Peroxynitrate

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Peroxynitrate
Peroxynitrate.svg
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
PubChem CID
  • InChI=1S/HNO4/c2-1(3)5-4/h4H/p-1
    Key: UUZZMWZGAZGXSF-UHFFFAOYSA-M
  • [N+](=O)([O-])O[O-]
Properties
NO4
Molar mass 78.004 g·mol−1
Related compounds
Related compounds
peroxycarbonate; peroxysulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Peroxynitrate (or peroxonitrate) refers to salts of the unstable peroxynitric acid, HNO4. Peroxynitrate is unstable and decomposes to nitrate and dioxygen. [1]

No solid peroxynitrate salts are known. [2] However, there is a report that the chemist Sebastian Moiseevich Tanatar produced sodium peroxynitrate octahydrate (NaNO3·H2O2·8H2O) by evaporating a solution of sodium nitrate and hydrogen peroxide until crystallisation begins and then mixing with alcohol to form crystals of the octahydrate. [3]

Related Research Articles

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<span class="mw-page-title-main">Silver nitrate</span> Chemical compound

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3
. It is a versatile precursor to many other silver compounds, such as those used in photography. It is far less sensitive to light than the halides. It was once called lunar caustic because silver was called luna by ancient alchemists who associated silver with the moon. In solid silver nitrate, the silver ions are three-coordinated in a trigonal planar arrangement.

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<span class="mw-page-title-main">Barium hydroxide</span> Chemical compound

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<span class="mw-page-title-main">Barium nitrate</span> Chemical compound

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<span class="mw-page-title-main">Sodium peroxide</span> Chemical compound

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<span class="mw-page-title-main">Sodium perchlorate</span> Chemical compound

Sodium perchlorate is an inorganic compound with the chemical formula NaClO4. It consists of sodium cations Na+ and perchlorate anions ClO−4. It is a white crystalline, hygroscopic solid that is highly soluble in water and ethanol. It is usually encountered as sodium perchlorate monohydrate NaClO4·H2O. The compound is noteworthy as the most water-soluble of the common perchlorate salts.

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Sodium monothiophosphate, or sodium phosphorothioate, is an inorganic compound with the chemical formula Na3PO3S. It is a sodium salt of monothiophosphoric acid (H3PO3S). Sodium monothiophosphate forms hydrates Na3PO3xH2O. The anhydrous form and all hydrates are white solids. The anhydrous salt (x = 0) (Na3PO3S) decomposes without melting at 120-125 °C. More common is the dodecahydrate (Na3PO3S·12H2O). A nonahydrate is also known (Na3PO3S·9H2O).

<span class="mw-page-title-main">Bromous acid</span> Chemical compound

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<span class="mw-page-title-main">Nitrate radical</span> Chemical compound

Nitrogen trioxide or nitrate radical is an oxide of nitrogen with formula NO
3
, consisting of three oxygen atoms covalently bound to a nitrogen atom. This highly unstable blue compound has not been isolated in pure form, but can be generated and observed as a short-lived component of gas, liquid, or solid systems.

<span class="mw-page-title-main">Lead compounds</span> Type of compound

Compounds of lead exist with lead in two main oxidation states: +2 and +4. The former is more common. Inorganic lead(IV) compounds are typically strong oxidants or exist only in highly acidic solutions.

<span class="mw-page-title-main">Cerium(III) sulfate</span> Chemical compound

Cerium(III) sulfate, also called cerous sulfate, is an inorganic compound with the formula Ce2(SO4)3. It is one of the few salts whose solubility in water decreases with rising temperature.

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<span class="mw-page-title-main">Thorium(IV) nitrate</span> Chemical compound

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

<span class="mw-page-title-main">Trichloronitrosomethane</span> Chemical compound

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<span class="mw-page-title-main">Neodymium compounds</span> Chemical compounds with at least one neodymium atom

Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.

References

  1. Miyamoto, Sayuri; Ronsein, Graziella E.; Corrêa, Thaís C.; Martinez, Glaucia R.; Medeiros, Marisa H. G.; Di Mascio, Paolo (2009). "Direct evidence of singlet molecular oxygen generation from peroxynitrate, a decomposition product of peroxynitrite". Dalton Transactions (29): 5720–5729. doi:10.1039/b905560f. ISSN   1477-9226. PMID   20449086.
  2. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8.
  3. Mellor, Joseph William (1922). A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Volume 2. New York: Longmans, Green and Co. p. 816.