Polymetallic ores or multimetal ores are complex ores containing a number of chemical elements, among which the most important are lead and zinc. In addition, polymetallic ores can contain copper, gold, silver, cadmium, sometimes bismuth, tin, indium and gallium. [1] The main minerals that form polymetallic ores are galena, sphalerite, to a lesser extent pyrite, chalcopyrite, arsenopyrite, cassiterite. [1] [2] They are most commonly formed from sulfides but also include oxides. [1] [3]
The three main families of sulfide polymetallic ores are identified as volcanogenic massive sulphide family, the sedimentary exhalative family, and the Mississippi Valley type family. The classification of lead-zinc deposits in particular has been varied and resulted in a number of different organizations schemes. [1] The term "polymetallic ore" also includes nodules, principally Manganese nodules, that do not form as terrestrial deposits but as concretions on the ocean floor. [3] [4]
Rocks containing polymetallic ores are often altered or formed by hydrothermal processes — chloritization, sericitization and silicification. [5] [6] These deposits are often iron hydroxides containing cerussite PbCO3, anglesite PbSO4, smithsonite ZnCO3, calamine Zn4[Si2O7] [OH]2×H2O, malachite Cu2[CO3](OH)2, azurite Cu3[CO3]2(OH)2. Depending on the concentration of ore minerals, a distinction is made between solid or disseminated ores. Ore bodies of polymetallic ores are distinguished by a variety of sizes (having a length of several m to km), morphology (lenticular bedding deposits, [7] stockwork, veins, [8] nests, complex tube-like bodies) and occurrence conditions (gentle, steep, consonant, secant, etc.). [9]