Cyphochilus is a genus of beetles with unusually bright white scales that cover the whole exoskeleton. Cyphochilus inhabit Southeast Asia. [1]
Probably the same etymology as the former Cyphochilus orchid: from the Greek kyphos meaning "bent" and cheilos meaning "lip", because of the reflexed lip. [2]
The whiteness of the scales is caused by a thin disordered photonic structure (≈7 μm) which scatters light of all wavelengths with the same efficiency, thus resulting in a white colouration. This is particularly interesting as the beetle's exoskeleton underneath the scales is black, meaning that the scattering events must be very efficient in order to achieve such high opacity. [3]
The white scales are composed of sclerotin, a modified form of the polymer chitin, and are whiter than paper or any artificial material produced as of 2022. That is they have a scattering mean free path shorter than any natural material thanks to the anisotropy in the spatial architecture of the fibres, which ensures a high packing efficiency whilst preventing optical crowding. [4]
The beetles are believed to have developed white coloration to camouflage themselves among white fungi. The chitin filaments are just a few micrometres thick – far thinner than a very fine sheet of paper. The elements are tightly packed, [5] scattering light efficiently, but still able to keep a degree of disorder in their shape. [6] It has been shown how this strategy is evolutionarily optimised to produce bright whiteness despite the low refractive index of sclerotin. [7]
Scientists have exploited the topology of the random network to fabricate materials of comparable performance for application as ultra-white paints and coatings. For instance, in 2018 Syurik et al. have developed a bioinspired PMMA-based material that scatters light efficiently and is flexible and switchable in appearance. [8]
Another recent example consists of the use of cellulose nanofibrils to fabricate ultra-white paper for cosmetics and coatings. [9] Or ceramic for tiles. [10]
In 2023 a durable alumina-based ceramic based on Cyphochilus achieved a solar reflectivity of 99.6%, a record high, along with infrared thermal emission of 96.5%. It tolerates ultraviolet light and increases water evaporation and withstands temperatures of over 1,000 °C. [11]
Finally, the researchers also say that the material can be easily mass produced, using common materials like alumina and a two-step process of phase inversion and sintering. And if white is too boring for some houses, the material can apparently be produced in other colors and patterns by adding extra layers.
Rayleigh scattering, named after the 19th-century British physicist Lord Rayleigh, is the predominantly elastic scattering of light, or other electromagnetic radiation, by particles with a size much smaller than the wavelength of the radiation. For light frequencies well below the resonance frequency of the scattering medium, the amount of scattering is inversely proportional to the fourth power of the wavelength, e.g., a blue color is scattered much more than a red color as light propagates through air.
Biomimetics or biomimicry is the emulation of the models, systems, and elements of nature for the purpose of solving complex human problems. The terms "biomimetics" and "biomimicry" are derived from Ancient Greek: βίος (bios), life, and μίμησις (mīmēsis), imitation, from μιμεῖσθαι (mīmeisthai), to imitate, from μῖμος (mimos), actor. A closely related field is bionics.
An exoskeleton is an external skeleton that both supports the body shape and protects the internal organs of an animal, in contrast to an internal endoskeleton which is enclosed under other soft tissues. Some large, hard protective exoskeletons are known as "shells".
Chitin (C8H13O5N)n ( KY-tin) is a long-chain polymer of N-acetylglucosamine, an amide derivative of glucose. Chitin is probably the second most abundant polysaccharide in nature (behind only cellulose); an estimated 1 billion tons of chitin are produced each year in the biosphere. It is a primary component of cell walls in fungi (especially filamentous and mushroom forming fungi), the exoskeletons of arthropods such as crustaceans and insects, the radulae, cephalopod beaks and gladii of molluscs and in some nematodes and diatoms. It is also synthesised by at least some fish and lissamphibians. Commercially, chitin is extracted from the shells of crabs, shrimps, shellfish and lobsters, which are major by-products of the seafood industry. The structure of chitin is comparable to cellulose, forming crystalline nanofibrils or whiskers. It is functionally comparable to the protein keratin. Chitin has proved useful for several medicinal, industrial and biotechnological purposes.
In the field of optics, transparency is the physical property of allowing light to pass through the material without appreciable scattering of light. On a macroscopic scale, the photons can be said to follow Snell's law. Translucency allows light to pass through, but does not necessarily follow Snell's law; the photons can be scattered at either of the two interfaces, or internally, where there is a change in index of refraction. In other words, a translucent material is made up of components with different indices of refraction. A transparent material is made up of components with a uniform index of refraction. Transparent materials appear clear, with the overall appearance of one color, or any combination leading up to a brilliant spectrum of every color. The opposite property of translucency is opacity. Other categories of visual appearance, related to the perception of regular or diffuse reflection and transmission of light, have been organized under the concept of cesia in an order system with three variables, including transparency, translucency and opacity among the involved aspects.
Soft matter or soft condensed matter is a subfield of condensed matter comprising a variety of physical systems that are deformed or structurally altered by thermal or mechanical stress of the magnitude of thermal fluctuations. These materials share an important common feature in that predominant physical behaviors occur at an energy scale comparable with room temperature thermal energy, and that entropy is considered the dominant factor. At these temperatures, quantum aspects are generally unimportant. Soft materials include liquids, colloids, polymers, foams, gels, granular materials, liquid crystals, flesh, and a number of biomaterials. When soft materials interact favorably with surfaces, they become squashed without an external compressive force. Pierre-Gilles de Gennes, who has been called the "founding father of soft matter," received the Nobel Prize in Physics in 1991 for discovering that methods developed for studying order phenomena in simple systems can be generalized to the more complex cases found in soft matter, in particular, to the behaviors of liquid crystals and polymers.
Chitosan is a linear polysaccharide composed of randomly distributed β-(1→4)-linked D-glucosamine and N-acetyl-D-glucosamine. It is made by treating the chitin shells of shrimp and other crustaceans with an alkaline substance, such as sodium hydroxide.
Dental porcelain is a dental material used by dental technicians to create biocompatible lifelike dental restorations, such as crowns, bridges, and veneers. Evidence suggests they are an effective material as they are biocompatible, aesthetic, insoluble and have a hardness of 7 on the Mohs scale. For certain dental prostheses, such as three-unit molars porcelain fused to metal or in complete porcelain group, zirconia-based restorations are recommended.
Molybdenum trioxide describes a family of inorganic compounds with the formula MoO3(H2O)n where n = 0, 1, 2. These compounds are produced on the largest scale of any molybdenum compound. The anhydrous oxide is a precursor to molybdenum metal, an important alloying agent. It is also an important industrial catalyst. It is a yellow solid, although impure samples can appear blue or green.
Anomalous diffusion is a diffusion process with a non-linear relationship between the mean squared displacement (MSD), , and time. This behavior is in stark contrast to Brownian motion, the typical diffusion process described by Einstein and Smoluchowski, where the MSD is linear in time.
Rhenium diboride (ReB2) is a synthetic superhard material. It was first synthesized in 1962 and re-emerged recently due to hopes of achieving high hardness comparable to that of diamond. The reported ultrahigh hardness has been questioned, although this is a matter of definition as in the initial test rhenium diboride was able to scratch diamond.
Bioceramics and bioglasses are ceramic materials that are biocompatible. Bioceramics are an important subset of biomaterials. Bioceramics range in biocompatibility from the ceramic oxides, which are inert in the body, to the other extreme of resorbable materials, which are eventually replaced by the body after they have assisted repair. Bioceramics are used in many types of medical procedures. Bioceramics are typically used as rigid materials in surgical implants, though some bioceramics are flexible. The ceramic materials used are not the same as porcelain type ceramic materials. Rather, bioceramics are closely related to either the body's own materials or are extremely durable metal oxides.
Mineralized tissues are biological tissues that incorporate minerals into soft matrices. Typically these tissues form a protective shield or structural support. Bone, mollusc shells, deep sea sponge Euplectella species, radiolarians, diatoms, antler bone, tendon, cartilage, tooth enamel and dentin are some examples of mineralized tissues.
Gastrophysa viridula, known as the green dock beetle, green dock leaf beetle or green sorrel beetle, is a species of beetle native to Europe.
Structural coloration in animals, and a few plants, is the production of colour by microscopically structured surfaces fine enough to interfere with visible light instead of pigments, although some structural coloration occurs in combination with pigments. For example, peacock tail feathers are pigmented brown, but their microscopic structure makes them also reflect blue, turquoise, and green light, and they are often iridescent.
Freeze-casting, also frequently referred to as ice-templating, or freeze alignment, is a technique that exploits the highly anisotropic solidification behavior of a solvent in a well-dispersed slurry to controllably template a directionally porous ceramic. By subjecting an aqueous slurry to a directional temperature gradient, ice crystals will nucleate on one side of the slurry and grow along the temperature gradient. The ice crystals will redistribute the suspended ceramic particles as they grow within the slurry, effectively templating the ceramic.
Robocasting is an additive manufacturing technique analogous to Direct Ink Writing and other extrusion-based 3D-printing techniques in which a filament of a paste-like material is extruded from a small nozzle while the nozzle is moved across a platform. The object is thus built by printing the required shape layer by layer. The technique was first developed in the United States in 1996 as a method to allow geometrically complex ceramic green bodies to be produced by additive manufacturing. In robocasting, a 3D CAD model is divided up into layers in a similar manner to other additive manufacturing techniques. The material is then extruded through a small nozzle as the nozzle's position is controlled, drawing out the shape of each layer of the CAD model. The material exits the nozzle in a liquid-like state but retains its shape immediately, exploiting the rheological property of shear thinning. It is distinct from fused deposition modelling as it does not rely on the solidification or drying to retain its shape after extrusion.
Bio-inspired photonics or bio-inspired optical materials are the application of biomimicry to the field of photonics. This differs slightly from biophotonics which is the study and manipulation of light to observe its interactions with biology. One area that inspiration may be drawn from is structural color, which allows color to appear as a result of the detailed material structure. Other inspiration can be drawn from both static and dynamic camouflage in animals like the chameleon or some cephalopods. Scientists have also been looking to recreate the ability to absorb light using molecules from various plants and microorganisms. Pulling from these heavily evolved constructs allows engineers to improve and optimize existing photonic technologies, whilst also solving existing problems within this field.
A nanolattice is a synthetic porous material consisting of nanometer-size members patterned into an ordered lattice structure, like a space frame. The nanolattice is a newly emerged material class that has been rapidly developed over the last decade. Nanolattices redefine the limits of the material property space. Despite being composed of 50-99% of air, nanolattices are very mechanically robust because they take advantage of size-dependent properties that we generally see in nanoparticles, nanowires, and thin films. The most typical mechanical properties of nanolattices include ultrahigh strength, damage tolerance, and high stiffness. Thus, nanolattices have a wide range of applications.
Silvia Vignolini is an Italian physicist who is Director of research at the Max Planck Institute of Colloids and Interfaces and Professor of Chemistry and Bio-materials in the Yusuf Hamied Department of Chemistry at the University of Cambridge. Her research investigates natural photonics structures, the self-assembly of cellulose and light propagation through complex structures. She was awarded the KINGFA young investigator award by the American Chemical Society and the Gibson-Fawcett Award in 2018.