The lead cycle is the biogeochemical cycle of lead through the atmosphere, lithosphere, biosphere, and hydrosphere, which has been influenced by anthropogenic activities.
The lead cycle is the biogeochemical cycle of lead through the atmosphere, lithosphere, biosphere, and hydrosphere, which has been influenced by anthropogenic activities.
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Lead (Pb) is a heavy trace element and is formed by the radioactive decay of uranium and thorium. In crustal rocks, it is present as the lead sulfide mineral galena. [1] Natural sources of lead in the lead cycle include wind borne dust, volcanic outgassing, and forest fires. [2] Natural weathering of rocks by physical and chemical agents can mobilize lead in soils. Mobilized lead can react to form oxides or carbonates. It can co-precipitate with other minerals by being occluded through surface adsorption and complexation [4]
Anthropogenic activities have accelerated lead mobilization to the environment. The majority of anthropogenic lead comes from non-ferrous metal manufacturing plants, mining and smelting of ores, stationary and mobile fossil fuel combustion platforms, and lead batteries. [2] [5] These activities produce very fine micron-sized Pb particles that can be transported as aerosols. Anthropogenic lead fluxes decreased from the 1980s to the 2000s as a result of global regulation and outlawing of leaded gasoline. [6] However, the global production in lead has seen a steady rise in the 21st century [7] .
Wet deposition removes lead from the atmosphere to the surface ocean. Precipitation leads to solubilization of aerosols and washout of particulates. Pb concentrations in the oceans is dependent on wet deposition and the concentration of Pb present in atmosphere. [3] The main sink for lead is burial in marine sediments [1]
Lead is highly regulated in drinking water because it affects the developing brain and the nervous system. Children are more prone to lead exposure because they absorb more of ingested Pb from gastrointestinal tracts. [8] Environmental Protection Agency established the Lead and Copper rule (LCR) in 1991 which states that lead and copper concentrations should not exceed 15 ppb and 1.3 ppm in more than 10% of customer taps sampled. In spite of such regulations, lead was found to be in high concentration exceeding the LCR threshold in Flint, Michigan drinking water. The problem was exacerbated when the drinking water supply was switched to Flint river rather than the treated water from Lake Huron and Detroit river. [9] The water was corrosive which caused the dissolution of lead from water pipes. The preventive measure in such cases is to add phosphate to control the mobilization of lead by formation of protective scales.
The nitrogen cycle is the biogeochemical cycle by which nitrogen is converted into multiple chemical forms as it circulates among atmospheric, terrestrial, and marine ecosystems. The conversion of nitrogen can be carried out through both biological and physical processes. Important processes in the nitrogen cycle include fixation, ammonification, nitrification, and denitrification. The majority of Earth's atmosphere (78%) is atmospheric nitrogen, making it the largest source of nitrogen. However, atmospheric nitrogen has limited availability for biological use, leading to a scarcity of usable nitrogen in many types of ecosystems.
The sulfate or sulphate ion is a polyatomic anion with the empirical formula SO2−4. Salts, acid derivatives, and peroxides of sulfate are widely used in industry. Sulfates occur widely in everyday life. Sulfates are salts of sulfuric acid and many are prepared from that acid.
The pedosphere is the outermost layer of the Earth that is composed of soil and subject to soil formation processes. It exists at the interface of the lithosphere, atmosphere, hydrosphere and biosphere. The pedosphere is the skin of the Earth and only develops when there is a dynamic interaction between the atmosphere, biosphere, lithosphere and the hydrosphere. The pedosphere is the foundation of terrestrial life on Earth.
The iron cycle (Fe) is the biogeochemical cycle of iron through the atmosphere, hydrosphere, biosphere and lithosphere. While Fe is highly abundant in the Earth's crust, it is less common in oxygenated surface waters. Iron is a key micronutrient in primary productivity, and a limiting nutrient in the Southern ocean, eastern equatorial Pacific, and the subarctic Pacific referred to as High-Nutrient, Low-Chlorophyll (HNLC) regions of the ocean.
Geobotanical prospecting refers to prospecting based on the composition and health of surrounding botanical life to identify potential resource deposits. Using a variety of techniques, including indicator plant identification, remote sensing and determining the physical and chemical condition of the botanical life in the area, geobotanical prospecting can be used to discover different minerals. This process has clear advantages and benefits, such as being relatively non-invasive and cost efficient. However, the efficacy of this method is not without question. There is evidence that this form of prospecting is a valid scientific method, especially when used in conjunction with other prospecting methods. But as identification of commercial mines are invariably guided by geological principles and confirmed by chemical assays, it is unclear as to whether this prospecting method is a valid standalone scientific method or an outdated method of the past.
The phosphorus cycle is the biogeochemical cycle that involves the movement of phosphorus through the lithosphere, hydrosphere, and biosphere. Unlike many other biogeochemical cycles, the atmosphere does not play a significant role in the movement of phosphorus, because phosphorus and phosphorus-based materials do not enter the gaseous phase readily, as the main source of gaseous phosphorus, phosphine, is only produced in isolated and specific conditions. Therefore, the phosphorus cycle is primarily examined studying the movement of orthophosphate (PO4)3-, the form of phosphorus that is most commonly seen in the environment, through terrestrial and aquatic ecosystems.
In agriculture, leaching is the loss of water-soluble plant nutrients from the soil, due to rain and irrigation. Soil structure, crop planting, type and application rates of fertilizers, and other factors are taken into account to avoid excessive nutrient loss. Leaching may also refer to the practice of applying a small amount of excess irrigation where the water has a high salt content to avoid salts from building up in the soil. Where this is practiced, drainage must also usually be employed, to carry away the excess water.
The mercury cycle is a biogeochemical cycle influenced by natural and anthropogenic processes that transform mercury through multiple chemical forms and environments.
Marine biogeochemical cycles are biogeochemical cycles that occur within marine environments, that is, in the saltwater of seas or oceans or the brackish water of coastal estuaries. These biogeochemical cycles are the pathways chemical substances and elements move through within the marine environment. In addition, substances and elements can be imported into or exported from the marine environment. These imports and exports can occur as exchanges with the atmosphere above, the ocean floor below, or as runoff from the land.
Aluminum is the third most abundant element in the lithosphere at 82,000 ppm. It occurs in low levels, 0.9 ppm, in humans. Aluminum is known to be an ecotoxicant and expected to be a health risk to people. Global primary production (GPP) of aluminum was about 52 million tons in 2013 and remains one of the world's most important metals. It is used for infrastructure, vehicles, aviation, energy and more due to its lightweight, ductility, and cheap cost. Aluminum is harvested from gibbsite, boehmite, and diaspore which make up bauxite. The aluminum cycle is the biogeochemical cycle by which aluminum is moved through the environment by natural and anthropogenic processes. The biogeochemical cycle of aluminum is integral with silicon and phosphorus. For example, phosphates store aluminum that has been sedimented and aluminum is found in diatoms. Aluminum has been found to prevent growth in organisms by making phosphates less available. The humans/lithosphere ratio (B/L) is very low at 0.000011. This level shows that aluminum is more essential in the lithospheric cycle than in the biotic cycle.
Elsie M. Sunderland is a Canadian toxicologist and environmental scientist and the Gordon McKay Professor of Environmental Chemistry at Harvard University. She studies processes through which human activities increase and modify pollutants in natural ecosystems and living systems.
The copper cycle is the biogeochemical cycle of natural and anthropogenic exchanges of copper between reservoirs in the hydrosphere, atmosphere, biosphere, and lithosphere. Human mining and extraction activities have exerted large influence on the copper cycle.
The boron cycle is the biogeochemical cycle of boron through the atmosphere, lithosphere, biosphere, and hydrosphere.
The arsenic (As) cycle is the biogeochemical cycle of natural and anthropogenic exchanges of arsenic terms through the atmosphere, lithosphere, pedosphere, hydrosphere, and biosphere. Although arsenic is naturally abundant in the Earth's crust, long-term exposure and high concentrations of arsenic can be detrimental to human health.
The chromium cycle is the biogeochemical cycle of chromium through the atmosphere, hydrosphere, biosphere and lithosphere.
The iodine cycle is a biogeochemical cycle that primarily consists of natural and biological processes that exchange iodine through the lithosphere, hydrosphere, and atmosphere. Iodine exists in many forms, but in the environment, it generally has an oxidation state of -1, 0, or +5.
The fluorine cycle is the series of biogeochemical processes through which fluorine moves through the lithosphere, hydrosphere, atmosphere, and biosphere. Fluorine originates from the Earth’s crust, and its cycling between various sources and sinks is modulated by a variety of natural and anthropogenic processes.
The cadmium cycle is a biogeochemical cycle of dispersion and deposition of cadmium through the atmosphere, biosphere, pedosphere, and hydrosphere. Cadmium typically exists in the environment with an oxidation state of +2 but can be found with an oxidation state of +1.
The zinc cycle is a biogeochemical cycle that transports zinc through the lithosphere, hydrosphere, and biosphere.
The manganese cycle is the biogeochemical cycle of manganese through the atmosphere, hydrosphere, biosphere and lithosphere. There are bacteria that oxidise manganese to insoluble oxides, and others that reduce it to Mn2+ in order to use it.
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