Nonene

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Nonene is an alkene with the molecular formula C9H18. Many structural isomers are possible, depending on the location of the C=C double bond and the branching of the other parts of the molecule. Industrially, the most important nonenes are trimers of propene: Tripropylene. This mixture of branched nonenes is used in the alkylation of phenol to produce nonylphenol, a precursor to detergents, which are also controversial pollutants. [1]

Linear nonenes

Linear Nonene
Name 1-Nonene 2-Nonene 3-Nonene 4-Nonene
Systematic nameNon-1-eneNon-2-eneNon-3-eneNon-4-ene
Structure Non-1-ene 200.svg Cis-Non-2-ene structure.svg
Trans-Non-2-ene structure.svg
Cis-Non-3-ene structure.svg
Trans-Non-3-ene structure.svg
Cis-Non-4-ene structure.svg
Trans-Non-4-ene structure.svg
CAS Number 124-11-8
  • 2216-38-8
  • 6434-77-1 (cis)
  • 6434-78-2 (trans)
  • 125146-82-9
  • 20237-46-1 (cis)
  • 20063-77-8 (trans)
  • 2198-23-4
  • 10405-84-2 (cis)
  • 10405-85-3 (trans)
27215-95-8 (all isomers)
PubChem CID 31285 from PubChem CID 33744 from PubChem CID 88350 from PubChem CID 94226 from PubChem
Chemical formula C9H18
Molecular weight 126.24 g·mol−1
Melting point −81 °C [2]
Boiling point 147 °C [2] 144–145 °C [3] 147 °C [4]
Density 0,73 g·cm−3 (20 °C) [2] 0,734 g·cm−3 (25 °C) [3] 0,734 g·cm−3 (25 °C) [5] 0,73 g·cm−3 [4]
GHS hazard pictograms GHS-pictogram-flamme.svg GHS-pictogram-silhouette.svg GHS-pictogram-exclam.svg [2] GHS-pictogram-flamme.svg [3] GHS-pictogram-flamme.svg [5] GHS-pictogram-flamme.svg GHS-pictogram-silhouette.svg [4]
GHS hazard statements H226, H304, H315, H319, H335H226H226H226, H304
P261, P301+P310, P305+P351+P338, P331P210, P233, P240, P241, P242, P243, P280, P301, P310
P303+P361+P353, P331, P370+P378, P403+P235, P405, P501

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References

  1. Helmut Fiege, Heinz-Werner Voges, Toshikazu Hamamoto, Sumio Umemura, Tadao Iwata, Hisaya Miki, Yasuhiro Fujita, Hans-Josef Buysch, Dorothea Garbe, Wilfried Paulus "Phenol Derivatives" in Ullmann's Encyclopedia of Industrial Chemistry 2002, Wiley-VCH, Weinheim.doi : 10.1002/14356007.a19_313.
  2. 1 2 3 4 Record of 1-Nonen in the GESTIS Substance Database of the Institute for Occupational Safety and Health , accessed on 1 February 2016.
  3. 1 2 3 Sigma-Aldrich Co. , trans-2-Nonen, 99% . Retrieved on 2 June 2017.
  4. 1 2 3 Entry from 4-Nonene (cis- and trans-mixture) from TCI Europe, retrieved on 2 June 2017
  5. 1 2 Sigma-Aldrich Co. , trans-3-Nonene, 99% . Retrieved on 2 June 2017.