Linda Nazar

Last updated
Linda Nazar

FRS
Born
Linda Faye Nazar
Alma mater University of British Columbia
University of Toronto
Awards Chemical Institute of Canada Medal
Scientific career
Institutions University of Waterloo
Exxon Research and Engineering Company
Doctoral advisor Geoffrey Ozin
Notable students Kathryn Toghill
Website Nazar Group Lab

Linda Faye Nazar OC FRSC FRS is a Senior Canada Research Chair in Solid State Materials and Distinguished Research Professor of Chemistry at the University of Waterloo. She develops materials for electrochemical energy storage and conversion. Nazar demonstrated that interwoven composites could be used to improve the energy density of lithium–sulphur batteries. She was awarded the 2019 Chemical Institute of Canada Medal.

Contents

Early life and education

Nazar studied chemistry at the University of British Columbia, where she earned a bachelor's degree in 1978. [1] She was inspired to study chemistry after being inspired by her first year professor. [2] Her father had trained as a scientist and ran his own jewellery making business. [2] Nazar joined the University of Toronto for her graduate studies, and completed a PhD under the supervision of Geoffrey Ozin in 1984. After obtaining her degree, she worked as a postdoctoral researcher working with Allan Jacobson at Exxon Research and Engineering Company, [3] before joining the University of Waterloo in the late 1980s, when she became interested in electrochemistry and Inorganic chemistry. [2]

Research and career

Nazar works in materials chemistry at the University of Waterloo, where she designs energy storage devices and electrochemical systems. Her research group create new materials and nanostructures for lithium–sulfur batteries, including interwoven composites. She develops structural probes to understand how the morphology of materials that are capable of charge/ ionic redox processes impact their functions. These techniques include nuclear magnetic resonance (NMR), electrochemistry, AC Impedance Spectroscopy and X-ray diffraction measurements. [4] [5] Nazar was a founding member of the Waterloo Institute for Nanotechnology. [3] Nazar is recognised as being a "leading authority in advanced materials". [6] She was awarded a Canada Research Chair in 2004, which was renewed in 2008 and 2012. [7] [8] [9] In 2009 Nazar joined the California Institute of Technology as a More Distinguished Scholar. [3] [10] In 2013 she was awarded a $1.8 million fellowship from the National Research Council to investigate energy storage materials for automotive applications. [11]

Nazar is particularly interested in storage materials that go beyond lithium-ion batteries, sodium-ion batteries, zinc ion batteries and magnesium-ion batteries. [12] [13] [14] [15] Lithium-ion batteries are the battery of choice in hybrid electric vehicles, but concerns have arisen about the global supply of lithium. Her early work developed porous carbon architectures as frameworks for cathodes, enhancing their conductivity and discharge capacity. [16] She demonstrated that interwoven carbon composites could be used to improve the energy density of lithium–sulphur batteries. [4] She showed it was possible to create mesoporous carbon frameworks that constrain the grown of sulphur nanofillers, which improved energy storage and reversibility. [16]

Nazar calculated the low-cost lithium–sulphur batteries could take electric cars twice as far as current lithium-ion technologies. [2] Sulphur is an abundant material that can be used to replace cobalt oxide in lithium-ion batteries. [17] Unfortunately, sulphur can dissolve into the electrolyte solution, and be reduced by electrons to form polysulphides. [18] They are also susceptible to high internal resistance and capacity fading on cycling. [17] These challenges can be overcome by creating nanostructures in the electrodes. [17] Interwoven composites can also be made from manganese dioxide, which stabilise polysuplphides in lithium–sulphur batteries. [18] Manganese dioxide reduces sulphides via a surface-bound polythiosulphanates, and can withstand 2,000 discharge cycles without the loss of capacitance. [2] [18] [19] She has also developed lithium oxygen batteries, which are lightweight with high energy density. [20] [21] In lithium oxygen batteries, superoxide and peroxide can act to degrade the cells; limiting their lifetime. [21] If the electrolyte is replaced with a molten salt and the porous cathode with a bifunctional metal oxide, the peroxide does not form. [21] Nazar has worked on supercapacitors and polyanion materials. [22] [23]

She was made a Professor at the University of Waterloo in 2016 and holds a Tier 1 Canada Research Chair in Solid State Energy Materials. [24] Since 2014 Nazar has served on the board of directors of the International Meeting on Li-Batteries. [25] She serves on the editorial boards of the journals Angewandte Chemie, Energy & Environmental Science and the Journal of Materials Chemistry A. [26] [27]

Awards and honours

Her awards and honours include;

Patents

Nazar's patents include;

Related Research Articles

<span class="mw-page-title-main">Electrode</span> Electrical conductor used to make contact with nonmetallic parts of a circuit

An electrode is an electrical conductor used to make contact with a nonmetallic part of a circuit. Electrodes are essential parts of batteries that can consist of a variety of materials depending on the type of battery.

<span class="mw-page-title-main">Lithium-ion battery</span> Rechargeable battery type

A lithium-ion or Li-ion battery is a type of rechargeable battery which uses the reversible reduction of lithium ions to store energy. The anode of a conventional lithium-ion cell is typically graphite made from carbon. The cathode is typically a metal oxide. The electrolyte is typically a lithium salt in an organic solvent.

<span class="mw-page-title-main">M. Stanley Whittingham</span> British-American chemist

Michael Stanley Whittingham is a British-American chemist. He is currently a professor of chemistry and director of both the Institute for Materials Research and the Materials Science and Engineering program at Binghamton University, State University of New York. He also serves as director of the Northeastern Center for Chemical Energy Storage (NECCES) of the U.S. Department of Energy at Binghamton. He was awarded the Nobel Prize in Chemistry in 2019 alongside Akira Yoshino and John B. Goodenough.

<span class="mw-page-title-main">Nanobatteries</span> Type of battery

Nanobatteries are fabricated batteries employing technology at the nanoscale, particles that measure less than 100 nanometers or 10−7 meters. These batteries may be nano in size or may use nanotechnology in a macro scale battery. Nanoscale batteries can be combined to function as a macrobattery such as within a nanopore battery.

<span class="mw-page-title-main">Lithium iron phosphate</span> Chemical compound

Lithium iron phosphate or lithium ferro-phosphate (LFP) is an inorganic compound with the formula LiFePO
4
. It is a gray, red-grey, brown or black solid that is insoluble in water. The material has attracted attention as a component of lithium iron phosphate batteries, a type of Li-ion battery. This battery chemistry is targeted for use in power tools, electric vehicles, solar energy installations and more recently large grid-scale energy storage.

<span class="mw-page-title-main">Lithium-ion capacitor</span> Hybrid type of capacitor

A lithium-ion capacitor is a hybrid type of capacitor classified as a type of supercapacitor. It is called a hybrid because the anode is the same as those used in lithium-ion batteries and the cathode is the same as those used in supercapacitors. Activated carbon is typically used as the cathode. The anode of the LIC consists of carbon material which is often pre-doped with lithium ions. This pre-doping process lowers the potential of the anode and allows a relatively high output voltage compared to other supercapacitors.

<span class="mw-page-title-main">Lithium–sulfur battery</span> Type of rechargeable battery

The lithium–sulfur battery is a type of rechargeable battery. It is notable for its high specific energy. The low atomic weight of lithium and moderate atomic weight of sulfur means that Li–S batteries are relatively light. They were used on the longest and highest-altitude unmanned solar-powered aeroplane flight by Zephyr 6 in August 2008.

The lithium–air battery (Li–air) is a metal–air electrochemical cell or battery chemistry that uses oxidation of lithium at the anode and reduction of oxygen at the cathode to induce a current flow.

A potassium-ion battery or K-ion battery is a type of battery and analogue to lithium-ion batteries, using potassium ions for charge transfer instead of lithium ions. It was invented by the Iranian/American chemist Ali Eftekhari in 2004.

A lithium ion manganese oxide battery (LMO) is a lithium-ion cell that uses manganese dioxide, MnO
2
, as the cathode material. They function through the same intercalation/de-intercalation mechanism as other commercialized secondary battery technologies, such as LiCoO
2
. Cathodes based on manganese-oxide components are earth-abundant, inexpensive, non-toxic, and provide better thermal stability.

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Magnesium batteries are batteries that utilize magnesium cations as the active charge transporting agents in solution and often as the elemental anode of an electrochemical cell. Both non-rechargeable primary cell and rechargeable secondary cell chemistries have been investigated. Magnesium primary cell batteries have been commercialised and have found use as reserve and general use batteries.

A zinc-ion battery or Zn-ion battery (abbreviated as ZIB) uses zinc ions (Zn2+) as the charge carriers. Specifically, ZIBs utilize Zn as the anode, Zn-intercalating materials as the cathode, and a Zn-containing electrolyte. Generally, the term zinc-ion battery is reserved for rechargeable (secondary) batteries, which are sometimes also referred to as rechargeable zinc metal batteries (RZMB). Thus, ZIBs are different than non-rechargeable (primary) batteries which use zinc, such as alkaline or zinc–carbon batteries.

Debra R. Rolison is a physical chemist at the Naval Research Laboratory, where she is a head of the Advanced Electrochemical Materials section. Rolison's research involves the design, synthesis, and characterization of multi-functional nanostructures and ultra porous materials for rate-critical applications such as catalysis and energy storage. She is the 112th recipient of the William H. Nichols Medal Award.

Structural batteries are multifunctional materials or structures, capable of acting as an electrochemical energy storage system while possessing mechanical integrity.

Calcium (ion) batteries are energy storage and delivery technologies (i.e., electro–chemical energy storage) that employ calcium ions (cations), Ca2+, as the active charge carrier in the electrolytes as well as in the electrodes (anode and cathode). Calcium (ion) batteries remain an active area of research, with studies and work persisting in the discovery and development of electrodes and electrolytes that enable stable, long-term battery operation.

Arumugam Manthiram is an American materials scientist and engineer, best known for his identification of the polyanion class of lithium ion battery cathodes, understanding of how chemical instability limits the capacity of layered oxide cathodes, and technological advances in lithium sulfur batteries. He is a Cockrell Family Regents Chair in engineering, Director of the Texas Materials Institute, the Director of the Materials Science and Engineering Program at the University of Texas at Austin, and a former lecturer of Madurai Kamaraj University. Manthiram delivered the 2019 Nobel Lecture in Chemistry on behalf of Chemistry Laureate John B. Goodenough.

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References

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