Refinery

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Shell Haven Oil Refinery Shell Haven oil refinery.tif
Shell Haven Oil Refinery

A refinery is a production facility composed of a group of chemical engineering unit processes and unit operations refining certain materials or converting raw material into products of value.

Contents

Types of refineries

Different types of refineries are as follows:

A typical oil refinery

The image below is a schematic flow diagram of a typical oil refinery depicting various unit processes and the flow of intermediate products between the inlet crude oil feedstock and the final products. The diagram depicts only one of the hundreds of different configurations. It does not include any of the usual facilities providing utilities such as steam, cooling water, and electric power as well as storage tanks for crude oil feedstock and for intermediate products and end products. [2] [3] [4] [5] [6]

Schematic flow diagram of a typical oil refinery RefineryFlow.png
Schematic flow diagram of a typical oil refinery

Natural gas processing plant

The image below is a schematic block flow diagram of a typical natural gas processing plant. It shows various unit processes converting raw natural gas into gas pipelined to end users.

The block flow diagram also shows how processing of the raw natural gas yields byproduct sulfur, byproduct ethane, and natural gas liquids (NGL) propane, butanes and natural gasoline (denoted as pentanes +). [7] [8] [9] [10] [11]

Schematic flow diagram of a typical natural gas processing plant NatGasProcessing.png
Schematic flow diagram of a typical natural gas processing plant

Sugar refining

Sugar is generally produced from sugarcane or sugar beets. As the global production of sugar from sugarcane is at least twice the production from sugar beets, this section focuses on sugarcane. [12]

Milling

Harvested sugar cane ready for processing Cut sugarcane.jpg
Harvested sugar cane ready for processing

Sugarcane is traditionally refined into sugar in two stages. In the first stage, raw sugar is produced by the milling of harvested sugarcane. In a sugar mill, sugarcane is washed, chopped, and shredded by revolving knives. The shredded cane is mixed with water and crushed. The juices (containing 10-15 percent sucrose) are collected and mixed with lime to adjust pH to 7, prevent decay into glucose and fructose, and precipitate impurities. The lime and other suspended solids are settled out, and the clarified juice is concentrated in a multiple-effect evaporator to make a syrup with about 60 weight percent sucrose. The syrup is further concentrated under vacuum until it becomes supersaturated and is then seeded with crystalline sugar. Upon cooling, sugar crystallizes out of the syrup. Centrifuging then separates the sugar from the remaining liquid (molasses). Raw sugar has a yellow to brown color. Sugar is sometimes consumed locally at this stage but usually undergoes further purification. [13] Sulfur dioxide is bubbled through the cane juice subsequent to crystallization in a process known as "sulfitation". This process inhibits color forming reactions and stabilizes the sugar juices to produce "mill white" or "plantation white" sugar.

The fibrous solids, called bagasse, remaining after the crushing of the shredded sugarcane are burned for fuel which helps a sugar mill to become self-sufficient in energy. Any excess bagasse can be used for animal feed, to produce paper, or burned to generate electricity for the local power grid.

Refining

Sugar refinery in Arabi, Louisiana, United States ArabiDominoSugarFromAlgiers19May06A.jpg
Sugar refinery in Arabi, Louisiana, United States

The second stage is often executed in heavy sugar-consuming regions such as North America, Europe, and Japan. In the second stage, white sugar is produced that is more than 99 percent pure sucrose. In such refineries, raw sugar is further purified by fractional crystallization.

Related Research Articles

<span class="mw-page-title-main">Sugar</span> Sweet-tasting, water-soluble carbohydrates

Sugar is the generic name for sweet-tasting, soluble carbohydrates, many of which are used in food. Simple sugars, also called monosaccharides, include glucose, fructose, and galactose. Compound sugars, also called disaccharides or double sugars, are molecules made of two bonded monosaccharides; common examples are sucrose, lactose, and maltose. White sugar is a refined form of sucrose. In the body, compound sugars are hydrolysed into simple sugars.

<span class="mw-page-title-main">Sugar beet</span> Plant grown commercially for sugar production

A sugar beet is a plant whose root contains a high concentration of sucrose and which is grown commercially for sugar production. In plant breeding, it is known as the Altissima cultivar group of the common beet. Together with other beet cultivars, such as beetroot and chard, it belongs to the subspecies Beta vulgaris subsp. vulgaris but classified as var. saccharifera . Its closest wild relative is the sea beet.

<span class="mw-page-title-main">Sucrose</span> Disaccharide made of glucose and fructose

Sucrose, a disaccharide, is a sugar composed of glucose and fructose subunits. It is produced naturally in plants and is the main constituent of white sugar. It has the molecular formula C
12
H
22
O
11
.

<span class="mw-page-title-main">Oil refinery</span> Facility that processes crude oil

An oil refinery or petroleum refinery is an industrial process plant where petroleum is transformed and refined into products such as gasoline (petrol), diesel fuel, asphalt base, fuel oils, heating oil, kerosene, liquefied petroleum gas and petroleum naphtha. Petrochemical feedstock like ethylene and propylene can also be produced directly by cracking crude oil without the need of using refined products of crude oil such as naphtha. The crude oil feedstock has typically been processed by an oil production plant. There is usually an oil depot at or near an oil refinery for the storage of incoming crude oil feedstock as well as bulk liquid products. In 2020, the total capacity of global refineries for crude oil was about 101.2 million barrels per day.

<span class="mw-page-title-main">Syrup</span> Thick, viscous solution of sugar in water

In cooking, syrup is a condiment that is a thick, viscous liquid consisting primarily of a solution of sugar in water, containing a large amount of dissolved sugars but showing little tendency to deposit crystals. In its concentrated form, its consistency is similar to that of molasses. The viscosity arises from the multiple hydrogen bonds between the dissolved sugar, which has many hydroxyl (OH) groups.

<span class="mw-page-title-main">Brown sugar</span> Sucrose sugar product with a distinctive brown colour

Brown sugar is a sucrose sugar product with a distinctive brown color due to the presence of molasses. It is by tradition an unrefined or partially refined soft sugar consisting of sugar crystals with some residual molasses content, but is now often produced by the addition of molasses to refined white sugar.

Carbonatation is a chemical reaction in which calcium hydroxide reacts with carbon dioxide and forms insoluble calcium carbonate:

<span class="mw-page-title-main">Sugar refinery</span> Factory which processes raw sugar into white sugar

A sugar refinery is a refinery which processes raw sugar from cane or sugar extracted from beets into white refined sugar.

<span class="mw-page-title-main">Golden syrup</span> Thick amber-colored form of inverted sugar syrup

Golden syrup or light treacle is a thick, amber-coloured form of inverted sugar syrup made by the process of refining sugar cane or sugar beet juice into sugar. It is used in a variety of baking recipes and desserts. It has an appearance and consistency similar to honey, and is often used as a substitute where honey is unavailable.

The oil and gas industry is usually divided into three major sectors: upstream, midstream, and downstream. The downstream sector is the refining of petroleum crude oil and the processing and purifying of raw natural gas, as well as the marketing and distribution of products derived from crude oil and natural gas. The downstream sector reaches consumers through products such as gasoline or petrol, kerosene, jet fuel, diesel oil, heating oil, fuel oils, lubricants, waxes, asphalt, natural gas, and liquefied petroleum gas (LPG) as well as naphtha and hundreds of petrochemicals.

<span class="mw-page-title-main">Midstream</span> Sector of the oil and gas industry

The oil and gas industry is usually divided into three major components: upstream, midstream and downstream. The midstream sector involves the transportation, storage, and wholesale marketing of crude or refined petroleum products. Pipelines and other transport systems can be used to move crude oil from production sites to refineries and deliver the various refined products to downstream distributors. Natural gas pipeline networks aggregate gas from natural gas purification plants and deliver it to downstream customers, such as local utilities.

<span class="mw-page-title-main">Natural-gas processing</span> Industrial processes designed to purify raw natural gas

Natural-gas processing is a range of industrial processes designed to purify raw natural gas by removing contaminants such as solids, water, carbon dioxide (CO2), hydrogen sulfide (H2S), mercury and higher molecular mass hydrocarbons (condensate) to produce pipeline quality dry natural gas for pipeline distribution and final use. Some of the substances which contaminate natural gas have economic value and are further processed or sold. Hydrocarbons that are liquid at ambient conditions: temperature and pressure (i.e., pentane and heavier) are called natural-gas condensate (sometimes also called natural gasoline or simply condensate).

Coffeyville Resources, formerly known as the COOP Refinery, is a company which owns an oil refinery in Coffeyville, Kansas. The refinery is owned and operated by Coffeyville Resources Refining & Marketing. The refinery employs about 500 people and produces approximately 2,100,000 US gallons (7,900,000 L) of gasoline per day, and 1,700,000 US gallons (6,400,000 L) of middle distillates per day, predominantly diesel oil.

<span class="mw-page-title-main">Sugarcane</span> Several species of grass cultivated for sugar production

Sugarcane or sugar cane is a species of tall, perennial grass that is used for sugar production. The plants are 2–6 m (6–20 ft) tall with stout, jointed, fibrous stalks that are rich in sucrose, which accumulates in the stalk internodes. Sugarcanes belong to the grass family, Poaceae, an economically important flowering plant family that includes maize, wheat, rice, and sorghum, and many forage crops. It is native to the warm temperate and tropical regions of India, Southeast Asia, and New Guinea. Grown in tropical and subtropical regions, sugarcane is the world's largest crop by production quantity, totaling 1.9 billion tonnes in 2020, with Brazil accounting for 40% of the world total. Sugarcane accounts for 79% of sugar produced globally. About 70% of the sugar produced comes from Saccharum officinarum and its hybrids. All sugarcane species can interbreed, and the major commercial cultivars are complex hybrids.

<span class="mw-page-title-main">Sugarcane mill</span> Factory that processes sugar cane to produce raw or white sugar

A sugar cane mill is a factory that processes sugar cane to produce raw sugar or plantation white sugar. Some sugar mills are situated next to a back-end refinery, that turns raw sugar into (refined) white sugar.

<span class="mw-page-title-main">Petroleum refining processes</span> Methods of transforming crude oil

Petroleum refining processes are the chemical engineering processes and other facilities used in petroleum refineries to transform crude oil into useful products such as liquefied petroleum gas (LPG), gasoline or petrol, kerosene, jet fuel, diesel oil and fuel oils.

<span class="mw-page-title-main">Non-centrifugal cane sugar</span> Traditional raw sugar obtained by evaporating water from sugarcane juice

Non-centrifugal cane sugar (NCS) is the technical name given to traditional raw sugar obtained by evaporating water from sugarcane juice. NCS is internationally recognized as a discrete and unique product by the FAO since 1964 and by the World Customs Organization (WCO) since 2007. WCO defines NCS as "cane sugar obtained without centrifugation". It also states that "the product contains only natural anhedral micro-crystals, of irregular shape, not visible to the naked eye, which are surrounded by molasses' residues and other constituents of sugar cane". NCS is produced in most sugarcane-growing regions of the world, being known by many different names such as panela, jaggery, or gur. Some varieties of muscovado are non-centrifugal.

The sugar industry of the United States produces sugarcane and sugar beets, operates sugar refineries, and produces and markets refined sugars, sugar-sweetened goods, and other products. The United States is among the world's largest sugar producers. Unlike most other sugar producing countries, the United States has both large and well-developed sugarcane and sugar beet industries. Refined sugarcane, processed sugar beet, and high-fructose corn syrup are all commonly used in the U.S. as added sugars to sweeten food and beverages.

<span class="mw-page-title-main">Beet sugar factory</span> Manufacturing of sugar beet

A beet sugar factory or sugar factory, is a type of sugar production facility that produces sugar from sugar beet. Nowadays most sugar factories also act as a sugar refinery. The first beet sugar factory was founded in 1802.

References

  1. A HISTORY OF METALLURGY, 2nd edition, 1992, R. F. Tylecote, ISBN   1-902653-79-3, p.126
  2. Gary, J.H. & Handwerk, G.E. (1984). Petroleum Refining Technology and Economics (2nd ed.). Marcel Dekker, Inc. ISBN   0-8247-7150-8.
  3. Guide to Refining Archived 2006-08-08 at the Wayback Machine from Chevron Oil's website
  4. Refinery flowchart Archived 2006-06-28 at the Wayback Machine from Universal Oil Products' website
  5. An example flowchart Archived 2005-12-22 at the Wayback Machine of fractions from crude oil at a refinery
  6. Gunter Alfke, Walther W. Irion & Otto S. Neuwirth (2007). "Oil Refining". Ullmann's Encyclopedia of Industrial Chemistry. doi:10.1002/14356007.a18_051.pub2. ISBN   978-3527306732.
  7. Natural Gas Processing: The Crucial Link Between Natural Gas Production and Its Transportation to Market Archived 2011-03-04 at the Wayback Machine
  8. Example Gas Plant Flow Diagram
  9. From Purification to Liquefaction Gas Processing Archived 2010-01-15 at the Wayback Machine
  10. Feed-Gas Treatment Design for the Pearl GTL Project
  11. Benefits of integrating NGL extraction and LNG liquefaction
  12. Hubert Schiweck; Margaret Clarke; Günter Pollach (2007). "Sugar". Ullmann’s Encyclopedia of Industrial Chemistry. Weinheim: Wiley-VCH. doi:10.1002/14356007.a25_345.pub2. ISBN   978-3527306732.
  13. Shore, M.; Broughton, N.W.; Dutton, J.V.; Sissons, A. (1984). "Factors affecting white sugar colour" (PDF). Sugar Technology Reviews. 12: 1–99.