Arylide yellow

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Arylide yellow
 
Gtk-dialog-info.svg    Color coordinates
Hex triplet #E9D66B
sRGB B (r, g, b)(233, 214, 107)
HSV (h, s, v)(51°, 54%, 91%)
CIELChuv (L, C, h)(85, 71, 76°)
Source
ISCC–NBS descriptor Brilliant greenish yellow
B: Normalized to [0–255] (byte)

Arylide yellow, also known as Hansa yellow and monoazo yellow, is a family of organic compounds used as pigments. They are primarily used as industrial colorants including plastics, building paints and inks. They are also used in artistic oil paints, acrylics and watercolors. These pigments are usually semi-transparent and range from orange-yellow to yellow-greens. Related organic pigments are the diarylide pigments. Overall, these pigments have partially displaced the toxic cadmium yellow in the marketplace. Painters such as Alexander Calder and Jackson Pollock are known to have employed arylide yellow in their artworks. [1]

Contents

Production

The compound is obtained by azo coupling of aniline and acetoacetanilide or their derivatives. The class of compounds was discovered in Germany in 1909. [2]

Synthesis of Hansa Yellow Pigments, R and R' represent a variety of substituents. HansaYellowPigmentsCorrected.png
Synthesis of Hansa Yellow Pigments, R and R' represent a variety of substituents.

Examples

Members of this class include:

Artists Pigments

Several monoazo yellows are used as artists' pigments, frequently marketed under the names 'Hansa' or Arylide. [3] These include:

See also

Related Research Articles

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<span class="mw-page-title-main">Pigment</span> Colored material

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<span class="mw-page-title-main">Aniline</span> Organic compound (C₆H₅NH₂); simplest aromatic amine

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<span class="mw-page-title-main">Nitration</span> Chemical reaction which adds a nitro (–NO₂) group onto a molecule

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<span class="mw-page-title-main">Azo compound</span> Organic compounds with a diazenyl group (–N=N–)

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<span class="mw-page-title-main">Diazonium compound</span> Group of organonitrogen compounds

Diazonium compounds or diazonium salts are a group of organic compounds sharing a common functional group [R−N+≡N]X where R can be any organic group, such as an alkyl or an aryl, and X is an inorganic or organic anion, such as a halide. The parent compound where R is hydrogen, is diazenylium.

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<span class="mw-page-title-main">1,4-Dichloro-2-nitrobenzene</span> Chemical compound

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<span class="mw-page-title-main">Synthetic colorant</span>

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References

  1. Arylide Yellow, Colourlex
  2. K. Hunger. W. Herbst "Pigments, Organic" in Ullmann's Encyclopedia of Industrial Chemistry, Wiley-VCH, Weinheim, 2012. doi : 10.1002/14356007.a20_371
  3. https://www.handprint.com/HP/WCL/pigmt1d.html#monoazo
  4. https://artistpigments.org/pigments/PY1
  5. https://artistpigments.org/pigments/PY2
  6. https://artistpigments.org/pigments/PY3
  7. https://artistpigments.org/pigments/PY4
  8. https://artistpigments.org/pigments/PY5
  9. https://artistpigments.org/pigments/PY6
  10. https://artistpigments.org/pigments/PY10
  11. https://artistpigments.org/pigments/PY60
  12. https://artistpigments.org/pigments/PY65
  13. https://artistpigments.org/pigments/PY74
  14. https://artistpigments.org/pigments/PY82
  15. https://artistpigments.org/pigments/PY97