Yuksporite

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Yuksporite
Yuksporite-3.jpg
Yuksporite from the Khibiny Massif, Kola Peninsula, Russia (4 cm across)
General
Category Inosilicates
Formula
(repeating unit)
see text
IMA symbol Yks [1]
Strunz classification 9.DG.95
Dana classification66.3.1.5
Crystal system Monoclinic
Crystal class Prismatic (2/m)
(same H-M symbol)
Space group P2/m
Identification
Formula mass 2,546.97 g/mol
ColorBrownish pink to rose-red to straw-yellow
Crystal habit Fibrous, scaly or lamellar
Mohs scale hardness4+12 to 5
Luster Vitreous, silky
Streak Nearly white to white
Diaphaneity Semitransparent
Specific gravity 3.05
Optical propertiesBiaxial
Refractive index nα = 1.644, nγ = 1.660
Pleochroism X pale rose-yellow, Y, Z rose-yellow
Other characteristicsBarely detectable radioactivity
References [2] [3] [4] [5] [6]

Yuksporite is a rare inosilicate mineral with double width, unbranched chains, and the complicated chemical formula K4(Ca,Na)14Sr2Mn(Ti,Nb)4(O,OH)4(Si6O17)2(Si2O7)3(H2O,OH)3. [6] It contains the relatively rare elements strontium, titanium and niobium, as well as the commoner metallic elements potassium, calcium, sodium and manganese. As with all silicates, it contains groups of linked silicon and oxygen atoms, as well as some associated water molecules.

Contents

Yuksporite is a member of the umbite group that has just two known members, umbite, K2ZrSi>3O9·H2O, and yuksporite. [3] It was first reported in 1922, from nepheline syenite occurrences in the Kola Peninsula, Russia, and named by Alexander Fersman for the locality, near Mount Yukspor. [7]

Unit cell

Yuksporite was originally thought to be orthorhombic, space group unknown. [2] [3] [5] In 2004, however, the structure was solved using synchrotron radiation and found to be monoclinic 2/m with space group P21/m. [4] [8] The monoclinic unit cell has two formula units per cell (Z = 2) [4] and side lengths a = 7.126 Å, b = 24.913 Å and c = 17.075 Å, with the angle β between the a and c axes equal to 101.89°. [8]

Appearance

The mineral is brownish pink, rose pink or yellowish in color, with a silky to vitreous luster and a nearly white streak. It occurs in semi-transparent fibrous, scaly or lamellar aggregates up to 10 cm across. [2]

Properties

Yuksporite is a biaxial mineral, but most authors do not specify whether it is (+) or (-); the Handbook of Mineralogy [5] gives it as (+). All agree, however, that the refractive indices are Nx = 1.644 and Nz = 1.660 (with Ny unspecified), which are larger than those for quartz, but similar to those for tourmaline. Yuksporite shows pleochroism, with X pale rose-yellow, and Y, Z rose-yellow. It has a hardness of 4+12 to 5, between fluorite and apatite, and specific gravity 3.05, similar to fluorite. It exhibits barely detectable radioactivity. [4]

Occurrence and associations

The type locality is the Hackman Valley, Yukspor Mt, Khibiny Massif, Murmanskaja Oblast', Northern Region, Russia, [3] and type material is conserved at the Fersman Mineralogical Museum, Academy of Sciences, Moscow, Russia, catalogue number 25847. [5] The only occurrences reported by Mindat.org are in Russia. At the Khibiny massif it occurs in veins in nepheline syenite associated with titanite, pectolite, astrophyllite, biotite and aegirine. [7] At the Murun Massif in the Sakha Republic it is associated with aegirine, kalsilite, potassic feldspar, titanite, lamprophyllite, wadeite and tausonite. [5]

Yuksporite from Russia Yuksporite Hydrous sodium potassium calcium barium titanium aluminum iron silicate Khibiny Massif Kola Peninsula Russia 1960 b.jpg
Yuksporite from Russia

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Eveslogite is a complex inosilicate mineral with a chemical formula (Ca,K,Na,Sr,Ba)
48
[(Ti,Nb,Fe,Mn)
12
(OH)
12
Si
48
O
144
](F,OH,Cl)
14
found on Mt. Eveslogchorr in Khibiny Mountains, on the Kola peninsula, Russia. It was named after the place it was found. This silicate mineral occurs as an anchimonomineral veinlet that cross-cuts poikilitic nepheline syenite. This mineral appears to resemble yuksporite, as it forms similar placated fine fibrous of approximately 0.05 to 0.005mm that aggregates outwardly. The color of eveslogite is yellow or rather light brown. In addition, it is a semitransparent mineral that has a white streak and a vitreous luster. Its crystal system is monoclinic and possesses a hardness (Mohs) of 5. This newly discovered mineral belongs to the astrophyllite group of minerals and contains structures that are composed of titanosilicate layers. Limited information about this mineral exists due to the few research studies carried out since its recent discovery.

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Feklichevite is a rare mineral of the eudialyte group with the formula Na11Ca9(Fe3+,Fe2+)2Zr3NbSi(Si3O9)2(Si9O27)2. The original formula was extended to show the presence of cyclic silicate groups and presence of silicon at the M4 site, according to the nomenclature of eudialyte group. When compared to other minerals of the group, feklichevite characterizes in the presence of ferric iron (thus similar to ikranite, mogovidite and fengchengite) and dominance of calcium at the N4 site. Calcium is ordered in the structure and is also present at the M1 site. Other iron-bearing minerals of the group are eudialyte, ferrokentbrooksite, georgbarsanovite, khomyakovite, labyrinthite, oneillite and rastsvetaevite, but they rather contain ferrous iron Feklichevite name honors Russian mineralogist and crystallographer, V. G. Feklichev.

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<span class="mw-page-title-main">Rastsvetaevite</span> Mineral of the eudialyte group

Rastsveatevite is a rare mineral of the eudialyte group with the chemical formula Na27K8Ca12Fe3Zr6Si4[Si3O9]4[Si9O27]4(O,OH,H2O)6Cl2. Its structure is modular. It is only the third member of the group after andrianovite and davinciite with essential (site-dominating) potassium. Potassium and sodium enter both N4 and M2 sites. The mineral is named after Russian crystallographer Ramiza K. Rastsvetaeva.

<span class="mw-page-title-main">Baratovite</span> Cyclosilicate mineral

Baratovite is a very rare cyclosilicate mineral named after Rauf Baratovich Baratov from Tajikistan. It was discovered in 1974 at Dara-Pioz glacier, Tajikistan, and was approved by the International Mineralogical Association only a year later in 1975. The glacier gives home to 133 valid species, and is the type locality of 33 minerals, one of which is baratovite.

References

  1. Warr, L.N. (2021). "IMA–CNMNC approved mineral symbols". Mineralogical Magazine. 85 (3): 291–320. Bibcode:2021MinM...85..291W. doi: 10.1180/mgm.2021.43 . S2CID   235729616.
  2. 1 2 3 Gaines et al (1997) Dana’s New Mineralogy Eighth Edition. Wiley
  3. 1 2 3 4 Yuksporite, Mindat.org , retrieved 8 August 2022
  4. 1 2 3 4 Barthelmy, David (2014). "Yuksporite Mineral Data". Webmineral.com. Retrieved 8 August 2022.
  5. 1 2 3 4 5 Anthony, John W.; Bideaux, Richard A.; Bladh, Kenneth W.; Nichols, Monte C. (2005). "Yuksporite" (PDF). Handbook of Mineralogy. Mineral Data Publishing. Retrieved 8 August 2022.
  6. 1 2 "IMA Mineral List with Database of Mineral Properties".
  7. 1 2 Schairer J F (1927). "New Mineral Names: summarising Fersman A E (1923) Transactions of the Northern Scientific and Economic Expedition (16) 16-73" (PDF). American Mineralogist. 12: 58.
  8. 1 2 Krivovichev, Yakovenchuk, Armbruster, Dobelin, Pattison, Weber and Depmeier (2004) American Mineralogist 89:1561