Disulfur

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Disulfur
Ball and stick model of disulfur molecule Disulfur-2D-dimensions.png
Ball and stick model of disulfur molecule
Disulfur-3D-balls.png
Names
IUPAC name
Disulfur [1]
Systematic IUPAC name
Disulfene
Other names
Diatomic sulfur

Sulfur dimer

Disulphur
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
753
PubChem CID
  • InChI=1S/S2/c1-2 Yes check.svgY
    Key: MAHNFPMIPQKPPI-UHFFFAOYSA-N Yes check.svgY
  • S=S
Properties
S2
Molar mass 64.12 g·mol−1
0 D
Thermochemistry
32.51 kJ K−1 mol−1
Std molar
entropy (S⦵298)
228.17 J K−1 mol−1
128.60 kJ mol−1
Related compounds
Related compounds
 Triplet oxygen
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Disulfur is the diatomic molecule with the formula S2. [2] It is analogous to the dioxygen molecule but rarely occurs at room temperature. This violet gas is the dominant species in hot sulfur vapors. S2 is one of the minor components of the atmosphere of Io, which is predominantly composed of SO2. [3] The instability of S2 is usually described in the context of the double bond rule.

Contents

Synthesis

This violet gas is generated by heating sulfur above 720 °C, comprising 99% of the vapor at low pressure (1 mm Hg) at 530 °C.

Disulfur can be produced when an atmosphere of COS is irradiated with UV light using a mercury photosensitizer or when CS2, H2S2, S2Cl2 or C2H4S, PSF3 or COS are irradiated. [4]

Natural occurrence

Gaseous disulfur has been detected emanating from the surface of Jupiter's moon Io, from the vicinity of Pele volcano. [5]

Properties

The ground state of S2 is a triplet: a diradical, with two unpaired electrons like O2 and SO. [6] It has the S–S bond length of 189 pm, much shorter than the S–S single bonds in S8, which are 206 pm long. Its Raman spectrum consists of a band at 715 cm−1. [7] The corresponding O–O band for O2 is found at 1556 cm−1. [8] The S-S bond energy is 430 kJ/mol compared to 498 kJ/mol for O2. [9]

Singlet disulfur is believed to be the product of trisulfides with triphenylphosphine dibromide, or the thermal decomposition of dialkoxy disulfides. However, the disulfur produced in that reaction is believed singlet because it undergoes formal hetero-Diels–Alder cycloadditions, not because of any spectroscopic evidence. [10]

Triplet disulfur readily photodissociates, [11] with a mean lifespan of 7.5 min in sunlight. [12]

References

  1. ↑ ebi.ac.uk/chebi/searchId.do?chebiId=29387
  2. ↑ Steudel, Ralf; Eckert, Bodo (2003). "Solid Sulfur Allotropes". Elemental Sulfur and Sulfur-Rich Compounds I. Topics in Current Chemistry. Vol. 230. pp. 58–68. doi:10.1007/b12110. ISBN   978-3-540-40191-9.
  3. ↑ Lellouch, E. (January 2005). "Io's Atmosphere and Surface–Atmosphere Interactions". Space Science Reviews . 116 (1–2): 211–224. Bibcode:2005SSRv..116..211L. doi:10.1007/s11214-005-1957-z. S2CID   121867974.
  4. ↑ Tardif, Sylvie L.; Rys, Andrzej Z.; Abrams, Charles B.; Abu-Yousef, Imad A.; Lesté-Lasserre, Pierre B. F.; Schultz, Erwin K. V.; Harpp, David N. (1997). "Recent chemistry of the chalcogen diatomics". Tetrahedron . 53 (36): 12225–12236. doi:10.1016/S0040-4020(97)00555-3.
  5. ↑ Spencer, J. R. (2000). "Discovery of Gaseous S2 in Io's Pele Plume". Science. 288 (5469): 1208–1210. Bibcode:2000Sci...288.1208S. doi:10.1126/science.288.5469.1208. ISSN   0036-8075. PMID   10817990.
  6. ↑ Greenwood, N. N.; Earnshaw, A. (1986). Chemistry of the Elements. New York: Pergamon; as cited in Harpp, David N. (1997). "The sulfur diatomics". Phosphorus, Sulfur, and Silicon. 120. Amsterdam, NL: Gordon & Breach: 41. doi:10.1080/10426509708545509.
  7. ↑ Eckert, Bodo; Steudel, Ralf (2003). "Molecular Spectra of Sulfur Molecules and Solid Sulfur Allotropes". Elemental Sulfur and Sulfur-Rich Compounds II. Topics in Current Chemistry. Vol. 231. pp. 181–191. doi:10.1007/b13181. ISBN   978-3-540-40378-4.
  8. ↑ Hill, R.A.; Esherick, P.; Owyoung, A. (1983). "High-resolution stimulated Raman spectroscopy of O2". Journal of Molecular Spectroscopy. 100 (1): 119–133. Bibcode:1983JMoSp.100..119H. doi:10.1016/0022-2852(83)90029-2.
  9. ↑ (Lide, David R., ed. (2006). CRC Handbook of Chemistry and Physics (87th ed.). Boca Raton, Florida: CRC Press. ISBN   0-8493-0487-3.
  10. ↑ Makarov, Sergei V.; Makarova, Anna S.; Silaghi-Dumitrescu, Radu (2014). "Sulfoxylic and thiosulfurous acids and their dialkoxy derivatives". Peroxides. Chemistry of Functional Groups. Wiley. p. 297. doi:10.1002/9780470682531.pat0829. ISBN   978-0-470-68253-1.
  11. ↑ Frederix, Pim W. J. M.; Yang, Chung-Hsin; Groenenboom, Gerrit C.; Parker, David H.; Alnama, Koutayba; Western, Colin M.; Orr-Ewing, Andrew J. (2009). "Photodissociation Imaging of Diatomic Sulfur (S2)†". The Journal of Physical Chemistry A. 113 (52): 14995–15005. Bibcode:2009JPCA..11314995F. CiteSeerX   10.1.1.511.5087 . doi:10.1021/jp905104u. ISSN   1089-5639. PMID   19754091.
  12. ↑ Ahearn, M. F.; Schleicher, D. G.; Feldman, P. D. (1983). "The discovery of S2 in comet IRAS-Araki-Alcock 1983d". The Astrophysical Journal. 274: L99. Bibcode:1983ApJ...274L..99A. doi:10.1086/184158. ISSN   0004-637X.
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