A hydrogen infrastructure is the infrastructure of hydrogen pipeline transport, points of hydrogen production and hydrogen stations for distribution as well as the sale of hydrogen fuel, [1] and thus a crucial prerequisite before a successful commercialization of fuel cell technology. [2]
The hydrogen infrastructure would consist mainly of industrial hydrogen pipeline transport and hydrogen-equipped filling stations. Hydrogen stations which were not situated near a hydrogen pipeline would get supply via hydrogen tanks, compressed hydrogen tube trailers, liquid hydrogen trailers, liquid hydrogen tank trucks or dedicated onsite production.
Pipelines are the cheapest way to move hydrogen over long distances compared to other options. Hydrogen gas piping is routine in large oil-refineries, because hydrogen is used to hydrocrack fuels from crude oil. The IEA recommends existing industrial ports be used for production and existing natural gas pipelines for transport: also international co-operation and shipping. [3]
South Korea and Japan, [4] which as of 2019 lack international electrical interconnectors, are investing in the hydrogen economy. [5] In March 2020, the Fukushima Hydrogen Energy Research Field was opened in Japan, claiming to be the world's largest hydrogen production facility. [6] Much of the site is occupied by a solar array; power from the grid is also used for electrolysis of water to produce hydrogen fuel. [7]
A hydrogen highway is a chain of hydrogen-equipped filling stations and other infrastructure along a road or highway which allow hydrogen vehicles to travel.
Hydrogen stations which are not situated near a hydrogen pipeline get supply via hydrogen tanks, compressed hydrogen tube trailers, liquid hydrogen trailers, liquid hydrogen tank trucks or dedicated onsite production. Some firms as ITM Power are also providing solutions to make your own hydrogen (for use in the car) at home. [8] Government supported activities to expand an hydrogen fuel infrastructure are ongoing in the US state of California, in some member states of the European Union (most notably in Germany [2] ) and in particular in Japan.
Hydrogen pipeline transport is a transportation of hydrogen through a pipe as part of the hydrogen infrastructure. Hydrogen pipeline transport is used to connect the point of hydrogen production or delivery of hydrogen with the point of demand, pipeline transport costs are similar to CNG, [9] the technology is proven, [10] however most hydrogen is produced on the place of demand with every 50 to 100 miles (80 to 161 km) an industrial production facility. [11] As of 2004 [update] , there are 900 miles (1,448 km) of low pressure hydrogen pipelines in the US and 930 miles (1,497 km) in Europe.
According to a 2024 research report, the United States has 1,600 miles (2,570 kilometers) of hydrogen pipelines; the global total stands at 2,800 miles (4,500 kilometers). [12] The World Economic Forum, in December 2023, estimated that Europe had approximately 1,600 kilometers of hydrogen pipelines. [13]
Hydrogen embrittlement (a reduction in the ductility of a metal due to absorbed hydrogen) is not a problem for hydrogen gas pipelines. Hydrogen embrittlement only happens with 'diffusible' hydrogen, i.e. atoms or ions. Hydrogen gas, however, is molecular (H2), and there is a very significant energy barrier to splitting it into atoms. [14]
The National Renewable Energy Laboratory believes that US counties have the potential to produce more renewable hydrogen for fuel cell vehicles than the gasoline they consumed in 2002. [15]
As an energy buffer, hydrogen produced via water electrolysis and in combination with underground hydrogen storage or other large-scale storage technologies, could play an important role for the introduction of fluctuating renewable energy sources like wind or solar power. [2]
98% of hydrogen production uses the steam reforming method. [16] Methods such as electrolysis of water are also used. [17] The world's largest facility for producing electrolytic hydrogen fuel is claimed [18] to be the Fukushima Hydrogen Energy Research Field (FH2R), a 10MW-class hydrogen production unit, inaugurated on 7 March 2020, in Namie, Fukushima Prefecture. [19] The site occupies 180,000 square meters of land, much of which is occupied by a solar array; but power from the grid is also used to conduct electrolysis of water to produce hydrogen fuel. [18]
Hydrogen pipeline transport is a transportation of hydrogen through a pipe as part of the hydrogen infrastructure.
Hydrogen pipeline transport is used to transport hydrogen from the point of production or delivery to the point of demand. Although hydrogen pipeline transport is technologically mature, [24] [25] and the transport costs are similar to those of CNG, [26] most hydrogen is produced in the place of demand, with an industrial production facility every 50 to 100 miles (80 to 161 km) [27]
For process metal piping at pressures up to 7,000 psi (48 MPa), high-purity stainless steel piping with a maximum hardness of 80 HRB is preferred. [28] This is because higher hardnesses are associated with lower fracture toughness so stronger, higher hardness steel is less safe.
Composite pipes are assessed like:
Fiber-Reinforced Polymer pipelines (or FRP pipeline) and reinforced thermoplastic pipes are researched. [29] [30] [31] [32]
Carrying hydrogen in steel pipelines (grades: API5L-X42 and X52; up to 1,000psi/7,000kPa, constant pressure/low pressure cycling) does not lead to hydrogen embrittlement. [33] Hydrogen is typically stored in steel cylinders without problems. Coal gas (also known as town gas) is 50% hydrogen and was carried in cast-iron pipes for half a century without any embrittlement issues.
A hydrogen highway is a chain of hydrogen-equipped public filling stations, along a road or highway, that allows hydrogen powered cars to travel. [34] William Clay Ford Jr. has stated that infrastructure is one of three factors (also including costs and manufacturability in high volumes) that hold back the marketability of fuel cell cars.
Hydrogen fueling stations generally receive deliveries of hydrogen by tanker truck from hydrogen suppliers. [35] An interruption at a hydrogen supply facility can shut down multiple hydrogen fueling stations. [36] A hydrogen fueling station costs between $1 million and $4 million to build. [37]
As of 2019, 98% of hydrogen is produced by steam methane reforming, which emits carbon dioxide. [16] The bulk of hydrogen is also transported in trucks, so pollution is emitted in its transportation. [35]
A hydrogen station is a storage or filling station for hydrogen fuel. [38] The hydrogen is dispensed by weight. [39] [40] There are two filling pressures in common use: H70 or 700 bar, and the older standard H35 or 350 bar. [41] As of 2021 [update] , around 550 filling stations were available worldwide. [41] According to H2stations.org by Ludwig-Bölkow-Systemtechnik (LBST), as of the end of 2023, there were 921 hydrogen refueling stations globally, [42] although this number clearly conflicts with those published by AFDC. [43] The distribution of these stations is highly uneven, with a concentration in East Asia, particularly in China, Japan and South Korea; Central Europe and California in the United States. Other regions have very few, if any, hydrogen refuelling stations. [42] [43]
Hydrogen fueling stations can be divided into off-site stations, where hydrogen is delivered by truck or pipeline, and on-site stations that produce and compress hydrogen for the vehicles. [44] [45]
Home hydrogen fueling stations are available to consumers. [46] A model that can produce 12 kilograms of hydrogen per day sells for $325,000. [47]
Solar powered water electrolysing hydrogen home stations are composed of solar cells, power converter, water purifier, electrolyzer, piping, hydrogen purifier, [48] oxygen purifier, compressor, [49] pressure vessels [50] and a hydrogen outlet. [51]
Hydrogen fuel is hazardous because of its low ignition energy, high combustion energy, and because it easily leaks from tanks. [52] Explosions at hydrogen filling stations have been reported. [53]
Hydrogen fuelling stations generally receive deliveries by truck from hydrogen suppliers. An interruption at a hydrogen supply facility can shut down multiple hydrogen fuelling stations due to an interruption of the supply of hydrogen. [54]
There are far fewer Hydrogen filling stations than gasoline fuel stations, which in the US alone numbered 168,000 in 2004. [55] Replacing the US gasoline infrastructure with hydrogen fuel infrastructure is estimated to cost a half trillion U.S. dollars. [56] A hydrogen fueling station costs between $1 million and $4 million to build. [57] In comparison, battery electric vehicles can charge at home or at public chargers. As of 2023, there are more than 60,000 public charging stations in the United States, with more than 160,000 outlets. [43] A public Level 2 charger, which comprise the majority of public chargers in the US, costs about $2,000, and DC fast chargers, of which there are more than 30,000 in the U.S., [43] generally cost between $100,000 and $250,000, [58] although Tesla superchargers are estimated to cost approximately $43,000. [59]
During refueling, the flow of cold hydrogen can cause frost to form on the dispenser nozzle, sometimes leading to the nozzle becoming frozen to the vehicle being refueled. [60]
Consulting firm Ludwig-Bölkow-Systemtechnik tracks global hydrogen filling stations and publishes a map. [61]
In 2019, there were 178 publicly available hydrogen fuel stations in operation. [62]
As of May 2023 [update] , there are 167 publicly available hydrogen fuel stations in operation in Japan. [63] [64] In 2012 there were 17 hydrogen stations, [65] and in 2021, there were 137 publicly available hydrogen fuel stations in Japan. [41]
By the end of 2023, China had built 354 hydrogen refueling stations. [66]
In 2019, there were 33 publicly available hydrogen fuel stations in operation in South Korea. [62] [67] In November 2023, however, due to hydrogen supply problems and broken stations, most fueling stations in South Korea offered no hydrogen. [68] 41 out of the 159 hydrogen stations in the country were listed as open, and some of these were rationing supplies of hydrogen. [69]
In 2019, there were 177 stations in Europe. [62] [70] [71] According to H2stations.org by Ludwig-Bölkow-Systemtechnik (LBST), there were 265 hydrogen refuelling stations in Europe by the end of 2023. [42]
As of June 2023, [update] there were 105 hydrogen fuel stations in Germany, [42] As of June 2023, [update] there were 5 publicly available hydrogen fuel stations in France, [70] 3 publicly available hydrogen fuel stations in Iceland, [70] one publicly available hydrogen fuel station in Italy, [70] 4 publicly available hydrogen fuel stations in The Netherlands, [70] 2 publicly available hydrogen fuel stations in Belgium, [70] 4 publicly available hydrogen fuel stations in Sweden, [70] 3 publicly available hydrogen fuel stations in Switzerland [70] and 6 publicly available hydrogen fuel stations in Denmark. [70] Everfuel, the only operator of hydrogen stations in Denmark, announced in 2023 the closure of all of its public hydrogen stations in the country. [72] [73]
As of June 2021, [update] there were 2 publicly available hydrogen fuel stations in Norway, both in the Oslo area. [74] Since the explosion at the hydrogen filling station in Sandvika in June 2019, the sale of hydrogen cars in Norway has halted. [75] In 2023, Everfuel announced the closure of its two public hydrogen stations in Norway and cancelled the opening of a third. [72] In 2024 Shell discontinued its hydrogen fuel projects in Norway. [76]
As of June 2020, [update] there were 11 publicly available hydrogen fuel stations in the United Kingdom, [70] but as of 2023, the number decreased to 5. [77] In 2022, Shell closed its three hydrogen stations in the UK, [78]
As of July 2023, there were 10 fueling stations in Canada, 9 of which were open to the public:
As of July 2024 [update] , there were 54 publicly accessible hydrogen refueling stations in the US, 53 of which were located in California, with one in Hawaii. [43]
In 2021, the first Australian publicly available hydrogen fuel station opened in Canberra, operated by ActewAGL. [88]
A hydrogen tank (other names- cartridge or canister) is used for hydrogen storage. [89] [90] [91] The first type IV hydrogen tanks for compressed hydrogen at 700 bars (70 MPa; 10,000 psi) were demonstrated in 2001, the first fuel cell vehicles on the road with type IV tanks are the Toyota FCHV, Mercedes-Benz F-Cell and the GM HydroGen4.
Various applications have allowed the development of different H2 storage scenarios. Recently, the Hy-Can [92] consortium has introduced a small one liter, 10 bars (1.0 MPa; 150 psi) format. Horizon Fuel Cells is now selling a refillable 3 megapascals (30 bar; 440 psi) metal hydride form factor for consumer use called HydroStik. [93]
In accordance with ISO/TS 15869 (revised):
This specification was replaced by ISO 13985:2006 and only applies to liquid hydrogen tanks.
Actual Standard EC 79/2009
Using magnesium [100] for hydrogen storage, a safe but weighty reversible storage technology. Typically the pressure requirement are limited to 10 bars (1.0 MPa; 150 psi). The charging process generates heat whereas the discharge process will require some heat to release the H2 contained in the storage material. To activate these types of hydrides, at the current state of development you need to reach approximately 300 °C (572 °F). [101] [102] [103]
See also sodium aluminium hydride
A fuel cell is an electrochemical cell that converts the chemical energy of a fuel and an oxidizing agent into electricity through a pair of redox reactions. Fuel cells are different from most batteries in requiring a continuous source of fuel and oxygen to sustain the chemical reaction, whereas in a battery the chemical energy usually comes from substances that are already present in the battery. Fuel cells can produce electricity continuously for as long as fuel and oxygen are supplied.
A compressed-air car is a compressed-air vehicle powered by pressure vessels filled with compressed air. It is propelled by the release and expansion of the air within a motor adapted to compressed air. The car might be powered solely by air, or combined with other fuels such as gasoline, diesel, or an electric plant with regenerative braking.
A hydrogen vehicle is a vehicle that uses hydrogen to move. Hydrogen vehicles include some road vehicles, rail vehicles, space rockets, forklifts, ships and aircraft. Motive power is generated by converting the chemical energy of hydrogen to mechanical energy, either by reacting hydrogen with oxygen in a fuel cell to power electric motors or, less commonly, by hydrogen internal combustion.
Compressed natural gas (CNG) is a fuel gas mainly composed of methane (CH4), compressed to less than 1% of the volume it occupies at standard atmospheric pressure. It is stored and distributed in hard containers at a pressure of 20–25 megapascals (2,900–3,600 psi; 200–250 atm), usually in cylindrical or spherical shapes.
The hydrogen economy is an umbrella term for the roles hydrogen can play alongside low-carbon electricity to reduce emissions of greenhouse gases. The aim is to reduce emissions where cheaper and more energy-efficient clean solutions are not available. In this context, hydrogen economy encompasses the production of hydrogen and the use of hydrogen in ways that contribute to phasing-out fossil fuels and limiting climate change.
A natural gas vehicle (NGV) utilizes compressed natural gas (CNG) or liquefied natural gas (LNG) as an alternative fuel source. Distinguished from autogas vehicles fueled by liquefied petroleum gas (LPG), NGVs rely on methane combustion, resulting in cleaner emissions due to the removal of contaminants from the natural gas source.
A fuel cell vehicle (FCV) or fuel cell electric vehicle (FCEV) is an electric vehicle that uses a fuel cell, sometimes in combination with a small battery or supercapacitor, to power its onboard electric motor. Fuel cells in vehicles generate electricity generally using oxygen from the air and compressed hydrogen. Most fuel cell vehicles are classified as zero-emissions vehicles. As compared with internal combustion vehicles, hydrogen vehicles centralize pollutants at the site of the hydrogen production, where hydrogen is typically derived from reformed natural gas. Transporting and storing hydrogen may also create pollutants. Fuel cells have been used in various kinds of vehicles including forklifts, especially in indoor applications where their clean emissions are important to air quality, and in space applications. Fuel cells are being developed and tested in trucks, buses, boats, ships, motorcycles and bicycles, among other kinds of vehicles.
The methanol economy is a suggested future economy in which methanol and dimethyl ether replace fossil fuels as a means of energy storage, ground transportation fuel, and raw material for synthetic hydrocarbons and their products. It offers an alternative to the proposed hydrogen economy or ethanol economy, although these concepts are not exclusive. Methanol can be produced from a variety of sources including fossil fuels as well as agricultural products and municipal waste, wood and varied biomass. It can also be made from chemical recycling of carbon dioxide.
Several methods exist for storing hydrogen. These include mechanical approaches such as using high pressures and low temperatures, or employing chemical compounds that release H2 upon demand. While large amounts of hydrogen are produced by various industries, it is mostly consumed at the site of production, notably for the synthesis of ammonia. For many years hydrogen has been stored as compressed gas or cryogenic liquid, and transported as such in cylinders, tubes, and cryogenic tanks for use in industry or as propellant in space programs. The overarching challenge is the very low boiling point of H2: it boils around 20.268 K (−252.882 °C or −423.188 °F). Achieving such low temperatures requires expending significant energy.
Hydrogen technologies are technologies that relate to the production and use of hydrogen as a part hydrogen economy. Hydrogen technologies are applicable for many uses.
A nickel–hydrogen battery (NiH2 or Ni–H2) is a rechargeable electrochemical power source based on nickel and hydrogen. It differs from a nickel–metal hydride (NiMH) battery by the use of hydrogen in gaseous form, stored in a pressurized cell at up to 1200 psi (82.7 bar) pressure. The nickel–hydrogen battery was patented in the United States on February 25, 1971 by Alexandr Ilich Kloss, Vyacheslav Mikhailovic Sergeev and Boris Ioselevich Tsenter from the Soviet Union.
Hydrogen tube trailers are semi-trailers that consist of 4 to 36 cluster high-pressure hydrogen tanks varying in length from 20 feet (6.10 m) for small tubes to 53 feet (16.15 m) on jumbo tube trailers. They are part of the hydrogen highway and usually precede a local hydrogen station.
A fuel cell bus is a bus that uses a hydrogen fuel cell as its power source for electrically driven wheels, sometimes augmented in a hybrid fashion with batteries or a supercapacitor. The only emission from the bus is water. Several cities around the world have trialled and tested fuel cell buses, with over 5,600 buses in use worldwide, the majority of which are in China.
Hydrogen safety covers the safe production, handling and use of hydrogen, particularly hydrogen gas fuel and liquid hydrogen. Hydrogen possesses the NFPA 704's highest rating of four on the flammability scale because it is flammable when mixed even in small amounts with ordinary air. Ignition can occur at a volumetric ratio of hydrogen to air as low as 4% due to the oxygen in the air and the simplicity and chemical properties of the reaction. However, hydrogen has no rating for innate hazard for reactivity or toxicity. The storage and use of hydrogen poses unique challenges due to its ease of leaking as a gaseous fuel, low-energy ignition, wide range of combustible fuel-air mixtures, buoyancy, and its ability to embrittle metals that must be accounted for to ensure safe operation.
High-pressure electrolysis (HPE) is the electrolysis of water by decomposition of water (H2O) into oxygen (O2) and hydrogen gas (H2) due to the passing of an electric current through the water. The difference with a standard proton exchange membrane (PEM) electrolyzer is the compressed hydrogen output around 12–20 megapascals (120–200 bar) at 70 °C. By pressurising the hydrogen in the electrolyser the need for an external hydrogen compressor is eliminated, the average energy consumption for internal differential pressure compression is around 3%.
Compressed hydrogen (CH2, CGH2 or CGH2) is the gaseous state of the element hydrogen kept under pressure. Compressed hydrogen in hydrogen tanks at 350 bar (5,000 psi) and 700 bar (10,000 psi) is used for mobile hydrogen storage in hydrogen vehicles. It is used as a fuel gas.
ITM Power plc is an energy storage and clean fuel company founded in the UK in 2001. It designs, manufactures, and integrates electrolysers based on proton exchange membrane (PEM) technology to produce green hydrogen using renewable electricity and tap water. Hydrogen produced via electrolysis is used for mobility, Power-to-X, and industry.
Power-to-gas is a technology that uses electric power to produce a gaseous fuel.
Nel ASA is a Norwegian company founded in 1927 and based in Oslo. Nel is a global company providing solutions for the production, storage and distribution of hydrogen from renewable energy sources. Nel is listed in the OBX Index of the Oslo Stock Exchange. As of March 2020, the largest shareholder is Clearstream Banking S.A. with a stake of 44.81%.
The NamX HUV is a hydrogen-powered coupe SUV from the Afro-European startup company NamX. It was designed by French designer Thomas de Lussac, and Italian car design firm Pininfarina.