Deuterated THF

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Deuterated THF
Skeletal formula of deuterated THF Gedeutereerd THF.png
Skeletal formula of deuterated THF
Spacefill model of deuterated THF Tetrahydrofuran-3D-vdW.png
Spacefill model of deuterated THF
Tetrahydrofuran-3D-balls.png
Identifiers
3D model (JSmol)
111854
ChemSpider
ECHA InfoCard 100.015.363 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 216-898-4
PubChem CID
UN number 2056
  • InChI=1S/C4H8O/c1-2-4-5-3-1/h1-4H2/i1D2,2D2,3D2,4D2 Yes check.svgY
    Key: WYURNTSHIVDZCO-SVYQBANQSA-N Yes check.svgY
  • [2H]C1([2H])OC([2H])([2H])C([2H])([2H])C1([2H])[2H]
Properties
C
4
D
8
O
Molar mass 80.1550 g mol−1
AppearanceColourless liquid
Density 985 mg cm−3
Melting point −106 °C (−159 °F; 167 K)
Boiling point 65 to 66 °C (149 to 151 °F; 338 to 339 K)
Hazards
GHS labelling:
GHS-pictogram-flamme.svg GHS-pictogram-exclam.svg
Danger
H225, H319, H335
P210, P261, P305+P351+P338
NFPA 704 (fire diamond)
NFPA 704.svgHealth 2: Intense or continued but not chronic exposure could cause temporary incapacitation or possible residual injury. E.g. chloroformFlammability 3: Liquids and solids that can be ignited under almost all ambient temperature conditions. Flash point between 23 and 38 °C (73 and 100 °F). E.g. gasolineInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
2
3
0
Flash point −17 °C (1 °F; 256 K)
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Yes check.svgY  verify  (what is  Yes check.svgYX mark.svgN ?)

Deuterated tetrahydrofuran (d8-THF) is a colourless, organic liquid at standard temperature and pressure. [1] This heterocyclic compound has the chemical formula C4D8O, and is an isotopologue of tetrahydrofuran. [2] Deuterated THF is used as a solvent in NMR spectroscopy, though its expense can often be prohibitive.[ citation needed ]

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References

  1. Andersson, O.; Suga, H. (1996-01-01). "Thermal conductivity of normal and deuterated tetrahydrofuran clathrate hydrates". Journal of Physics and Chemistry of Solids. 57 (1): 125–132. doi:10.1016/0022-3697(95)00157-3. ISSN   0022-3697.
  2. David, W. I. F.; Ibberson, R. M. (1992-02-15). "A reinvestigation of the structure of tetrahydrofuran by high-resolution neutron powder diffraction". Acta Crystallographica Section C: Crystal Structure Communications. 48 (2): 301–303. doi:10.1107/S0108270191008582. ISSN   0108-2701.