This article or section appears to contradict itself.(March 2024) |
Regelation is the phenomenon of ice melting under pressure and refreezing when the pressure is reduced. This can be demonstrated by looping a fine wire around a block of ice, with a heavy weight attached to it. The pressure exerted on the ice slowly melts it locally, permitting the wire to pass through the entire block. The wire's track will refill as soon as pressure is relieved, so the ice block will remain intact even after wire passes completely through. This experiment is possible for ice at −10 °C or cooler, and while essentially valid, the details of the process by which the wire passes through the ice are complex. [1] The phenomenon works best with high thermal conductivity materials such as copper, since latent heat of fusion from the top side needs to be transferred to the lower side to supply latent heat of melting. In short, the phenomenon in which ice converts to liquid due to applied pressure and then re-converts to ice once the pressure is removed is called regelation.
Regelation was discovered by Michael Faraday. It occurs only for substances such as ice, that have the property of expanding upon freezing, for the melting points of those substances decrease with the increasing external pressure. The melting point of ice falls by 0.0072 °C for each additional atm of pressure applied. For example, a pressure of 500 atmospheres is needed for ice to melt at −4 °C. [2]
For a normal crystalline ice far below its melting point, there will be some relaxation of the atoms near the surface. Simulations of ice near to its melting point show that there is significant melting of the surface layers rather than a symmetric relaxation of atom positions. Nuclear magnetic resonance provided evidence for a liquid layer on the surface of ice. In 1998, using atomic force microscopy, Astrid Döppenschmidt and Hans-Jürgen Butt measured the thickness of the liquid-like layer on ice to be roughly 32 nm at −1 °C, and 11 nm at −10 °C. [3]
The surface melting can account for the following:
A glacier can exert a sufficient amount of pressure on its lower surface to lower the melting point of its ice. The melting of the ice at the glacier's base allows it to move from a higher elevation to a lower elevation. Liquid water may flow from the base of a glacier at lower elevations when the temperature of the air is above the freezing point of water.
At least one 1992 article suggests it is a slightly misconceived misconception to ascribe regelation to ice skating. [4] The problem with matching the (large) magnitude of the water-ice p-V gradient above the triple point boundary with the magnitudes of prevailing temperature and pressure in the case of the ice skating context applies equally in the context of the classic lab experiment with a copper wire cutting through an 10cm ice block with say a 28 swg wire. The misconception is not that these observations fail to be regelation but that regelation can be explained (solely) in terms of the magnitude of p-V gradient above the triple point. There is much more going on. Regelation is empirical—it is a phenomenon as was, for example, Brownian Motion before, during, and arguably even after Einstein modelled it. It has been so widely observed and described that we generalise to describing it in terms of pressure causing increased surface melting. The recognition of this phenomenon in all the mentioned contexts is not in doubt. Car tyres work in snow even though there is some increased surface melting because they have tread which allows water to be liberated.
Ice skating is given as an example of regelation; however, the pressure required is much greater than the weight of a skater. Additionally, regelation does not explain how one can ice skate at sub-zero (0°C) temperatures. [5]
Compaction and creation of snow balls is another example from old texts. Here, the pressure required is far greater than the pressure that can be applied by hand. A counter example is that cars do not melt snow as they run over it.
A glacier is a persistent body of dense ice that is constantly moving under its own weight. A glacier forms where the accumulation of snow exceeds its ablation over many years, often centuries. It acquires distinguishing features, such as crevasses and seracs, as it slowly flows and deforms under stresses induced by its weight. As it moves, it abrades rock and debris from its substrate to create landforms such as cirques, moraines, or fjords. Although a glacier may flow into a body of water, it forms only on land and is distinct from the much thinner sea ice and lake ice that form on the surface of bodies of water.
Ice is water that is frozen into a solid state, typically forming at or below temperatures of 0 °C, 32 °F, or 273.15 K. As a naturally occurring crystalline inorganic solid with an ordered structure, ice is considered to be a mineral. Depending on the presence of impurities such as particles of soil or bubbles of air, it can appear transparent or a more or less opaque bluish-white color.
Ice skating is the self-propulsion and gliding of a person across an ice surface, using metal-bladed ice skates. People skate for various reasons, including recreation (fun), exercise, competitive sports, and commuting. Ice skating may be performed on naturally frozen bodies of water, such as ponds, lakes, canals, and rivers, and on human-made ice surfaces both indoors and outdoors.
Melting, or fusion, is a physical process that results in the phase transition of a substance from a solid to a liquid. This occurs when the internal energy of the solid increases, typically by the application of heat or pressure, which increases the substance's temperature to the melting point. At the melting point, the ordering of ions or molecules in the solid breaks down to a less ordered state, and the solid melts to become a liquid.
Snow comprises individual ice crystals that grow while suspended in the atmosphere—usually within clouds—and then fall, accumulating on the ground where they undergo further changes. It consists of frozen crystalline water throughout its life cycle, starting when, under suitable conditions, the ice crystals form in the atmosphere, increase to millimeter size, precipitate and accumulate on surfaces, then metamorphose in place, and ultimately melt, slide or sublimate away.
The melting point of a substance is the temperature at which it changes state from solid to liquid. At the melting point the solid and liquid phase exist in equilibrium. The melting point of a substance depends on pressure and is usually specified at a standard pressure such as 1 atmosphere or 100 kPa.
Freezing rain is rain maintained at temperatures below freezing by the ambient air mass that causes freezing on contact with surfaces. Unlike a mixture of rain and snow or ice pellets, freezing rain is made entirely of liquid droplets. The raindrops become supercooled while passing through a sub-freezing layer of air hundreds of meters above the ground, and then freeze upon impact with any surface they encounter, including the ground, trees, electrical wires, aircraft, and automobiles. The resulting ice, called glaze ice, can accumulate to a thickness of several centimeters and cover all exposed surfaces. The METAR code for freezing rain is FZRA.
Sea ice arises as seawater freezes. Because ice is less dense than water, it floats on the ocean's surface. Sea ice covers about 7% of the Earth's surface and about 12% of the world's oceans. Much of the world's sea ice is enclosed within the polar ice packs in the Earth's polar regions: the Arctic ice pack of the Arctic Ocean and the Antarctic ice pack of the Southern Ocean. Polar packs undergo a significant yearly cycling in surface extent, a natural process upon which depends the Arctic ecology, including the ocean's ecosystems. Due to the action of winds, currents and temperature fluctuations, sea ice is very dynamic, leading to a wide variety of ice types and features. Sea ice may be contrasted with icebergs, which are chunks of ice shelves or glaciers that calve into the ocean. Depending on location, sea ice expanses may also incorporate icebergs.
Freezing-point depression is a drop in the maximum temperature at which a substance freezes, caused when a smaller amount of another, non-volatile substance is added. Examples include adding salt into water, alcohol in water, ethylene or propylene glycol in water, adding copper to molten silver, or the mixing of two solids such as impurities into a finely powdered drug.
Scree is a collection of broken rock fragments at the base of a cliff or other steep rocky mass that has accumulated through periodic rockfall. Landforms associated with these materials are often called talus deposits. Talus deposits typically have a concave upwards form, where the maximum inclination corresponds to the angle of repose of the mean debris particle size. The exact definition of scree in the primary literature is somewhat relaxed, and it often overlaps with both talus and colluvium.
In glaciology, an ice cap is a mass of ice that covers less than 50,000 km2 (19,000 sq mi) of land area. Larger ice masses covering more than 50,000 km2 (19,000 sq mi) are termed ice sheets.
Premelting refers to a quasi-liquid film that can occur on the surface of a solid even below melting point. The thickness of the film is temperature dependent. This effect is common for all crystalline materials. Premelting shows its effects in frost heave, and, taking grain boundary interfaces into account, maybe even in the movement of glaciers.
In chemistry, fractional crystallization is a stage-wise separation technique that relies on the liquid-solid phase change. It fractionates via differences in crystallization temperature and enables the purification of multi-component mixtures, as long as none of the constituents can act as solvents to the others. Due to the high selectivity of the solid – liquid equilibrium, very high purities can be achieved for the selected component.
Meltwater is water released by the melting of snow or ice, including glacial ice, tabular icebergs and ice shelves over oceans. Meltwater is often found during early spring when snow packs and frozen rivers melt with rising temperatures, and in the ablation zone of glaciers where the rate of snow cover is reducing. Meltwater can be produced during volcanic eruptions, in a similar way in which the more dangerous lahars form. It can also be produced by the heat generated by the flow itself.
Melting-point depression is the phenomenon of reduction of the melting point of a material with a reduction of its size. This phenomenon is very prominent in nanoscale materials, which melt at temperatures hundreds of degrees lower than bulk materials.
A supraglacial lake is any pond of liquid water on the top of a glacier. Although these pools are ephemeral, they may reach kilometers in diameter and be several meters deep. They may last for months or even decades at a time, but can empty in the course of hours.
Ice sheet dynamics describe the motion within large bodies of ice such as those currently on Greenland and Antarctica. Ice motion is dominated by the movement of glaciers, whose gravity-driven activity is controlled by two main variable factors: the temperature and the strength of their bases. A number of processes alter these two factors, resulting in cyclic surges of activity interspersed with longer periods of inactivity, on both hourly and centennial time scales. Ice-sheet dynamics are of interest in modelling future sea level rise.
Overdeepening is a characteristic of basins and valleys eroded by glaciers. An overdeepened valley profile is often eroded to depths which are hundreds of metres below the lowest continuous surface line along a valley or watercourse. This phenomenon is observed under modern day glaciers, in salt-water fjords and fresh-water lakes remaining after glaciers melt, as well as in tunnel valleys which are partially or totally filled with sediment. When the channel produced by a glacier is filled with debris, the subsurface geomorphic structure is found to be erosionally cut into bedrock and subsequently filled by sediments. These overdeepened cuts into bedrock structures can reach a depth of several hundred metres below the valley floor.
Ice segregation is the geological phenomenon produced by the formation of ice lenses, which induce erosion when moisture, diffused within soil or rock, accumulates in a localized zone. The ice initially accumulates within small collocated pores or pre-existing cracks, and, as long as the conditions remain favorable, continues to collect in the ice layer or ice lens, wedging the soil or rock apart. Ice lenses grow parallel to the surface and several centimeters to several decimeters deep in the soil or rock. Studies between 1990 and present have demonstrated that rock fracture by ice segregation is a more effective weathering process than the freeze-thaw process which older texts proposed.
This glossary of meteorology is a list of terms and concepts relevant to meteorology and atmospheric science, their sub-disciplines, and related fields.