 2012. [4] [5]

Contents

The hitherto unknown meteorite mineral was named for the ancient Chinese god Pan Gu, the creator of the world through the separation of yin (earth) from yang (sky). [4]

Composition

The mineral's chemical formula is (Ti4+,Sc,Al,Mg,Zr,Ca)1.8O3. The elements found in it are titanium, scandium, aluminium, magnesium, zirconium, calcium, and oxygen. Samples from the meteorite include some which are zirconium rich. The mineral was found in conjunction with the already identified mineral davisite, within an olivine aggregate. [6]

Origin and properties

Panguite is in a class of refractory minerals that formed under the high temperatures and extremely varied pressures present in the early Solar System, up to 4.5 billion years ago. This makes panguite one of the oldest minerals in the Solar System. Zirconium is a key element in determining conditions prior to and during the Solar System's formation.

Discovery

Chi Ma, director of the Geological and Planetary Sciences division's Analytical Facility at the California Institute of Technology was the lead author of its first peer-reviewed article, published in American Mineralogist . [3] Ma has been leading a nano mineralogy investigation, since 2007, of primitive meteorites, including the well studied Allende meteorite. The mineral was first described in a paper submitted to the 42nd annual Lunar and Planetary Science Conference in 2011. [7]

See also

Related Research Articles

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Zirconium is a chemical element; it has symbol Zr and atomic number 40. The name zirconium is derived from the name of the mineral zircon, the most important source of zirconium. The word is related to Persian zargun. It is a lustrous, grey-white, strong transition metal that closely resembles hafnium and, to a lesser extent, titanium.

<span class="mw-page-title-main">Zircon</span> Zirconium silicate, a mineral belonging to the group of nesosilicates

Zircon is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green.

<span class="mw-page-title-main">Ilmenite</span> Titanium-iron oxide mineral

Ilmenite is a titanium-iron oxide mineral with the idealized formula FeTiO
3
. It is a weakly magnetic black or steel-gray solid. Ilmenite is the most important ore of titanium and the main source of titanium dioxide, which is used in paints, printing inks, fabrics, plastics, paper, sunscreen, food and cosmetics.

<span class="mw-page-title-main">Baddeleyite</span>

Baddeleyite is a rare zirconium oxide mineral (ZrO2 or zirconia), occurring in a variety of monoclinic prismatic crystal forms. It is transparent to translucent, has high indices of refraction, and ranges from colorless to yellow, green, and dark brown. See etymology below.

<span class="mw-page-title-main">Anorthosite</span> Mafic intrusive igneous rock composed predominantly of plagioclase

Anorthosite is a phaneritic, intrusive igneous rock characterized by its composition: mostly plagioclase feldspar (90–100%), with a minimal mafic component (0–10%). Pyroxene, ilmenite, magnetite, and olivine are the mafic minerals most commonly present.

<span class="mw-page-title-main">Armalcolite</span> Oxide mineral

Armalcolite is a titanium-rich mineral with the chemical formula (Mg,Fe2+)Ti2O5. It was first found at Tranquility Base on the Moon in 1969 during the Apollo 11 mission, and is named for Armstrong, Aldrin and Collins, the three Apollo 11 astronauts. Together with tranquillityite and pyroxferroite, it is one of three new minerals that were discovered on the Moon. Armalcolite was later identified at various locations on Earth and has been synthesized in the laboratory. (Tranquillityite and pyroxferroite were also later found at various locations on Earth). The synthesis requires low pressures, high temperatures and rapid quenching from about 1,000 °C to the ambient temperature. Armalcolite breaks down to a mixture of magnesium-rich ilmenite and rutile at temperatures below 1,000 °C, but the conversion slows down with cooling. Because of this quenching requirement, armalcolite is relatively rare and is usually found in association with ilmenite and rutile, among other minerals.

<span class="mw-page-title-main">Chondrite</span> Class of stony meteorites made of round grains

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Moon rock or lunar rock is rock originating from Earth's Moon. This includes lunar material collected during the course of human exploration of the Moon, and rock that has been ejected naturally from the Moon's surface and landed on Earth as meteorites.

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Wadsleyite is an orthorhombic mineral with the formula β-(Mg,Fe)2SiO4. It was first found in nature in the Peace River meteorite from Alberta, Canada. It is formed by a phase transformation from olivine (α-(Mg,Fe)2SiO4) under increasing pressure and eventually transforms into spinel-structured ringwoodite (γ-(Mg,Fe)2SiO4) as pressure increases further. The structure can take up a limited amount of other bivalent cations instead of magnesium, but contrary to the α and γ structures, a β structure with the sum formula Fe2SiO4 is not thermodynamically stable. Its cell parameters are approximately a = 5.7 Å, b = 11.71 Å and c = 8.24 Å.

<span class="mw-page-title-main">Gehlenite</span> Sorosilicate mineral

Gehlenite, (Ca2Al[AlSiO7]), is a sorosilicate, Al-rich endmember of the melilite complete solid solution series with akermanite. The type locality is in the Monzoni Mountains, Fassa Valley in Trentino in Italy, and is named after Adolf Ferdinand Gehlen (1775–1815) by A.J. Fuchs in 1815.

<span class="mw-page-title-main">Allende meteorite</span> CV3 carbonaceous chondrite meteorite

The Allende meteorite is the largest carbonaceous chondrite ever found on Earth. The fireball was witnessed at 01:05 on February 8, 1969, falling over the Mexican state of Chihuahua. After it broke up in the atmosphere, an extensive search for pieces was conducted and over 2 tonnes were recovered. The availability of large quantities of samples of the scientifically important chondrite class has enabled numerous investigations by many scientists; it is often described as "the best-studied meteorite in history." The Allende meteorite has abundant, large calcium–aluminium-rich inclusions (CAI), which are among the oldest objects formed in the Solar System.

<span class="mw-page-title-main">Enstatite chondrite</span> Rare type of meteorite

Enstatite chondrites are a rare form of meteorite, rich in the mineral enstatite. Only about 200 E-Type chondrites are currently known, comprising about 2% of the chondrites that fall on Earth. There are two main subtypes: EH and EL, classified based on their iron content.

<span class="mw-page-title-main">Primitive mantle</span> Layer in a newly formed planet

In geochemistry, the primitive mantle is the chemical composition of the Earth's mantle during the developmental stage between core-mantle differentiation and the formation of early continental crust. The chemical composition of the primitive mantle contains characteristics of both the crust and the mantle.

Tranquillityite is silicate mineral with formula (Fe2+)8Ti3Zr2 Si3O24. It is mostly composed of iron, oxygen, silicon, zirconium and titanium with smaller fractions of yttrium and calcium. It is named after the Mare Tranquillitatis (Sea of Tranquility), the place on the Moon where the rock samples were found during the 1969 Apollo 11 mission. It was the last mineral brought from the Moon which was thought to be unique, with no counterpart on Earth, until it was discovered in Australia in 2011.

Krotite is a natural mineral composed of calcium, aluminium and oxygen, with the molecular formula CaAl2O4. It is the low-pressure dimorph of CaAl2O4, of which the high-pressure dimorph is named dmitryivanovite.

<span class="mw-page-title-main">Zaklodzie meteorite</span> Meteorite found in Poland

The Zakłodzie meteorite is a stony-iron meteorite found in Poland in 1998. Its mass is 8.68 kilograms (19.1 lb). It is composed predominantly from enstatite and meteoric iron. Currently classified as an ungrouped enstatite achondrite its classification is still an ongoing scientific debate.

Kangite is an exceedingly rare scandium mineral, a natural form of impure scandium oxide (Sc2O3), with the formula (Sc,Ti,Al,Zr,Mg,Ca,□)2O3. It crystallizes in the cubic crystal system diploidal class. In terms of chemistry it scandium-analogue of tistarite. Both kangite and tistarite were discovered in the Allende meteorite.

Allendeite, Sc4Zr3O12, is an oxide mineral. Allendeite was discovered in a small ultrarefractory inclusion within the Allende meteorite. This inclusion has been named ACM-1. It is one of several scandium rich minerals that have been found in meteorites. Allendeite is trigonal, with a calculated density of 4.84 g/cm3. The new mineral was found along with hexamolybdenum. These minerals, are believed to demonstrate conditions during the early stages of the Solar System, as is the case with many CV3 carbonaceous chondrites such as the Allende meteorite. It is named after the Allende meteorite that fell in 1969 near Pueblito de Allende, Chihuahua, Mexico.

Tistarite is an exceedingly rare mineral with the formula Ti2O3, thus being the natural analogue of titanium(III) oxide. In terms of chemistry it is the titanium-analogue of hematite, corundum, eskolaite, and karelianite. Other minerals with the general formula A2O3 are arsenolite, avicennite, claudetite, bismite, bixbyite, kangite, sphaerobismoite, yttriaite-(Y) and valentinite. Tistarite and grossmanite – both found in the famous Allende meteorite (so is kangite) – are the only currently known minerals with trivalent titanium. Titanium in minerals is almost exclusively tetravalent. The only known terrestrial occurrence of tistarite was found during minerals exploration by Shefa Yamim Ltd. in the upper mantle beneath Mount Carmel, Israel.

CM chondrites are a group of chondritic meteorites which resemble their type specimen, the Mighei meteorite. The CM is the most commonly recovered group of the 'carbonaceous chondrite' class of meteorites, though all are rarer in collections than ordinary chondrites.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. Panguite on Mindat.org
  3. 1 2 Ma C. et al. 2012. "Panguite, (Ti4+,Sc,Al,Mg,Zr,Ca)1.8O3, a new ultra-refractory titania mineral from the Allende meteorite: Synchrotron micro-diffraction and EBSD", American Mineralogist, Volume 97, pages 1219–1225
  4. 1 2 "Caltech scientists find new primitive mineral in meteorite". Eurekalert. 26 June 2012. Retrieved 26 June 2012.
  5. Jeanna Bryner (26 June 2012), "1969 fireball meteorite reveals new ancient mineral", NBCNews.com , archived from the original on 3 January 2013
  6. Mann, Adam (26 June 2012). "Meteorite Hunter Discovers New Mineral". Wired. Retrieved 15 April 2024.
  7. Ma, Chi; Oliver Tschauner; John R. Beckett; Boris Kiefer; George R. Rossman; Wenjun Liu. "Discovery of Panguite, a New Ultra-Refractory Titania Mineral in Allende". 42nd Lunar and Planetary Science Conference (2011). Retrieved 28 June 2012.