(2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA synthase

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(2,2,3-Trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA synthase
Identifiers
EC no. 6.2.1.38
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(2,2,3-Trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA synthase (EC 6.2.1.38, 2-oxo-Delta3-4,5,5-trimethylcyclopentenylacetyl-CoA synthetase) is an enzyme with systematic name ((1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetate:CoA ligase (AMP-forming). [1] This enzyme catalyses the following chemical reaction

[(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetate + ATP + CoA AMP + diphosphate + [(1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl]acetyl-CoA

This enzyme is isolated from Pseudomonas putida .

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(2,2,3-Trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA 1,5-monooxygenase (EC 1.14.13.160, 2-oxo-Delta3-4,5,5-trimethylcyclopentenylacetyl-CoA monooxygenase, 2-oxo-Delta3-4,5,5-trimethylcyclopentenylacetyl-CoA 1,2-monooxygenase, OTEMO) is an enzyme with systematic name ((1R)-2,2,3-trimethyl-5-oxocyclopent-3-enyl)acetyl-CoA,NADPH:oxygen oxidoreductase (1,5-lactonizing). This enzyme catalyses the following chemical reaction

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References

  1. Ougham HJ, Taylor DG, Trudgill PW (January 1983). "Camphor revisited: involvement of a unique monooxygenase in metabolism of 2-oxo-Δ3-4,5,5-trimethylcyclopentenylacetic acid by Pseudomonas putida". Journal of Bacteriology. 153 (1): 140–52. PMC   217351 . PMID   6848481.