Concrete is a composite material composed of fine and coarse aggregate bonded together with a fluid cement that hardens (cures) over time. Concrete is the second-most-used substance in the world after water, and is the most widely used building material. Its usage worldwide, ton for ton, is twice that of steel, wood, plastics, and aluminum combined. Globally, the ready-mix concrete industry, the largest segment of the concrete market, is projected to exceed $600 billion in revenue by 2025. This widespread use results in a number of environmental impacts. Most notably, the production process for cement produces large volumes of greenhouse gas emissions, leading to net 8% of global emissions. Other environmental concerns include widespread illegal sand mining, impacts on the surrounding environment such as increased surface runoff or urban heat island effect, and potential public health implications from toxic ingredients. Significant research and development is being done to try to reduce the emissions or make concrete a source of carbon sequestration, and increase recycled and secondary raw materials content into the mix to achieve a circular economy. Concrete is expected to be a key material for structures resilient to climate disasters, as well as a solution to mitigate the pollution of other industries, capturing wastes such as coal fly ash or bauxite tailings and residue.
A cement is a binder, a substance used for construction that sets, hardens, and adheres to other materials to bind them together. Cement is seldom used on its own, but rather to bind sand and gravel (aggregate) together. Cement mixed with fine aggregate produces mortar for masonry, or with sand and gravel, produces concrete. Concrete is the most widely used material in existence and is behind only water as the planet's most-consumed resource.
Portland cement is the most common type of cement in general use around the world as a basic ingredient of concrete, mortar, stucco, and non-specialty grout. It was developed from other types of hydraulic lime in England in the early 19th century by Joseph Aspdin, and is usually made from limestone. It is a fine powder, produced by heating limestone and clay minerals in a kiln to form clinker, grinding the clinker, and adding 2 to 3 percent of gypsum. Several types of portland cement are available. The most common, called ordinary portland cement (OPC), is grey, but white portland cement is also available. Its name is derived from its resemblance to Portland stone which was quarried on the Isle of Portland in Dorset, England. It was named by Joseph Aspdin who obtained a patent for it in 1824. However, his son William Aspdin is regarded as the inventor of "modern" portland cement due to his developments in the 1840s.
Silicon dioxide, also known as silica, is an oxide of silicon with the chemical formula SiO2, most commonly found in nature as quartz and in various living organisms. In many parts of the world, silica is the major constituent of sand. Silica is one of the most complex and most abundant families of materials, existing as a compound of several minerals and as a synthetic product. Notable examples include fused quartz, fumed silica, silica gel, opal and aerogels. It is used in structural materials, microelectronics, and as components in the food and pharmaceutical industries.
Slag is a by-product of smelting (pyrometallurgical) ores and used metals. Broadly, it can be classified as ferrous, ferroalloy or non-ferrous/base metals. Within these general categories, slags can be further categorized by their precursor and processing conditions.
Pozzolana or pozzuolana, also known as pozzolanic ash, is a natural siliceous or siliceous-aluminous material which reacts with calcium hydroxide in the presence of water at room temperature. In this reaction insoluble calcium silicate hydrate and calcium aluminate hydrate compounds are formed possessing cementitious properties. The designation pozzolana is derived from one of the primary deposits of volcanic ash used by the Romans in Italy, at Pozzuoli. The modern definition of pozzolana encompasses any volcanic material, predominantly composed of fine volcanic glass, that is used as a pozzolan. Note the difference with the term pozzolan, which exerts no bearing on the specific origin of the material, as opposed to pozzolana, which can only be used for pozzolans of volcanic origin, primarily composed of volcanic glass.
Fly ash, flue ash, coal ash, or pulverised fuel ash – plurale tantum: coal combustion residuals (CCRs) – is a coal combustion product that is composed of the particulates that are driven out of coal-fired boilers together with the flue gases. Ash that falls to the bottom of the boiler's combustion chamber is called bottom ash. In modern coal-fired power plants, fly ash is generally captured by electrostatic precipitators or other particle filtration equipment before the flue gases reach the chimneys. Together with bottom ash removed from the bottom of the boiler, it is known as coal ash.
Controlled low strength material, abbreviated CLSM, also known as flowable fill, is a type of weak, runny concrete mix used in construction for non-structural purposes such as backfill or road bases.
Hydraulic lime (HL) is a general term for calcium oxide, a variety of lime also called quicklime, that sets by hydration. This contrasts with calcium hydroxide, also called slaked lime or air lime that is used to make lime mortar, the other common type of lime mortar, which sets by carbonation (re-absorbing carbon dioxide (CO2) from the air). Hydraulic lime provides a faster initial set and higher compressive strength than air lime and hydraulic lime will set in more extreme conditions, including under water.
Engineered Cementitious Composite (ECC), also called Strain Hardening Cement-based Composites (SHCC) or more popularly as bendable concrete, is an easily molded mortar-based composite reinforced with specially selected short random fibers, usually polymer fibers. Unlike regular concrete, ECC has a tensile strain capacity in the range of 3–7%, compared to 0.01% for ordinary portland cement (OPC) paste, mortar or concrete. ECC therefore acts more like a ductile metal material rather than a brittle glass material, leading to a wide variety of applications.
The water–cement ratio is the ratio of the weight of water to the weight of cement used in a concrete mix. A lower ratio leads to higher strength and durability, but may make the mix difficult to work with and form. Workability can be resolved with the use of plasticizers or super-plasticizers.
Metakaolin is the anhydrous calcined form of the clay mineral kaolinite. Minerals that are rich in kaolinite are known as china clay or kaolin, traditionally used in the manufacture of porcelain. The particle size of metakaolin is smaller than cement particles, but not as fine as silica fume.
Ground-granulated blast-furnace slag is obtained by quenching molten iron slag from a blast furnace in water or steam, to produce a glassy, granular product that is then dried and ground into a fine powder. Ground-granulated blast furnace slag is highly cementitious and high in calcium silicate hydrates (CSH) which is a strength enhancing compound which improves the strength, durability and appearance of the concrete.
Pozzolans are a broad class of siliceous and aluminous materials which, in themselves, possess little or no cementitious value but which will, in finely divided form and in the presence of water, react chemically with calcium hydroxide (Ca(OH)2) at ordinary temperature to form compounds possessing cementitious properties. The quantification of the capacity of a pozzolan to react with calcium hydroxide and water is given by measuring its pozzolanic activity. Pozzolana are naturally occurring pozzolans of volcanic origin.
The alkali–silica reaction (ASR), more commonly known as "concrete cancer", is a deleterious swelling reaction that occurs over time in concrete between the highly alkaline cement paste and the reactive amorphous silica found in many common aggregates, given sufficient moisture.
Roman concrete, also called opus caementicium, was a material used in construction in Ancient Rome. Roman concrete was based on a hydraulic-setting cement. It is durable due to its incorporation of pozzolanic ash, which prevents cracks from spreading. By the middle of the 1st century, the material was used frequently, often brick-faced, although variations in aggregate allowed different arrangements of materials. Further innovative developments in the material, called the concrete revolution, contributed to structurally complicated forms, such as the Pantheon dome, the world's largest and oldest unreinforced concrete dome.
Concrete has relatively high compressive strength, but significantly lower tensile strength. The compressive strength is typically controlled with the ratio of water to cement when forming the concrete, and tensile strength is increased by additives, typically steel, to create reinforced concrete. In other words we can say concrete is made up of sand, ballast, cement and water.
The pozzolanic activity is a measure for the degree of reaction over time or the reaction rate between a pozzolan and Ca2+ or calcium hydroxide (Ca(OH)2) in the presence of water. The rate of the pozzolanic reaction is dependent on the intrinsic characteristics of the pozzolan such as the specific surface area, the chemical composition and the active phase content.
Well cementing is the process of introducing cement to the annular space between the well-bore and casing or to the annular space between two successive casing strings. Personnel who conduct this job are called "Cementers".
Energetically modified cements (EMCs) are a class of cements made from pozzolans, silica sand, blast furnace slag, or Portland cement. The term "energetically modified" arises by virtue of the mechanochemistry process applied to the raw material, more accurately classified as "high energy ball milling" (HEBM). This causes, amongst others, a thermodynamic transformation in the material to increase its chemical reactivity. For EMCs, the HEBM process used is a unique form of specialised vibratory milling discovered in Sweden and applied only to cementitious materials, here called "EMC Activation".
