Paschen's law

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Paschen curves obtained for helium, neon, argon, hydrogen and nitrogen, using the expression for the breakdown voltage as a function of the parameters A,B that interpolate the first Townsend coefficient. Paschen curves.svg
Paschen curves obtained for helium, neon, argon, hydrogen and nitrogen, using the expression for the breakdown voltage as a function of the parameters A,B that interpolate the first Townsend coefficient.

Paschen's law is an equation that gives the breakdown voltage, that is, the voltage necessary to start a discharge or electric arc, between two electrodes in a gas as a function of pressure and gap length. [2] [3] It is named after Friedrich Paschen who discovered it empirically in 1889. [4]

Breakdown voltage

The breakdown voltage of an insulator is the minimum voltage that causes a portion of an insulator to become electrically conductive.

Voltage difference in the electric potential between two points in space

Voltage, electric potential difference, electric pressure or electric tension is the difference in electric potential between two points. The difference in electric potential between two points in a static electric field is defined as the work needed per unit of charge to move a test charge between the two points. In the International System of Units, the derived unit for voltage is named volt. In SI units, work per unit charge is expressed as joules per coulomb, where 1 volt = 1 joule per 1 coulomb. The official SI definition for volt uses power and current, where 1 volt = 1 watt per 1 ampere. This definition is equivalent to the more commonly used 'joules per coulomb'. Voltage or electric potential difference is denoted symbolically by V, but more often simply as V, for instance in the context of Ohm's or Kirchhoff's circuit laws.

Electric arc electrical breakdown of a gas that produces an ongoing electrical discharge

An electric arc, or arc discharge, is an electrical breakdown of a gas that produces a prolonged electrical discharge. The current through a normally nonconductive medium such as air produces a plasma; the plasma may produce visible light. An arc discharge is characterized by a lower voltage than a glow discharge and relies on thermionic emission of electrons from the electrodes supporting the arc. An archaic term is voltaic arc, as used in the phrase "voltaic arc lamp".

Contents

Paschen studied the breakdown voltage of various gases between parallel metal plates as the gas pressure and gap distance were varied:

Gas One of the four fundamental states of matter

Gas is one of the four fundamental states of matter. A pure gas may be made up of individual atoms, elemental molecules made from one type of atom, or compound molecules made from a variety of atoms. A gas mixture, such as air, contains a variety of pure gases. What distinguishes a gas from liquids and solids is the vast separation of the individual gas particles. This separation usually makes a colorless gas invisible to the human observer. The interaction of gas particles in the presence of electric and gravitational fields are considered negligible, as indicated by the constant velocity vectors in the image.

Pressure Force distributed continuously over an area

Pressure is the force applied perpendicular to the surface of an object per unit area over which that force is distributed. Gauge pressure is the pressure relative to the ambient pressure.

Distance is a numerical measurement of how far apart objects or points are. In physics or everyday usage, distance may refer to a physical length or an estimation based on other criteria. In most cases, "distance from A to B" is interchangeable with "distance from B to A". In mathematics, a distance function or metric is a generalization of the concept of physical distance. A metric is a function that behaves according to a specific set of rules, and is a way of describing what it means for elements of some space to be "close to" or "far away from" each other.

For a given gas, the voltage is a function only of the product of the pressure and gap length. [2] [3] The curve he found of voltage versus the pressure-gap length product (right) is called Paschen's curve. He found an equation that fit these curves, which is now called Paschen's law. [3]

At higher pressures and gap lengths, the breakdown voltage is approximately proportional to the product of pressure and gap length, and the term Paschen's law is sometimes used to refer to this simpler relation. [5] However, this is only roughly true, over a limited range of the curve.

Paschen curve

Early vacuum experimenters found a rather surprising behavior. An arc would sometimes take place in a long irregular path rather than at the minimal distance between the electrodes. For example, in air, at a pressure of one atmosphere, the distance for minimal breakdown voltage is about 7.5 μm. The voltage required to arc this distance is 327 V, which is insufficient to ignite the arcs for gaps that are either wider or narrower. For a 3.5 μm gap, the required voltage is 533 V, nearly twice as much. If 500 V were applied, it would not be sufficient to arc at the 2.85 μm distance, but would arc at a 7.5 μm distance.

Vacuum Space that is empty of matter

Vacuum is space devoid of matter. The word stems from the Latin adjective vacuus for "vacant" or "void". An approximation to such vacuum is a region with a gaseous pressure much less than atmospheric pressure. Physicists often discuss ideal test results that would occur in a perfect vacuum, which they sometimes simply call "vacuum" or free space, and use the term partial vacuum to refer to an actual imperfect vacuum as one might have in a laboratory or in space. In engineering and applied physics on the other hand, vacuum refers to any space in which the pressure is lower than atmospheric pressure. The Latin term in vacuo is used to describe an object that is surrounded by a vacuum.

The standard atmosphere is a unit of pressure defined as 101325 Pa. It is sometimes used as a reference or standard pressure. It is approximately equal to the atmospheric pressure at sea level.

Paschen found that breakdown voltage was described by the equation [1]

where is the breakdown voltage in volts, is the pressure in pascals, is the gap distance in meters, is the secondary-electron-emission coefficient (the number of secondary electrons produced per incident positive ion), is the saturation ionization in the gas at a particular (electric field/pressure), and is related to the excitation and ionization energies.

The constants and are determined experimentally and found to be roughly constant over a restricted range of for any given gas. For example, air with an in the range of 450 to 7500 V/(kPa·cm),  = 112.50 (kPa·cm)−1 and = 2737.50 V/(kPa·cm). [6]

The graph of this equation is the Paschen curve. By differentiating it with respect to and setting the derivative to zero, the minimal voltage can be found. This yields

and predicts the occurrence of a minimal breakdown voltage for  = 7.5×10−6 m·atm. This is 327 V in air at standard atmospheric pressure at a distance of 7.5 μm.

The composition of the gas determines both the minimal arc voltage and the distance at which it occurs. For argon, the minimal arc voltage is 137 V at a larger 12 μm. For sulfur dioxide, the minimal arc voltage is 457 V at only 4.4 μm.

Long gaps

For air at standard conditions for temperature and pressure (STP), the voltage needed to arc a 1-metre gap is about 3.4 MV. [7] The intensity of the electric field for this gap is therefore 3.4 MV/m.

The electric field needed to arc across the minimal-voltage gap is much greater than what is necessary to arc a gap of one metre. For a 7.5 μm gap the arc voltage is 327 V, which is 43 MV/m. This is about 13 times greater than the field strength for the 1-metre gap. The phenomenon is well verified experimentally and is referred to as the Paschen minimum.

The equation loses accuracy for gaps under about 10 μm in air at one atmosphere [8] and incorrectly predicts an infinite arc voltage at a gap of about 2.7 micrometres. Breakdown voltage can also differ from the Paschen curve prediction for very small electrode gaps, when field emission from the cathode surface becomes important.

Physical mechanism

The mean free path of a molecule in a gas is the average distance between its collision with other molecules. This is inversely proportional to the pressure of the gas. In air at 1 atm the mean free path of molecules is about 96 nm. Since electrons are much smaller, their average distance between colliding with molecules is about 5.6 times longer, or about 0.5 μm. This is a substantial fraction of the 7.5 μm spacing between the electrodes for minimal arc voltage. If the electron is in an electric field of 43 MV/m, it will be accelerated and acquire 21.5  eV of energy in 0.5 μm of travel in the direction of the field. The first ionization energy needed to dislodge an electron from nitrogen molecule is about 15.6 eV. The accelerated electron will acquire more than enough energy to ionize a nitrogen molecule. This liberated electron will in turn be accelerated, which will lead to another collision. A chain reaction then leads to avalanche breakdown, and an arc takes place from the cascade of released electrons. [9]

More collisions will take place in the electron path between the electrodes in a higher-pressure gas. When the pressure–gap product is high, an electron will collide with many different gas molecules as it travels from the cathode to the anode. Each of the collisions randomizes the electron direction, so the electron is not always being accelerated by the electric field—sometimes it travels back towards the cathode and is decelerated by the field.

Collisions reduce the electron's energy and make it more difficult for it to ionize a molecule. Energy losses from a greater number of collisions require larger voltages for the electrons to accumulate sufficient energy to ionize many gas molecules, which is required to produce an avalanche breakdown.

On the left side of the Paschen minimum, the product is small. The electron mean free path can become long compared to the gap between the electrodes. In this case, the electrons might gain lots of energy, but have fewer ionizing collisions. A greater voltage is therefore required to assure ionization of enough gas molecules to start an avalanche.

Derivation

Basics

To calculate the breakthrough voltage, a homogeneous electrical field is assumed. This is the case in a parallel-plate capacitor setup. The electrodes may have the distance . The cathode is located at the point .

To get impact ionization, the electron energy must become greater than the ionization energy of the gas atoms between the plates. Per length of path a number of ionizations will occur. is known as the first Townsend coefficient as it was introduced by Townsend [10] . The increase of the electron current , can be described for the assumed setup as

(So the number of free electrons at the anode is equal to the number of free electrons at the cathode that were multiplied by impact ionization. The larger and/or , the more free electrons are created.)

The number of created electrons is

Neglecting possible multiple ionizations of the same atom, the number of created ions is the same as the number of created electrons:

is the ion current. To keep the discharge going on, free electrons must be created at the cathode surface. This is possible because the ions hitting the cathode release secondary electrons at the impact. (For very large applied voltages also field electron emission can occur.) Without field emission, we can write

where is the mean number of generated secondary electrons per ion. This is also known as the second Townsend coefficient. Assuming that , one gets the relation between the Townsend coefficients by putting (4) into (3) and transforming:

Impact ionization

What is the amount of ? The number of ionization depends upon the probability that an electron hits a gas molecule. This probability is the relation of the cross-sectional area of a collision between electron and ion in relation to the overall area that is available for the electron to fly through:

As expressed by the second part of the equation, it is also possible to express the probability as relation of the path traveled by the electron to the mean free path (distance at which another collision occurs).

Visualization of the cross-section
s
{\displaystyle \sigma }
: If the center of particle b penetrates the blue circle, a collision occurs with particle a. So the area of the circle is the cross-section and its radius
r
{\displaystyle r}
is the sum of the radii of the particles. Wirkungsquerschnitt-Skizze.svg
Visualization of the cross-section : If the center of particle b penetrates the blue circle, a collision occurs with particle a. So the area of the circle is the cross-section and its radius is the sum of the radii of the particles.

is the number of molecules which electrons can hit. It can be calculated using the equation of state of the ideal gas

(: pressure, : volume, : Boltzmann constant, : temperature)

The adjoining sketch illustrates that . As the radius of an electron can be neglected compared to the radius of an ion it simplifies to . Using this relation, putting (7) into (6) and transforming to one gets

where the factor was only introduced for a better overview.

The alteration of the current of not yet collided electrons at every point in the path can be expressed as

This differential equation can easily be solved:

The probability that (that there was not yet a collision at the point ) is

According to its definition is the number of ionizations per length of path and thus the relation of the probability that there was no collision in the mean free path of the ions, and the mean free path of the electrons:

It was hereby considered that the energy that a charged particle can get between a collision depends on the electric field strength and the charge :

Breakdown voltage

For the parallel-plate capacitor we have , where is the applied voltage. As a single ionization was assumed is the elementary charge . We can now put (13) and (8) into (12) and get

Putting this into (5) and transforming to we get the Paschen law for the breakdown voltage that was first investigated by Paschen in [11] and whose formula was first derived by Townsend in, [12] section 227:

with

Plasma ignition

Plasma ignition in definition of Townsend (Townsend discharge) is a self-sustaining discharge, independent of an external source of free electrons. This means that electrons from the cathode can reach the anode in the distance and ionize at least one atom on their way. So according to the definition of this relation must be fulfilled:

If is used instead of (5) one gets for the breakdown voltage

Conclusions, validity

Paschen's law requires that:

Effects with different gases

Different gases will have different mean free paths for molecules and electrons. This is because different molecules have different diameters. Noble gases like helium and argon are monatomic and tend to have smaller diameters. This gives them greater mean free paths.

Ionization potentials differ between molecules, as well as the speed that they recapture electrons after they have been knocked out of orbit. All three effects change the number of collisions needed to cause an exponential growth in free electrons. These free electrons are necessary to cause an arc.

See also

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