All-trans-decaprenyl-diphosphate synthase

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All-trans-decaprenyl-diphosphate synthase
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EC no. 2.5.1.91
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All-trans-decaprenyl-diphosphate synthase (EC 2.5.1.91, decaprenyl-diphosphate synthase, decaprenyl pyrophosphate synthetase, polyprenylpyrophosphate synthetase, terpenoidallyltransferase, terpenyl pyrophosphate synthetase, trans-prenyltransferase) is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate:isopentenyl-diphosphate farnesyltranstransferase (adding 7 isopentenyl units). [1] This enzyme catalyses the following chemical reaction

(2E,6E)-farnesyl diphosphate + 7 isopentenyl diphosphate 7 diphosphate + all-trans-decaprenyl diphosphate

This enzyme catalyses the condensation reactions resulting in the formation of all-trans-decaprenyl diphosphate.

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<span class="mw-page-title-main">All-trans-octaprenyl-diphosphate synthase</span> Class of enzymes

All-trans-octaprenyl-diphosphate synthase is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate:isopentenyl-diphosphate farnesyltranstransferase . This enzyme catalyses the following chemical reaction

(2Z,6Z)-farnesyl diphosphate synthase is an enzyme with systematic name dimethylallyl-diphosphate:isopentenyl-diphosphate cistransferase . This enzyme catalyses the following chemical reaction

(+)-Epicubenol synthase (EC 4.2.3.64, farnesyl pyrophosphate cyclase) is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate diphosphate-lyase ((+)-epicubenol-forming). This enzyme catalyses the following chemical reaction

Patchoulol synthase (EC 4.2.3.70) is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate diphosphate-lyase (patchoulol-forming). This enzyme catalyses the following chemical reaction

Valencene synthase is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate diphosphate-lyase (valencene-forming). It is a terpene cyclase enzyme responsible for the biosynthesis of valencene, a sesquiterpene, using farnesyl pyrophosphate as its substrate. The first such enzyme was isolated using orange cDNA. This enzyme catalyses the following chemical reaction

Cubebol synthase (EC 4.2.3.91, Cop4) is an enzyme with systematic name (2E,6E)-farnesyl-diphosphate diphosphate-lyase (cyclizing, cubebol-forming). This enzyme catalyses the following chemical reaction

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References

  1. ↑ Saiki R, Nagata A, Kainou T, Matsuda H, Kawamukai M (November 2005). "Characterization of solanesyl and decaprenyl diphosphate synthases in mice and humans". The FEBS Journal. 272 (21): 5606–22. doi: 10.1111/j.1742-4658.2005.04956.x . PMID   16262699.
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