Peroxynitrate

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Peroxynitrate
Peroxynitrate.svg
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
PubChem CID
  • InChI=1S/HNO4/c2-1(3)5-4/h4H/p-1
    Key: UUZZMWZGAZGXSF-UHFFFAOYSA-M
  • [N+](=O)([O-])O[O-]
Properties
NO4
Molar mass 78.004 g·mol−1
Related compounds
Related compounds
peroxycarbonate; peroxysulfate
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Peroxynitrate (or peroxonitrate) refers to salts of the unstable peroxynitric acid, HNO4. Peroxynitrate is unstable and decomposes to nitrate and dioxygen. [1]

No solid peroxynitrate salts are known. [2] However, there is a report that the chemist Sebastian Moiseevich Tanatar produced sodium peroxynitrate octahydrate (NaNO3·H2O2·8H2O) by evaporating a solution of sodium nitrate and hydrogen peroxide until crystallisation begins and then mixing with alcohol to form crystals of the octahydrate. [3]

Related Research Articles

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Nitrogen is a chemical element; it has symbol N and atomic number 7. Nitrogen is a nonmetal and the lightest member of group 15 of the periodic table, often called the pnictogens. It is a common element in the universe, estimated at seventh in total abundance in the Milky Way and the Solar System. At standard temperature and pressure, two atoms of the element bond to form N2, a colourless and odourless diatomic gas. N2 forms about 78% of Earth's atmosphere, making it the most abundant chemical species in air. Because of the volatility of nitrogen compounds, nitrogen is relatively rare in the solid parts of the Earth.

<span class="mw-page-title-main">Nitrate</span> Polyatomic ion (NO₃, charge –1) found in explosives and fertilisers

Nitrate is a polyatomic ion with the chemical formula NO
3
. Salts containing this ion are called nitrates. Nitrates are common components of fertilizers and explosives. Almost all inorganic nitrates are soluble in water. An example of an insoluble nitrate is bismuth oxynitrate.

In chemistry, perxenates are salts of the yellow xenon-containing anion XeO4−
6
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<span class="mw-page-title-main">Barium hydroxide</span> Chemical compound

Barium hydroxide is a chemical compound with the chemical formula Ba(OH)2. The monohydrate (x = 1), known as baryta or baryta-water, is one of the principal compounds of barium. This white granular monohydrate is the usual commercial form.

<span class="mw-page-title-main">Barium nitrate</span> Chemical compound

Barium nitrate is the inorganic compound with the chemical formula Ba(NO3)2. It, like most barium salts, is colorless, toxic, and water-soluble. It burns with a green flame and is an oxidizer; the compound is commonly used in pyrotechnics.

<span class="mw-page-title-main">Sodium peroxide</span> Chemical compound

Sodium peroxide is an inorganic compound with the formula Na2O2. This yellowish solid is the product of sodium ignited in excess oxygen. It is a strong base. This metal peroxide exists in several hydrates and peroxyhydrates including Na2O2·2H2O2·4H2O, Na2O2·2H2O, Na2O2·2H2O2, and Na2O2·8H2O. The octahydrate, which is simple to prepare, is white, in contrast to the anhydrous material.

<span class="mw-page-title-main">Sodium perchlorate</span> Chemical compound

Sodium perchlorate is an inorganic compound with the chemical formula NaClO4. It consists of sodium cations Na+ and perchlorate anions ClO−4. It is a white crystalline, hygroscopic solid that is highly soluble in water and ethanol. It is usually encountered as sodium perchlorate monohydrate NaClO4·H2O. The compound is noteworthy as the most water-soluble of the common perchlorate salts.

<span class="mw-page-title-main">Ferrate(VI)</span> Ion

Ferrate(VI) is the inorganic anion with the chemical formula [FeO4]2−. It is photosensitive, contributes a pale violet colour to compounds and solutions containing it and is one of the strongest water-stable oxidizing species known. Although it is classified as a weak base, concentrated solutions containing ferrate(VI) are corrosive and attack the skin and are only stable at high pH. It is similar to the somewhat more stable permanganate.

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<span class="mw-page-title-main">Molten salt</span> Salt that has melted, often by heating to high temperatures

Molten salt is salt which is solid at standard temperature and pressure but liquified due to elevated temperature. A salt that is liquid even at standard temperature and pressure is usually called a room-temperature ionic liquid, and molten salts are technically a class of ionic liquids.

<span class="mw-page-title-main">Sodium monothiophosphate</span> Chemical compound

Sodium monothiophosphate, or sodium phosphorothioate, is an inorganic compound with the chemical formula Na3PO3S. It is a sodium salt of monothiophosphoric acid (H3PO3S). Sodium monothiophosphate forms hydrates Na3PO3xH2O. The anhydrous form and all hydrates are white solids. The anhydrous salt (x = 0) (Na3PO3S) decomposes without melting at 120-125 °C. More common is the dodecahydrate (Na3PO3S·12H2O). A nonahydrate is also known (Na3PO3S·9H2O).

<span class="mw-page-title-main">Lead compounds</span> Type of compound

Compounds of lead exist with lead in two main oxidation states: +2 and +4. The former is more common. Inorganic lead(IV) compounds are typically strong oxidants or exist only in highly acidic solutions.

<span class="mw-page-title-main">Peroxynitric acid</span> Chemical compound

Peroxynitric acid or peroxonitric acid is a chemical compound with the formula HNO
4
. It is an oxyacid of nitrogen, after peroxynitrous acid.

<span class="mw-page-title-main">Cerium(III) sulfate</span> Chemical compound

Cerium(III) sulfate, also called cerous sulfate, is an inorganic compound with the formula Ce2(SO4)3. It is one of the few salts whose solubility in water decreases with rising temperature.

Tetranitratoborate is an anion composed of boron with four nitrate groups. It has formula [B(NO3)4]. It can form salts with large cations such as tetramethylammonium nitratoborate, or tetraethylammonium tetranitratoborate. The ion was first discovered by C. R. Guibert and M. D. Marshall in 1966 after failed attempts to make neutral (non-ionic) boron nitrate, B(NO3)3, which has resisted attempts to make it; if it exists, it is unstable above −78 °C.

<span class="mw-page-title-main">Thorium(IV) nitrate</span> Chemical compound

Thorium(IV) nitrate is a chemical compound, a salt of thorium and nitric acid with the formula Th(NO3)4. A white solid in its anhydrous form, it can form tetra- and pentahydrates. As a salt of thorium it is weakly radioactive.

<span class="mw-page-title-main">Nitroxylic acid</span> Chemical compound

Nitroxylic acid or hydronitrous acid is an unstable reduced oxonitrogen acid. It has formula H4N2O4 containing nitrogen in the +2 oxidation state. It consists of a central pair of bonded nitrogen atoms with four hydroxyl groups around them, giving rise to hydrazine-1,1,2,2-tetrol as an alternate chemical name.

<span class="mw-page-title-main">Trichloronitrosomethane</span> Chemical compound

Trichloronitrosomethane is a chlorinated nitrosoalkane. It is a deep blue liquid with powerful lachrymatory effects.

<span class="mw-page-title-main">Neodymium compounds</span> Chemical compounds with at least one neodymium atom

Neodymium compounds are compounds formed by the lanthanide metal neodymium (Nd). In these compounds, neodymium generally exhibits the +3 oxidation state, such as NdCl3, Nd2(SO4)3 and Nd(CH3COO)3. Compounds with neodymium in the +2 oxidation state are also known, such as NdCl2 and NdI2. Some neodymium compounds have colors that vary based upon the type of lighting.

References

  1. Miyamoto, Sayuri; Ronsein, Graziella E.; Corrêa, Thaís C.; Martinez, Glaucia R.; Medeiros, Marisa H. G.; Di Mascio, Paolo (2009). "Direct evidence of singlet molecular oxygen generation from peroxynitrate, a decomposition product of peroxynitrite". Dalton Transactions (29): 5720–5729. doi:10.1039/b905560f. ISSN   1477-9226. PMID   20449086.
  2. Greenwood, Norman N.; Earnshaw, Alan (1997). Chemistry of the Elements (2nd ed.). Butterworth-Heinemann. ISBN   978-0-08-037941-8.
  3. Mellor, Joseph William (1922). A Comprehensive Treatise on Inorganic and Theoretical Chemistry, Volume 2. New York: Longmans, Green and Co. p. 816.