Mass concrete

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Mass concrete is defined by American Concrete Institute Committee 207 as "any volume of concrete with dimensions large enough to require that measures be taken to cope with the generation of heat from hydration of cement and attendant volume change to minimize cracking." [1]

As interior temperature of mass concrete rises due to the process of cement hydration, the outer concrete may be cooling and contracting. If the temperature differs too much within the structure, the material can crack. The main factors influencing temperature variation in the mass concrete structure are: the size of the structure, the ambient temperature, the initial temperature of the concrete at time of placement and curing program, the cement type, and the cement contents in the mix.

Mass concrete structures include massive mat foundations, dams, and other concrete structures with a width or depth exceeding three feet or one meter.

History

Historically, in Britain, mass concrete designated early concrete with no reinforcement cast in situ using shuttering. It was used mainly between 1850 and 1900 on a variety of buildings, mainly as a walling material or where mass was required for gravity such as in dams, reservoirs, retaining walls and maritime structures. In those days, the term was not officially defined and did not contain any connotation to large dimensions generating heat from hydration of cement, as these occurrences were not yet understood. [2]

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<span class="mw-page-title-main">Lime (material)</span> Calcium oxides and/or hydroxides

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The water–cement ratio is the ratio of the mass of water to the mass of cement used in a concrete mix:

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Cement clinker is a solid material produced in the manufacture of portland cement as an intermediary product. Clinker occurs as lumps or nodules, usually 3 millimetres (0.12 in) to 25 millimetres (0.98 in) in diameter. It is produced by sintering limestone and aluminosilicate materials such as clay during the cement kiln stage.

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<span class="mw-page-title-main">Types of concrete</span> Building material consisting of aggregates cemented by a binder

Concrete is produced in a variety of compositions, finishes and performance characteristics to meet a wide range of needs.

<span class="mw-page-title-main">Concrete degradation</span> Damage to concrete affecting its mechanical strength and its durability

Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damages are caused by the formation of expansive products produced by various chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms. Other damaging processes can also involve calcium leaching by water infiltration and different physical phenomena initiating cracks formation and propagation. All these detrimental processes and damaging agents adversely affects the concrete mechanical strength and its durability.

Concrete has relatively high compressive strength, but significantly lower tensile strength. The compressive strength is typically controlled with the ratio of water to cement when forming the concrete, and tensile strength is increased by additives, typically steel, to create reinforced concrete. In other words we can say concrete is made up of sand, ballast, cement and water.

Creep and shrinkage of concrete are two physical properties of concrete. The creep of concrete, which originates from the calcium silicate hydrates (C-S-H) in the hardened Portland cement paste, is fundamentally different from the creep of metals and polymers. Unlike the creep of metals, it occurs at all stress levels and, within the service stress range, is linearly dependent on the stress if the pore water content is constant. Unlike the creep of polymers and metals, it exhibits multi-months aging, caused by chemical hardening due to hydration which stiffens the microstructure, and multi-year aging, caused by long-term relaxation of self-equilibrated micro-stresses in the nano-porous microstructure of the C-S-H. If concrete is fully dried, it does not creep, but it is next to impossible to dry concrete fully without severe cracking.

<span class="mw-page-title-main">Energetically modified cement</span> Class of cements, mechanically processed to transform reactivity

Energetically modified cements (EMCs) are a class of cements made from pozzolans, silica sand, blast furnace slag, or Portland cement. The term "energetically modified" arises by virtue of the mechanochemistry process applied to the raw material, more accurately classified as "high energy ball milling" (HEBM). At its simplest this means a milling method that invokes high kinetics by subjecting "powders to the repeated action of hitting balls" as compared to (say) the low kinetics of rotating ball mills. This causes, amongst others, a thermodynamic transformation in the material to increase its chemical reactivity. For EMCs, the HEBM process used is a unique form of specialised vibratory milling discovered in Sweden and applied only to cementitious materials, here called "EMC Activation".

Cement hydration and strength development mainly depend on two silicate phases: tricalcium silicate (C3S) (alite), and dicalcium silicate (C2S) (belite). Upon hydration, the main reaction products are calcium silicate hydrates (C-S-H) and calcium hydroxide Ca(OH)2, written as CH in the cement chemist notation. C-S-H is the phase playing the role of the glue in the cement hardened paste and responsible of its cohesion. Cement also contains two aluminate phases: C3A and C4AF, respectively the tricalcium aluminate and the tetracalcium aluminoferrite. C3A hydration products are AFm, calcium aluminoferrite monosulfate, and ettringite, a calcium aluminoferrite trisulfate (AFt). C4AF hydrates as hydrogarnet and ferrous ettringite.

References

  1. ACI Committee 207–Mass and Thermally Controlled Concrete
  2. Urquhart, Denis (2013). (huanhi) "Historic Concrete in Scotland Part 1: History and Development" Archived 2016-03-04 at the Wayback Machine Historic Scotland, National Conservation Centre, ISBN   978-1-84917-119-9, p. 9