Deuterated DMF

Deuterated DMF

Skeletal formula of deuterated DMF
Ball and stick model of deuterated DMF Spacefill model of deuterated DMF
Names
IUPAC name 1-Deuterio-N,N-bis(trideuteriomethyl)formamide[ citation needed ]
Other names Dimethylformamide-d7[ citation needed ] N,N-Dimethylformamide-d7[ citation needed ] Heptadeutero-N,N-dimethylformamide[ citation needed ]
Identifiers
CAS Number	4472-41-7  Y
3D model (JSmol)	Interactive image
Abbreviations	DMF-d7[ citation needed ]
Beilstein Reference	1908468
ChemSpider	70601  N
ECHA InfoCard	100.022.497
EC Number	224-745-8
PubChem CID	78225
UN number	2265
CompTox Dashboard (EPA)	DTXSID30196283
InChI InChI=1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3/i1D3,2D3,3D N Key: ZMXDDKWLCZADIW-YYWVXINBSA-N N
SMILES [2H]C(=O)N(C([2H])([2H])[2H])C([2H])([2H])[2H]
Properties
Chemical formula	C 32 H 7NO or C 3D 7NO
Molar mass	80.1369 g mol−1
Appearance	Colourless liquid
Density	1.03 g mL−1
Boiling point	153 °C (307 °F; 426 K)
Refractive index (nD)	1.428
Hazards
GHS labelling:
Pictograms
Signal word	Danger
Hazard statements	H312, H319, H332, H360
Precautionary statements	P280, P305+P351+P338, P308+P313
Flash point	58 °C (136 °F; 331 K)
Explosive limits	2.2–15.2%
Lethal dose or concentration (LD, LC):
LD50 (median dose)	2.8 g kg−1(oral, rat) 1.5–4.72 g kg−1(dermal, rabbit)
Related compounds
Related alkanamides	N-Methylformamide Dimethylformamide
Related compounds	N-Nitroso-N-methylurea ENU
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa). N  verify  (what is  YN ?) Infobox references

Deuterated dimethylformamide ((CD₃)₂NCOD), also known as deuterated DMF, is an isotopologue of DMF ((CH₃)₂NCOH) in which the hydrogen atom ("H") is replaced with a deuterium isotope ("D"). Deuterated DMF is a relatively uncommon solvent used in NMR spectroscopy. ^{[1] [2]}

References

1. Walker, Lynn M.; Wagner, Norman J. (1996-01-01). "SANS Analysis of the Molecular Order in Poly(γ-benzyl l -glutamate)/Deuterated Dimethylformamide (PBLG/d-DMF) under Shear and during Relaxation" . Macromolecules. 29 (6): 2298–2301. doi:10.1021/ma951127p. ISSN   0024-9297.
2. Kim, Ahran; Kim, Cheal (2019-05-14). "A hydrazono-quinoline-based chemosensor sensing In3+ and Zn2+via fluorescence turn-on and ClO−via color change in aqueous solution" . New Journal of Chemistry. 43 (19): 7320–7328. doi:10.1039/C9NJ00899C. ISSN   1369-9261. S2CID   132588760.