R-407C

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R-407c container R407C container.png
R-407c container

R-407C is a mixture of hydrofluorocarbons used as a refrigerant. It is a zeotropic blend of difluoromethane (R-32), pentafluoroethane (R-125), and 1,1,1,2-tetrafluoroethane (R-134a). Difluoromethane serves to provide the heat capacity, pentafluoroethane decreases flammability, tetrafluoroethane reduces pressure. [1] R-407C cylinders are colored burnt orange.

Contents

This refrigerant is intended as a replacement for R-22. R-22 production will be phased out by 2020 as per the Montreal Protocol. [2]

Key Characteristics:

Applications

R407C is employed in a variety of cooling and refrigeration contexts:

Features & Benefits

R407C offers several notable benefits:

Environmental and Safety Considerations

While R407C presents environmental advantages over older refrigerants, it still requires careful handling:

Safety Precautions

For safe handling of R407C, consider the following precautions:

Physical properties

Physical properties of R407C refrigerant
PropertyValue
Formula
CH2F2R32 (23%)
CF3CHF2R125 (25%)
CF3CH2FR134a (52%)
Molecular Weight (kg/kmol)86.2
Boiling point (°C)43.8
Saturated liquid density (25°C), kg/m31138
Saturated vapour density (25°C), kg/m343.8
Critical temperature (°C)86.4
Critical pressure, bar46.3
Liquid heat capacity @ 25°C, (kJ/(kg·K))1.533
Vapour heat capacity @ 1.013 bar (kJ/(kg·K))1.107

Related Research Articles

<span class="mw-page-title-main">Heating, ventilation, and air conditioning</span> Technology of indoor and vehicular environmental comfort

Heating, ventilation, and air conditioning (HVAC) is the use of various technologies to control the temperature, humidity, and purity of the air in an enclosed space. Its goal is to provide thermal comfort and acceptable indoor air quality. HVAC system design is a subdiscipline of mechanical engineering, based on the principles of thermodynamics, fluid mechanics, and heat transfer. "Refrigeration" is sometimes added to the field's abbreviation as HVAC&R or HVACR, or "ventilation" is dropped, as in HACR.

<span class="mw-page-title-main">Heat pump</span> System that transfers heat from one space to another

A heat pump is a device that consumes energy to transfer heat from a cold heat sink to a hot heat sink. Specifically, the heat pump transfers thermal energy using a refrigeration cycle, cooling the cool space and warming the warm space. In cold weather, a heat pump can move heat from the cool outdoors to warm a house ; the pump may also be designed to move heat from the house to the warmer outdoors in warm weather. As they transfer heat rather than generating heat, they are more energy-efficient than other ways of heating or cooling a home.

<span class="mw-page-title-main">Refrigerant</span> Substance in a refrigeration cycle

A refrigerant is a working fluid used in the refrigeration cycle of air conditioning systems and heat pumps where in most cases they undergo a repeated phase transition from a liquid to a gas and back again. Refrigerants are heavily regulated because of their toxicity and flammability and the contribution of CFC and HCFC refrigerants to ozone depletion and that of HFC refrigerants to climate change.

<span class="mw-page-title-main">Difluoromethane</span> Chemical compound

Difluoromethane, also called difluoromethylene, HFC-32Methylene Fluoride or R-32, is an organic compound of the dihalogenoalkane variety. Invented in 1964 by Hoechst AG (not Daikin) it has the formula of CH2F2. It is a colorless gas in the ambient atmosphere and is slightly soluble in water, with a high thermal stability. Due to the low melting and boiling point, (−136.0 and −51.6 °C [−212.8 and −60.9 °F; 137.2 and 221.6 K] respectively) contact with this compound may result in frostbite. In the United States, the Clean Air Act Section 111 on Volatile Organic Compounds (VOC) has listed difluoromethane as an exception (since 1997) from the definition of VOC due to its low production of tropospheric ozone. Difluoromethane is commonly used in endothermic processes such as refrigeration or air conditioning.

Dichlorodifluoromethane (R-12) is a colorless gas usually sold under the brand name Freon-12, and a chlorofluorocarbon halomethane (CFC) used as a refrigerant and aerosol spray propellant. In compliance with the Montreal Protocol, its manufacture was banned in developed countries in 1996, and in developing countries in 2010 out of concerns about its damaging effect on the ozone layer. Its only allowed usage is as a fire retardant in submarines and aircraft. It is soluble in many organic solvents. R-12 cylinders are colored white.

1,1,1,2-Tetrafluoroethane (also known as norflurane (INN), R-134a, Klea 134a, Freon 134a, Forane 134a, Genetron 134a, Green Gas, Florasol 134a, Suva 134a, HFA-134a, or HFC-134a) is a hydrofluorocarbon (HFC) and haloalkane refrigerant with thermodynamic properties similar to R-12 (dichlorodifluoromethane) but with insignificant ozone depletion potential and a lower 100-year global warming potential (1,430, compared to R-12's GWP of 10,900). It has the formula CF3CH2F and a boiling point of −26.3 °C (−15.34 °F) at atmospheric pressure. R-134a cylinders are colored light blue. A phaseout and transition to HFO-1234yf and other refrigerants, with GWPs similar to CO2, began in 2012 within the automotive market.

<span class="mw-page-title-main">Chlorodifluoromethane</span> Chemical propellant and refrigerant

Chlorodifluoromethane or difluoromonochloromethane is a hydrochlorofluorocarbon (HCFC). This colorless gas is better known as HCFC-22, or R-22, or CHClF
2
. It was commonly used as a propellant and refrigerant. These applications were phased out under the Montreal Protocol in developed countries in 2020 due to the compound's ozone depletion potential (ODP) and high global warming potential (GWP), and in developing countries this process will be completed by 2030. R-22 is a versatile intermediate in industrial organofluorine chemistry, e.g. as a precursor to tetrafluoroethylene.

R-410A is a refrigerant used in air conditioning and heat pump applications. It is a zeotropic but near-azeotropic mixture of difluoromethane (CH2F2, called R-32) and pentafluoroethane (CHF2CF3, called R-125). R-410A is sold under the trademarked names AZ-20, EcoFluor R410, Forane 410A, Genetron R410A, Puron, and Suva 410A.

<span class="mw-page-title-main">Vapor-compression refrigeration</span> Refrigeration process

Vapour-compression refrigeration or vapor-compression refrigeration system (VCRS), in which the refrigerant undergoes phase changes, is one of the many refrigeration cycles and is the most widely used method for air conditioning of buildings and automobiles. It is also used in domestic and commercial refrigerators, large-scale warehouses for chilled or frozen storage of foods and meats, refrigerated trucks and railroad cars, and a host of other commercial and industrial services. Oil refineries, petrochemical and chemical processing plants, and natural gas processing plants are among the many types of industrial plants that often utilize large vapor-compression refrigeration systems. Cascade refrigeration systems may also be implemented using two compressors.

<span class="mw-page-title-main">Air source heat pump</span> Most common type of heat pump

An air source heat pump (ASHP) is a heat pump that can absorb heat from air outside a building and release it inside; it uses the same vapor-compression refrigeration process and much the same equipment as an air conditioner, but in the opposite direction. ASHPs are the most common type of heat pump and, usually being smaller, tend to be used to heat individual houses or flats rather than blocks, districts or industrial processes.

Natural refrigerants are considered substances that serve as refrigerants in refrigeration systems. They are alternatives to synthetic refrigerants such as chlorofluorocarbon (CFC), hydrochlorofluorocarbon (HCFC), and hydrofluorocarbon (HFC) based refrigerants. Unlike other refrigerants, natural refrigerants can be found in nature and are commercially available thanks to physical industrial processes like fractional distillation, chemical reactions such as Haber process and spin-off gases. The most prominent of these include various natural hydrocarbons, carbon dioxide, ammonia, and water. Natural refrigerants are preferred actually in new equipment to their synthetic counterparts for their presumption of higher degrees of sustainability. With the current technologies available, almost 75 percent of the refrigeration and air conditioning sector has the potential to be converted to natural refrigerants.

HC-12a, also called ES-12a, OZ-12a, DURACOOL 12a and Hydrocarbon Blend B, is a "drop-in" replacement refrigerant for Freon-12 and to a lesser extent, R-134a. HC-12a is a mixture of hydrocarbons, specifically propane (R-290) and isobutane (R-600a), and is therefore considered nearly non-ozone-depleting compared to dichlorodifluoromethane or 1,1,1,2-tetrafluoroethane (R-134a). The mixture can be used in refrigeration systems designed for R-12. HC-12a provides better cooling than an R-12 system retrofitted to R-134a, with much greater energy efficiency as well. Unlike R-134a, HC-12a is completely compatible with the hoses and oils used in R-12 systems, making the conversion much easier to accomplish. HC-12a is also patent-free due to its non-synthetic nature.

Section 608 of the Clean Air Act serves as the main form of occupational licensure for technicians in the heating, ventilation, and air conditioning (HVAC) industry in the United States. The law requires that all persons who maintain, service, repair or dispose of appliances that contain regulated refrigerants be certified in proper refrigerant handling techniques. The regulatory program helps to minimize the release of refrigerants, and in particular ozone depleting refrigerants such as chlorofluorocarbons and hydrofluorocarbons, as well as other regulated refrigerants as determined by Section 612. The licensure program complies with the requirements under the Montreal Protocol. The Environmental Protection Agency (EPA) published implementing regulations at 40 CFR Part 82.

R-407A is a mixture of gasses used as a refrigerant. It is a zeotropic blend of difluoromethane (HFC-32), pentafluoroethane (HFC-125) and 1,1,1,2-tetrafluoroethane (HFC-134a). R-407A was developed as a close match to R-22's capacities and flow rates, making it well suited as an energy efficient retrofit for R-22 in medium and low temperature refrigeration systems for supermarket and food storage applications, but not for air conditioning systems or those with flooded evaporators. It must be used with synthetic oils. Its global warming potential is 2107.

<span class="mw-page-title-main">Pentafluoroethane</span> Chemical compound

Pentafluoroethane is a fluorocarbon with the formula CF3CHF2. Pentafluoroethane is currently used as a refrigerant (known as R-125) and also used as a fire suppression agent in fire suppression systems.

<span class="mw-page-title-main">Automotive air conditioning</span> System to cool the air in a vehicle

Automotive air conditioning systems use air conditioning to cool the air in a vehicle.

Fluorinated gases (F-gases) are a group of gases containing fluorine. They are divided into several types, the main of those are hydrofluorocarbons (HFCs), perfluorocarbons (PFCs), sulphur hexafluoride (SF6). They are used in refrigeration, air conditioning, heat pumps, fire suppression, electronics, aerospace, magnesium industry, foam and high voltage switchgear. As they are greenhouse gases with a strong global warming potential, their use is regulated.

R-469A is a refrigerant blend consisting of 35% carbon dioxide (R-744), 32.5% difluoromethane (R-32), and 32.5% pentafluoroethane (R-125).

The Significant New Alternatives Policy is a program of the EPA to determine acceptable chemical substitutes, and establish which are prohibited or regulated by the EPA. It also establishes a program by which new alternatives may be accepted, and promulgates timelines to the industry regarding phase-outs of substitutes.

References

  1. A brief history of refrigerant Archived 2011-07-18 at the Wayback Machine
  2. "Unwrapping The Mystery Of R-407C". www.achrnews.com. Retrieved 27 June 2016.
  3. "Refrigerants". EPA. March 22, 2002. Retrieved August 28, 2024.
  4. "Refrigerant gas cylinder". Starkehvacr.com. March 13, 2024. Retrieved August 28, 2024.{{cite web}}: CS1 maint: url-status (link)
  5. "End-uses of refrigerant gas" (PDF). EPA. July 28, 1995. Retrieved August 28, 2024.{{cite web}}: CS1 maint: url-status (link)