Players
| Player | W-L (Total) | W-L (Singles) | W-L (Doubles) | Ties | Debut |
|---|---|---|---|---|---|
| Mario Ančić | 21–13 | 13–11 | 8–2 | 18 | 1999 |
| Ivan Beroš | 1–0 | 1–0 | 0–0 | 1 | 1999 |
| Ivan Cerović | 0–1 | 0–1 | 0–0 | 1 | 2006 |
| Marin Čilić | 18–13 | 14–7 | 4–6 | 14 | 2006 |
| Borna Ćorić | 0–1 | 0–1 | 0–0 | 1 | 2013 |
| Ivan Dodig | 4–11 | 2–7 | 2–4 | 7 | 2010 |
| Saša Hiršzon | 11–12 | 6–8 | 5–4 | 9 | 1994 |
| Goran Ivanišević | 33–11 | 20–6 | 13–5 | 18 | 1993 |
| Roko Karanušić | 2–6 | 2–5 | 0–1 | 6 | 2005 |
| Ivo Karlović | 13–12 | 9–8 | 4–4 | 14 | 2000 |
| Željko Krajan | 1–2 | 1–2 | 0–0 | 3 | 1998 |
| Ivan Ljubičić | 36–19 | 23–13 | 13–6 | 22 | 1998 |
| Nikola Mektić | 1–0 | 1–0 | 0–0 | 1 | 2011 |
| Goran Orešić | 1–1 | 1–1 | 0–0 | 2 | 1996 |
| Mate Pavić | 0–2 | 0–1 | 0–1 | 1 | 2013 |
| Goran Prpić | 1–5 | 1–3 | 0–2 | 2 | 1993 |
| Igor Šarić | 2–0 | 2–0 | 0–0 | 2 | 1994 |
| Saša Tuksar | 0–2 | 0–2 | 0–0 | 2 | 2004 |
| Ivan Vajda | 0–1 | 0–1 | 0–0 | 1 | 2001 |
| Antonio Veić | 1–2 | 1–2 | 0–0 | 3 | 2010 |
| Lovro Zovko | 6–9 | 5–2 | 1–7 | 10 | 1998 |
