Carbonates on Mars

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Estimating carbon in the Nili Fossae plains region of Mars from orbiters (2 September 2015). PIA19816-Mars-EstimatingCarbon-Orbiters-20150902.jpg
Estimating carbon in the Nili Fossae plains region of Mars from orbiters (2 September 2015).

The formation of carbonates on Mars have been suggested based on evidence of the presence of liquid water and atmospheric carbon dioxide in the planet's early stages. [1] Moreover, due to their utility in registering changes in environmental conditions such as pH, temperature, fluid composition, [2] carbonates have been considered as a primary target for planetary scientists' research. [1] However, since their first detection in 2008, [3] the large deposits of carbonates that were one expected on Mars have not been found, [4] leading to multiple potential explanations that can explain why carbonates did not form massively on the planet.

Contents

Mars probes

Previously, most remote sensing instruments such as OMEGA and THEMIS—sensitive to infrared emissivity spectral features of carbonates—had not suggested the presence of carbonate outcrops, [5] at least at the 100 m or coarser spatial scales available from the returned data. [6]

Though ubiquitous, a 2003 study of carbonates on Mars showed that they are dominated by magnesite (MgCO3) in Martian dust, had mass fractions less than 5%, and could have formed under current atmospheric conditions. [7] Furthermore, with the exception of the surface dust component, by 2007 carbonates had not been detected by any in situ mission, even though mineralogic modeling did not preclude small amounts of calcium carbonate in Independence class rocks of Husband Hill in Gusev crater. [8] [9] (note: An IAU naming convention within Gusev is not yet established).

Remote sensing data

The first successful identification of a strong infrared spectral signature from surficial carbonate minerals of local scale (< 10 km2) was made by the MRO-CRISM team in 2008. [10] Spectral modeling in 2007 identified a key deposit in Nili Fossae dominated by a single mineral phase that was spatially associated with olivine outcrops. The dominant mineral appeared to be magnesite, while morphology inferred with HiRISE and thermal properties suggested that the deposit was lithic. Stratigraphically, this layer appeared between phyllosilicates below and mafic cap rocks above, temporally between the Noachian and Hesperian eras. Even though infrared spectra are representative of minerals to less than ≈0.1 mm depths [11] (in contrast to gamma spectra which are sensitive to tens of cm depths), [12] stratigraphic,[ clarification needed ] morphologic,[ clarification needed ] and thermal properties are consistent with the existence of the carbonate as outcrop rather than alteration rinds.[ clarification needed ] Nevertheless, the morphology was distinct from typical terrestrial sedimentary carbonate layers suggesting formation from local aqueous alteration of olivine and other igneous minerals. However, key implications were that the alteration would have occurred under moderate pH and that the resulting carbonates were not exposed to sustained low pH aqueous conditions even as recently as the Hesperian.

Evidence for widespread presence of carbonates began to increase in 2009, when low levels (<10%) of Mg-rich carbonates were found across the Martian area of Syrtis Major, Margaritifer Terra, Lunae Planum, Elysium Planitia, as reported from analysis of data acquired by the Planetary Fourier Spectrometer (PFS) on board the Mars Express spacecraft. [13]

when the Thermal and Evolved Gas Analyzer (TEGA) and WCL experiments on the 2009 Phoenix Mars lander found between 3–5wt% calcite (CaCO3) and an alkaline soil. [14] In 2010 analyses by the Mars Exploration Rover Spirit, identified outcrops rich in magnesium-iron carbonate (16–34 wt%) in the Columbia Hills of Gusev crater, most likely precipitated from carbonate-bearing solutions under hydrothermal conditions at near-neutral pH in association with volcanic activity during the Noachian era. [15]

After Spirit Rover stopped working scientists studied old data from the Miniature Thermal Emission Spectrometer, or Mini-TES and confirmed the presence of large amounts of carbonate-rich rocks, which means that regions of the planet may have once harbored water. The carbonates were discovered in an outcrop of rocks called "Comanche." [16] [15]

Carbonates (calcium or iron carbonates) were discovered in a crater on the rim of Huygens Crater, located in the Iapygia quadrangle. The impact on the rim exposed material that had been dug up from the impact that created Huygens. These minerals represent evidence that Mars once had a thicker carbon dioxide atmosphere with abundant moisture. These kind of carbonates only form when there is a lot of water. They were found with the Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) instrument on the Mars Reconnaissance Orbiter. Earlier, the instrument had detected clay minerals. The carbonates were found near the clay minerals. Both of these minerals form in wet environments. It is supposed that billions of years age Mars was much warmer and wetter. At that time, carbonates would have formed from water and the carbon dioxide-rich atmosphere. Later the deposits of carbonate would have been buried. The double impact has now exposed the minerals. Earth has vast carbonate deposits in the form of limestone. [17]

Carbonates found on Mars
NameMission
MgCO3magnesiteremote sensing, MRO-CRISM2008
MgCO3magnesiteremote sensing Mars Express-PFS2009
CaCO3calcitePhoenix2009
FeCO3sideriteCuriosity2020

Absence of Carbonates on Mars

Geological and geomorphological evidence has reinforced the idea of the presence of liquid water on early Mars. [4] [18] Therefore, abundant precipitation of carbonates from atmospheric and water reactions is expected. However, spectral imaging has revealed only small amounts of carbonates, generating doubts about humans' understanding of geological processes on Mars. [4] To overcome this problem, scientists have proposed explanations that reconcile the absence of carbonates with the presence of a CO2-rich atmosphere and liquid water.

Cold and Dry Early Mars Environments

According to this explanation, the early Martian conditions are similar to those at present. [19] Essentially, it suggests that carbonates are absent because the planet never experienced conditions that included the presence of liquid water and a CO2-rich thick atmosphere. Even if this explanation provides an insight in the reasons why carbonates are not present, it is in disagreement with the geomorphological and mineralogical evidence supporting the existence of liquid water on Mars' surface. [1] [4] [18]

Inability of Detection with Current Technology

This hypothesis establishes that the Thermal Emission Spectrometer (TES) aboard the Mars Global Surveyor spacecraft and the Thermal Emission Imaging System (THEMIS) on board the Mars Odyssey spacecraft are unable to detect carbonates. [20] According to this notion, the carbonates indeed formed and are still exist on Mars, but they remain undetected due to the limited sensitivity of the current tools used for mineralogical detection on the planet. [20]

Secondary Chemical Alteration

This concept involves the potential for secondary chemical alteration of ancient carbonates on Mars, due to the formation of acid rain [21] resulting from the combination of water vapor and sulfates. The consequence of this process implies the chemical decomposition of superficial carbonates layers, as carbonates are not resistant to acidic pH conditions; acid-fog weathering; and photo-decomposition. [22] [23]

Hidden Carbonate Deposits

According to this perspective, massive carbonates deposits formed but are hidden beneath several layers of secondary alteration rocks, preventing their identification on the surface. Other alternatives to this hypothesis include: Masking of carbonates as a consequence of the abundant soils on Mars; and resurfacing processes that have covered carbonate deposits, such as eolian deposition and late sedimentation processes. [24]

Inhibition due to Acidic Conditions

Finally, this hypothesis defends the idea that carbonates never precipitated because the pH conditions of the environment were too acidic to allow carbonates to precipitate, or at least siderite, which is the primary carbonate mineral expected to precipitate first. [25] The acidic conditions are derived from the high partial pressures of atmospheric carbon dioxide, as well as a persistent sulfate and iron enrichment that affect the optimal conditions for carbonates to precipitate. [4]

See also

Related Research Articles

<span class="mw-page-title-main">Gusev (Martian crater)</span> Crater on Mars

Gusev is a crater on the planet Mars and is located at 14.5°S 175.4°E and is in the Aeolis quadrangle. The crater is about 166 kilometers in diameter and formed approximately three to four billion years ago. It was named after Russian astronomer Matvey Gusev (1826–1866) in 1976.

<span class="mw-page-title-main">Meridiani Planum</span> Equatorial plain on Mars

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<span class="mw-page-title-main">Martian spherules</span> Small iron oxide spherules found on Mars

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<span class="mw-page-title-main">Scientific information from the Mars Exploration Rover mission</span>

NASA's 2003 Mars Exploration Rover Mission has amassed an enormous amount of scientific information related to the Martian geology and atmosphere, as well as providing some astronomical observations from Mars. This article covers information gathered by the Opportunity rover during the initial phase of its mission. Information on science gathered by Spirit can be found mostly in the Spirit rover article.

<span class="mw-page-title-main">Compact Reconnaissance Imaging Spectrometer for Mars</span> Visible-infrared spectrometer

The Compact Reconnaissance Imaging Spectrometer for Mars (CRISM) was a visible-infrared spectrometer aboard the Mars Reconnaissance Orbiter searching for mineralogic indications of past and present water on Mars. The CRISM instrument team comprised scientists from over ten universities and was led by principal investigator Scott Murchie. CRISM was designed, built, and tested by the Johns Hopkins University Applied Physics Laboratory.

<span class="mw-page-title-main">Isidis Planitia</span> Crater on Mars

Isidis Planitia is a plain located within a giant impact basin on Mars, located partly in the Syrtis Major quadrangle and partly in the Amenthes quadrangle. At approximately 1,900 km (1,200 mi) in diameter, it is the third-largest confirmed impact structure on the planet, after the Hellas and Utopia basins. Isidis was likely the last major basin to be formed on Mars, having formed approximately 3.9 billion years ago during the Noachian period. Due to dust coverage, it typically appears bright in telescopic views, and was mapped as a classical albedo feature, Isidis Regio, visible by telescope in the pre-spacecraft era.

<span class="mw-page-title-main">Aram Chaos</span> Crater on Mars

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<span class="mw-page-title-main">Mawrth Vallis</span> Valley on Mars

Mawrth Vallis is a valley on Mars, located in the Oxia Palus quadrangle at 22.3°N, 343.5°E with an elevation approximately two kilometers below datum. Situated between the southern highlands and northern lowlands, the valley is a channel formed by massive flooding which occurred in Mars’ ancient past. It is an ancient water outflow channel with light-colored clay-rich rocks.

<span class="mw-page-title-main">Jezero (crater)</span> Crater on Mars

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<span class="mw-page-title-main">Martian soil</span> Fine regolith found on the surface of Mars

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<span class="mw-page-title-main">Aeolis quadrangle</span> One of a series of 30 quadrangle maps of Mars

The Aeolis quadrangle is one of a series of 30 quadrangle maps of Mars used by the United States Geological Survey (USGS) Astrogeology Research Program. The Aeolis quadrangle is also referred to as MC-23 . The Aeolis quadrangle covers 180° to 225° W and 0° to 30° south on Mars, and contains parts of the regions Elysium Planitia and Terra Cimmeria. A small part of the Medusae Fossae Formation lies in this quadrangle.

<span class="mw-page-title-main">Water on Mars</span> Study of past and present water on Mars

Almost all water on Mars today exists as ice, though it also exists in small quantities as vapor in the atmosphere. What was thought to be low-volume liquid brines in shallow Martian soil, also called recurrent slope lineae, may be grains of flowing sand and dust slipping downhill to make dark streaks. While most water ice is buried, it is exposed at the surface across several locations on Mars. In the mid-latitudes, it is exposed by impact craters, steep scarps and gullies. Additionally, water ice is also visible at the surface at the north polar ice cap. Abundant water ice is also present beneath the permanent carbon dioxide ice cap at the Martian south pole. More than 5 million km3 of ice have been detected at or near the surface of Mars, enough to cover the whole planet to a depth of 35 meters (115 ft). Even more ice might be locked away in the deep subsurface. Some liquid water may occur transiently on the Martian surface today, but limited to traces of dissolved moisture from the atmosphere and thin films, which are challenging environments for known life. No evidence of present-day liquid water has been discovered on the planet's surface because under typical Martian conditions, warming water ice on the Martian surface would sublime at rates of up to 4 meters per year. Before about 3.8 billion years ago, Mars may have had a denser atmosphere and higher surface temperatures, potentially allowing greater amounts of liquid water on the surface, possibly including a large ocean that may have covered one-third of the planet. Water has also apparently flowed across the surface for short periods at various intervals more recently in Mars' history. Aeolis Palus in Gale Crater, explored by the Curiosity rover, is the geological remains of an ancient freshwater lake that could have been a hospitable environment for microbial life. The present-day inventory of water on Mars can be estimated from spacecraft images, remote sensing techniques, and surface investigations from landers and rovers. Geologic evidence of past water includes enormous outflow channels carved by floods, ancient river valley networks, deltas, and lakebeds; and the detection of rocks and minerals on the surface that could only have formed in liquid water. Numerous geomorphic features suggest the presence of ground ice (permafrost) and the movement of ice in glaciers, both in the recent past and present. Gullies and slope lineae along cliffs and crater walls suggest that flowing water continues to shape the surface of Mars, although to a far lesser degree than in the ancient past.

Mars may contain ores that would be very useful to potential colonists. The abundance of volcanic features together with widespread cratering are strong evidence for a variety of ores. While nothing may be found on Mars that would justify the high cost of transport to Earth, the more ores that future colonists can obtain from Mars, the easier it would be to build colonies there.

<span class="mw-page-title-main">Hesperian</span> Era of Mars geologic history

The Hesperian is a geologic system and time period on the planet Mars characterized by widespread volcanic activity and catastrophic flooding that carved immense outflow channels across the surface. The Hesperian is an intermediate and transitional period of Martian history. During the Hesperian, Mars changed from the wetter and perhaps warmer world of the Noachian to the dry, cold, and dusty planet seen today. The absolute age of the Hesperian Period is uncertain. The beginning of the period followed the end of the Late Heavy Bombardment and probably corresponds to the start of the lunar Late Imbrian period, around 3700 million years ago (Mya). The end of the Hesperian Period is much more uncertain and could range anywhere from 3200 to 2000 Mya, with 3000 Mya being frequently cited. The Hesperian Period is roughly coincident with the Earth's early Archean Eon.

<span class="mw-page-title-main">Groundwater on Mars</span> Water held in permeable ground

Rain and snow was a regular occurrence on Mars in the past; especially in the Noachian and early Hesperian epochs. Water was theorized to seep into the ground until it reached a formation that would not allow it to penetrate further. Water then accumulated forming a saturated layer. Deep aquifers may still exist.

<span class="mw-page-title-main">Composition of Mars</span> Branch of the geology of Mars

The composition of Mars covers the branch of the geology of Mars that describes the make-up of the planet Mars.

<span class="mw-page-title-main">Geological history of Mars</span> Physical evolution of the planet Mars

The geological history of Mars follows the physical evolution of Mars as substantiated by observations, indirect and direct measurements, and various inference techniques. Methods dating back to 17th-century techniques developed by Nicholas Steno, including the so-called law of superposition and stratigraphy, used to estimate the geological histories of Earth and the Moon, are being actively applied to the data available from several Martian observational and measurement resources. These include landers, orbiting platforms, Earth-based observations, and Martian meteorites.

<span class="mw-page-title-main">Lakes on Mars</span> Overview of the presence of lakes on Mars

In summer 1965, the first close-up images from Mars showed a cratered desert with no signs of water. However, over the decades, as more parts of the planet were imaged with better cameras on more sophisticated satellites, Mars showed evidence of past river valleys, lakes and present ice in glaciers and in the ground. It was discovered that the climate of Mars displays huge changes over geologic time because its axis is not stabilized by a large moon, as Earth's is. Also, some researchers maintain that surface liquid water could have existed for periods of time due to geothermal effects, chemical composition or asteroid impacts. This article describes some of the places that could have held large lakes.

<span class="mw-page-title-main">Northeast Syrtis</span>

Northeast Syrtis is a region of Mars once considered by NASA as a landing site for the Mars 2020 rover mission. This landing site failed in the competition with Jezero crater, another landing site dozens of kilometers away from Northeast Syrtis. It is located in the northern hemisphere of Mars at coordinates 18°N,77°E in the northeastern part of the Syrtis Major volcanic province, within the ring structure of Isidis impact basin as well. This region contains diverse morphological features and minerals, indicating that water once flowed here. It may be an ancient habitable environment; microbes could have developed and thrived here.

Janice Bishop is a planetary scientist known for her research into the minerals found on Mars.

References

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