Tetrahydroxydiboron

Last updated
Tetrahydroxydiboron
Tetrahydroxydiboron structure.svg
Names
IUPAC name
Hypoboric acid [1]
Other names
(Dihydroxyboranyl)boronic acid
Hypoboric acid
Hypodiboric acid
Sub-boric acid (Unterborsäure in German)
1,1,2,2-Tetrahydroxydiborane
Identifiers
3D model (JSmol)
ChEBI
ChemSpider
ECHA InfoCard 100.222.662 OOjs UI icon edit-ltr-progressive.svg
PubChem CID
UNII
  • InChI=1S/B2H4O4/c3-1(4)2(5)6/h3-6H
    Key: SKOWZLGOFVSKLB-UHFFFAOYSA-N
  • B(B(O)O)(O)O
Properties
B2H4O4
Molar mass 89.65 g·mol−1
AppearanceWhite powder
Density 1.657
Melting point 143–148 °C (289–298 °F; 416–421 K)
very soluble
Solubility ethanol, DMF, DMSO, DMA
Structure
monoclinic P21/c
Thermochemistry
Std molar
entropy
(S298)
125.46 J K1 mol1
1410.43 kJ mol1
Hazards
GHS labelling:
H302, H315, H319, H332, H335
P261, P264, P270, P271, P280, P301+P312, P302+P352, P304+P312, P304+P340, P305+P351+P338, P312, P321, P330, P332+P313, P337+P313, P362, P403+P233, P405, P501
Related compounds
Related compounds
Diborane
Diboron tetrafluoride
Bis(pinacolato)diboron
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Tetrahydroxydiboron is a chemical reagent which can be used to prepare boronic acids. [2]

Contents

Synthesis

The reaction of boron trichloride with alcohols was reported in 1931, and was used to prepare dimethoxyboron chloride, B(OCH3)2Cl. [3] Egon Wiberg and Wilhelm Ruschmann used it to prepare tetrahydroxydiboron by first introducing the boronboron bond by reduction with sodium and then hydrolysing the resulting tetramethoxydiboron, B2(OCH3)4, to produce what they termed sub-boric acid. [4] The methanol used in this process can be recycled:

BCl3   B(OCH3)2Cl    B2(OCH3)4   B2(OH)4

Overall: 2  BCl3  + 2  Na  + 4  H2O   B2(OH)4 + 2  NaCl  + 4  HCl

Reactions

When heated to over 90 °C, tetrahydroxydiboron dehydrates to a polymeric boron(II) oxide. The temperature must rise to 220 °C to be totally free from water. [5]

Tetrahydroxydiboron is a reducing agent. A water solution slowly gives off hydrogen gas. [4]

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References

  1. "Hypodiboric acid". IUPAC.
  2. Little, Sarah; Trice, Jane (2001). "Tetrahydroxydiboron". Encyclopedia of Reagents for Organic Synthesis . John Wiley & Sons. doi:10.1002/047084289x.rn01181. ISBN   9780470842898.
  3. Wiberg, Egon; Sütterlin, Walther (1931). "Zur Kenntnis einiger Verbindungen vom Typus BCl3−n(OR)n. (Über alkoxyl-substituierte Borchloride)" [Notes on some compounds of type BCl3−n(OR)n. (Via alkoxy-substituted boron chlorides)]. Z. anorg. allg. Chem. (in German). 202 (1): 1–21. doi:10.1002/zaac.19312020102.
  4. 1 2 Wiberg, Egon; Ruschmann, Wilhelm (1937). "Über eine neue Borsäure ('Unterborsäure'︁) der Formel H4B2O4 und ihre Ester" [On a new boric acid ('Sub-boric acid') of the formula H4B2O4 and its esters]. Ber. Dtsch. Chem. Ges. A/B (in German). 70 (6): 1393–1402. doi:10.1002/cber.19370700636.
  5. Wartik, Thomas; Apple, Eugene F. (1955). "A New Modification of Boron Monoxide". J. Am. Chem. Soc. 77 (23): 6400–6401. doi:10.1021/ja01628a116.