A perovskite is any material with a crystal structure following the formula ABX3, which was first discovered as the mineral called perovskite, which consists of calcium titanium oxide (CaTiO3). The mineral was first discovered in the Ural mountains of Russia by Gustav Rose in 1839 and named after Russian mineralogist L. A. Perovski (1792–1856). 'A' and 'B' are two positively charged ions (i.e. cations), often of very different sizes, and X is a negatively charged ion (an anion, frequently oxide) that bonds to both cations. The 'A' atoms are generally larger than the 'B' atoms. The ideal cubic structure has the B cation in 6-fold coordination, surrounded by an octahedron of anions, and the A cation in 12-fold cuboctahedral coordination. Additional perovskite forms may exist where either/both the A and B sites have a configuration of A1x-1A2x and/or B1y-1B2y and the X may deviate from the ideal coordination configuration as ions within the A and B sites undergo changes in their oxidation states.
Sir Richard Henry Friend is a British physicist who was the Cavendish Professor of Physics at the University of Cambridge from 1995 until 2020 and is Tan Chin Tuan Centennial Professor at the National University of Singapore. Friend's research concerns the physics and engineering of carbon-based semiconductors. He also serves as Chairman of the Scientific Advisory Board of the National Research Foundation (NRF) of Singapore.
In the 19th century, it was observed that the sunlight striking certain materials generates detectable electric current – the photoelectric effect. This discovery laid the foundation for solar cells. Solar cells have gone on to be used in many applications. They have historically been used in situations where electrical power from the grid was unavailable.
A dye-sensitized solar cell is a low-cost solar cell belonging to the group of thin film solar cells. It is based on a semiconductor formed between a photo-sensitized anode and an electrolyte, a photoelectrochemical system. The modern version of a dye solar cell, also known as the Grätzel cell, was originally co-invented in 1988 by Brian O'Regan and Michael Grätzel at UC Berkeley and this work was later developed by the aforementioned scientists at the École Polytechnique Fédérale de Lausanne (EPFL) until the publication of the first high efficiency DSSC in 1991. Michael Grätzel has been awarded the 2010 Millennium Technology Prize for this invention.
Michael Grätzel is a professor at the École Polytechnique Fédérale de Lausanne where he directs the Laboratory of Photonics and Interfaces. He pioneered research on energy and electron transfer reactions in mesoscopic-materials and their optoelectronic applications. He co-invented with Brian O'Regan the Grätzel cell in 1988.
Jenny Nelson is Professor of Physics in the Blackett Laboratory and Head of the Climate change mitigation team at the Grantham Institute - Climate Change and Environment at Imperial College London.
A perovskite solar cell (PSC) is a type of solar cell that includes a perovskite-structured compound, most commonly a hybrid organic–inorganic lead or tin halide-based material as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture.
Methylammonium lead halides (MALHs) are solid compounds with perovskite structure and a chemical formula of [CH3NH3]+Pb2+(X−)3, where X = Cl, Br or I. They have potential applications in solar cells, lasers, light-emitting diodes, photodetectors, radiation detectors, scintillator, magneto-optical data storage and hydrogen production.
Mercouri Kanatzidis is a Charles E. and Emma H. Morrison Professor of chemistry and professor of materials science and engineering at Northwestern University and Senior Scientist at Argonne National Laboratory.
James Robert DurrantFRSC FLSW is a British photochemist. He is a professor of photochemistry at Imperial College London and Sêr Cymru Solar Professor at Swansea University. He serves as director of the centre for plastic electronics (CPE).
Jeremy John Baumberg, is a British physicist who is Professor of Nanoscience in the Cavendish Laboratory at the University of Cambridge, a Fellow of Jesus College, Cambridge and Director of the NanoPhotonics Centre.
Laura Maria Herz is a professor of physics at the University of Oxford. She works on femtosecond spectroscopy for the analysis of semiconductor materials.
Wendy Ruth Flavell is Vice Dean for Research and a Professor of Surface Physics in the School of Physics and Astronomy at the University of Manchester. Her research investigates the electronic structure of complex metal oxides, chalcogenides, photoemission and photovoltaics.
Tsutomu Miyasaka, is a Japanese engineer in electrochemistry best known for the inventor of perovskite solar cell.
Oxford Photovoltaics Limited is an Oxford University spin-off company in the field of perovskite photovoltaics and solar cells.
David S. Ginger is an American physical chemist. He is the B. Seymour Rabinovitch Endowed Professor of Chemistry at the University of Washington. He is also a Washington Research Foundation distinguished scholar, and chief scientist of the University of Washington Clean Energy Institute. In 2018, he was elected to the Washington State Academy of Sciences for his work on the microscopic investigation of materials for thin-film semiconductors. He was elected a member of the American Association for the Advancement of Science in 2012, and was a 2016 National Finalist of the Blavatnik Awards for Young Scientists.
The James Joule Medal and Prize is awarded by the Institute of Physics. It was established in 2008, and was named in honour of James Prescott Joule, British physicist and brewer. The award is made for distinguished contributions to applied physics. The medal is silver and is accompanied by a prize of £1000.
Mohammad Khaja Nazeeruddin is an Indian-Swiss chemist and materials scientist who conducts research on Perovskite solar cells, dye-sensitized solar cells, and light-emitting diodes. He is a professor at EPFL and the director of the Laboratory for Molecular Engineering of Functional Materials at School of Basic Sciences.
Anita Ho-Baillie is an Australian scientist who is the John Hooke Chair of Nanoscience at the University of Sydney. Her research considers the development of durable perovskite solar cells and their integration into different applications. She was named as one of the Web of Science's most highly cited researchers in 2019–2022.
Annamaria Petrozza is an American chemist who is a professor at the Istituto Italiano di Tecnologia. Her research considers sustainable materials for optoelectronic devices. She was awarded the 2022 Materials Research Society Award in Innovation in Materials Characterization.
