Chalcolithic Eneolithic, Aeneolithic, or Copper Age |
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↑ Stone Age ↑ Neolithic |
↓ Bronze Age ↓ Iron Age |
The Copper Age, also called the Eneolithic or the Chalcolithic Age, has been traditionally understood as a transitional period between the Neolithic and the Bronze Age, in which a gradual introduction of the metal (native copper) took place, while stone was still the main resource utilized. Recent archaeology has found that the metal was not introduced so gradually and that this entailed significant social changes, such as developments in the type of habitation (larger villages, launching of fortifications), long-distance trade, and copper metallurgy.
Some of the earliest Copper Age artifacts were found in the 5th and 6th millennia BCE archaeological sites of the Vinča culture such as Majdanpek, Jarmovac and Pločnik (including a copper axe from 5500 BCE). Somewhat later, in the 5th millennium BCE, metalwork is attested at Rudna Glava mine in Serbia, and at Ai Bunar mine in Bulgaria. [1]
3rd millennium BCE copper metalwork is attested in places like Palmela (Portugal), Cortes (Navarre), and Stonehenge (England). However, as often happens with the prehistoric times, the limits of the age cannot be clearly defined and vary between different sources.
The theory that metallurgy was imported into Europe from the Near East has been practically ruled out. A second hypothesis, that there were two main points of origin of metallurgy in Europe, in southern Spain and in West Bulgaria, is also doubtful due to the existence of sites outside the centers of diffusion where metallurgy was known simultaneously with, or before, those in the ‘original’ nuclei, such as Brixlegg (Tyrol, Austria), while sites closer to the supposed origins of metallurgy, such as in the north of Spain, show fewer metal artifacts than sites in the south and practically no evidence of production. [2]
Currently, the general opinion is that the development of metallurgy took place independently in different places, at different times, with various techniques. One fact that supports this interpretation is that, although the final products (beads, rings, sickles, swords, axes, etc.) are quite similar throughout Europe, the method of production is not. Thus the use of crucibles was the technique utilized in the south of Spain, whereas central Europe employed a slagging process, but Cabrierés (France) used a primitive oxidizing non-slagging process, [3] while in the British Isles the absence of debris, slag or ceramic suggests another technique. [4]
Consequently, the way in which metallurgy was initiated differs considerably depending on the region. There are areas in which copper seems to play a crucial role (i.e., the Balkans), whereas other areas show no interest in it at all. Then there are societies that use copper artifacts, but do not practice metallurgy, [5] and there are other ones that fully adopt some of the cultural innovations but ignore the rest.[ who? ] One example of the latter is Basque country in northern Spain, where splendid large dolmens are present along the Ebro river, but metal is rather infrequent, and when it does appear between the trapping, it is more often bronze or arsenical copper than copper. [6]
Copper is the eighth most abundant metal in the Earth's crust, is available all over the world, and is one of the few that can appear in a pure state. [7] It is not complicated to work with, and a bare hammering can be enough to transform a nugget into a bead. The eye-catching look of native copper makes it easy to recognize, and even flashier if converted into jewelry, a possible motivation for humankind to start metallurgy with it. An evolutive technological process has been described, [8] although there are authors like Javinovic, [9] who think that it is not necessary to pass through the first stages to reach the last one.
To start with, the raw material must be obtained. Copper can be found in over 160 different minerals, [7] but mining activities are entailed to obtain them in large quantities if a reasonable amount of copper is wanted. Some of the most commonly exploited minerals are cuprite, malachite, azurite, chalcopyrite, chrysocolla and tennantite; e.g. malachite was extracted in Rudna Glava (Serbia), Cabrierés (France) or Chinflón (Riotinto, Spain). In fact, one of the possible explanations about what Ötzi the Iceman , the ancient mummy found in the Alps who lived around 3300 years BCE, was doing at 3,210 metres (10,530 ft) of altitude is that he could have been prospecting for new ores of minerals. [10]
Secondly, the mineral is separated from the gangue. This is only possible by smelting or beneficiation. To do so, it is necessary to use a furnace that is able to reach at least 1,089 °C (1,992 °F).
Lastly, a wide range of specific tools and resources have to be available, such as furnaces, moulds, crucibles, mauls, etc.
Minerals of copper were known from ancient times. In Crete, little fragments of malachite and azurite were powdered and used as make up or to decorate ceramic as early as 6000 BCE. [5]
Therefore, the minerals were not collected because people were looking for copper but for virtues like those mentioned or simply because of its brightness and colour, but this knowledge of the minerals is critical since they already knew how to recognize them and where to collect them when, later, they started the systematic search for ores.
Numerous examples of mines are known all over Europe, [11] from the east: Rudna Glava (Serbia), Ai Bunar (Bulgaria); to the west: Mount Gabriel (Ireland), Great Orme, Alderley Edge (United Kingdom); crossing Central Europe: Mitterberg (Salzach, Austria), Neuchâtel (Switzerland), Cabrierés (France); to the south: Riotinto, Mola Alta de Serelles (Spain); and the Mediterranean: Corsica, Cyprus, and the Cyclades islands. It is remarkable that, usually, it is not a single mine but a complex, with a variable, large number of mineshafts, as in Rudna Glava (30) or Mount Gabriel (31).
The techniques observed in all of them are quite similar. Basically they used the thermic alteration or firesetting (Mohen 1992, Craddock 1995, Eiroa et al. 1996, Timberlake 2003). This consists of applying fire to the rock and then pouring water over it: the rapid changes of temperature will cause cracks within the rocks that can be totally broken with the help of mauls and picks. Then the useful masses were selected, crushed and transported to the production centre that could be in the surrounding area (Mitterberg) or far away (Rudna Glava).
The mines were exploited in extremely efficient and clever ways, according to the technology available (Jovanovic 1980, Craddock 1995, Timberlake 2003). The entire convenient mineral was collected and the abandoned shafts carefully refilled with gangue and rocks (Mohen 1992; 85). For example, at Mount Gabriel, it was estimated that they extracted the astonishing number of 32,570.15 tonnes (35,902.44 tons) of rock, gangue and ore. The usable amount of copper was 162.85 tonnes and the final smelting finished metal was 146.56 tonnes (Jackson 1980; 24). The entire process was thoroughly described in 1744 by Lewis Morris, Crown Mineral Agent for Cardiganshire, and, incidentally, antiquarian. [12]
Their method seems to be this. They make a great fire of wood in the bottom of their rakes which were always open up on that account, and when the rock was sufficiently hot they cast water upon it, which shiver’d it; and then with stone wedges, which they drove in with other stones, they work’d their way through the hardest rocks, tho’ but slowly.
The tools employed are mainly presented in Lewis' observations, but other ones have been recovered in archaeological context:
The information available about the people of the Copper Age has not substantially increased along with the number of archaeological sites. Several ideas have been proffered, one of the most followed is that the metal itself did not bring abrupt transformation into the people's life, [17] or even more that early copper does not produce anything useful at all, [18] meaning with this that with the copper, they produced mainly jewellery and, overall, weapons that obviously were not within reach of the majority of the population but only to privileged individuals. In other words, the real importance of the metal is not utilitarian but social. This is a suitable explanation about the rising of Great Cultures of Metal such as Vinča culture (Ex-Yugoslavia) Tiszapolgar and Unetice culture (Central Europe), Remedello and Rinaldone (Italy), Montagne Noire (France), El Argar and Targas (Spain), etc.
As the period moved forward, especially around the 3rd millennium, new and complex realities would appear strongly linked to the metal, like the impressive fortified villages of Los Millares (Spain), Vila Nova de Sao Pedro (Portugal) or the more modest cairn next to Copa Hill in the United Kingdom destinated to control the centres of extraction, or the equally and generalized cultural phenomenons of Megalithism, Rock Art, Bell Beakers Vessels that are known from Scandinavia to the South of Spain and from Scotland to Turkey.
Brass is an alloy of copper and zinc, in proportions which can be varied to achieve different colours and mechanical, electrical, acoustic and chemical properties, but copper typically has the larger proportion, generally 66% copper and 34% zinc. In use since prehistoric times, it is a substitutional alloy: atoms of the two constituents may replace each other within the same crystal structure.
The Chalcolithic was an archaeological period characterized by the increasing use of smelted copper. It followed the Neolithic and preceded the Bronze Age. It occurred at different periods in different areas, but was absent in some parts of the world, such as Russia, where there was no well-defined Copper Age between the Stone and Bronze ages. Stone tools were still predominantly used during this period.
Smelting is a process of applying heat and a chemical reducing agent to an ore to extract a desired base metal product. It is a form of extractive metallurgy that is used to obtain many metals such as iron, copper, silver, tin, lead and zinc. Smelting uses heat and a chemical reducing agent to decompose the ore, driving off other elements as gases or slag and leaving the metal behind. The reducing agent is commonly a fossil fuel source of carbon, such as carbon monoxide from incomplete combustion of coke—or, in earlier times, of charcoal. The oxygen in the ore binds to carbon at high temperatures as the chemical potential energy of the bonds in carbon dioxide is lower than that of the bonds in the ore.
A crucible is a ceramic or metal container in which metals or other substances may be melted or subjected to very high temperatures. Although crucibles have historically tended to be made out of clay, they can be made from any material that withstands temperatures high enough to melt or otherwise alter its contents.
Malachite is a copper carbonate hydroxide mineral, with the formula Cu2CO3(OH)2. This opaque, green-banded mineral crystallizes in the monoclinic crystal system, and most often forms botryoidal, fibrous, or stalagmitic masses, in fractures and deep, underground spaces, where the water table and hydrothermal fluids provide the means for chemical precipitation. Individual crystals are rare, but occur as slender to acicular prisms. Pseudomorphs after more tabular or blocky azurite crystals also occur.
Copper extraction refers to the methods used to obtain copper from its ores. The conversion of copper ores consists of a series of physical, chemical and electrochemical processes. Methods have evolved and vary with country depending on the ore source, local environmental regulations, and other factors.
Cupellation is a refining process in metallurgy in which ores or alloyed metals are treated under very high temperatures and subjected to controlled operations to separate noble metals, like gold and silver, from base metals, like lead, copper, zinc, arsenic, antimony, or bismuth, present in the ore. The process is based on the principle that precious metals typically oxidise or react chemically at much higher temperatures than base metals. When they are heated at high temperatures, the precious metals remain apart, and the others react, forming slags or other compounds.
The history of metallurgy in the Indian subcontinent began prior to the 3rd millennium BCE. Metals and related concepts were mentioned in various early Vedic age texts. The Rigveda already uses the Sanskrit term ayas. The Indian cultural and commercial contacts with the Near East and the Greco-Roman world enabled an exchange of metallurgic sciences. The advent of the Mughals further improved the established tradition of metallurgy and metal working in India. During the period of British rule in India, the metalworking industry in India stagnated due to various colonial policies, though efforts by industrialists led to the industry's revival during the 19th century.
Rudna Glava is a mining site in present-day eastern Serbia, a village and an archeological site.
A native metal is any metal that is found pure in its metallic form in nature. Metals that can be found as native deposits singly or in alloys include antimony, arsenic, bismuth, cadmium, chromium, cobalt, indium, iron, manganese, molybdenum, nickel, niobium, rhenium, selenium, tantalum, tellurium, tin, titanium, tungsten, vanadium, and zinc, as well as the gold group and the platinum group. Among the alloys found in native state have been brass, bronze, pewter, German silver, osmiridium, electrum, white gold, silver-mercury amalgam, and gold-mercury amalgam.
Kargaly is a copper mining-metallurgical district in the southern Urals of Russia. Prehistoric sites in Kargaly form a large and unique complex, especially when compared to neighboring metal production centers or the more distant ancient centers that emerged on the vast territory of the northern half of the Eurasian continent or supercontinent during the 5th to 2nd millennia BCE[1-8].
Fire-setting is a method of traditional mining used most commonly from prehistoric times up to the Middle Ages. Fires were set against a rock face to heat the stone, which was then doused with liquid, causing the stone to fracture by thermal shock. Rapid heating causes thermal shock by itself—without subsequent cooling—by producing different degrees of expansion in different parts of the rock. In practice, rapid cooling may or may not have been helpful to produce the desired effect. Some experiments have suggested that the water did not have a noticeable effect on the rock, but rather helped the miners' progress by quickly cooling down the area after the fire. This technique was best performed in opencast mines where the smoke and fumes could dissipate safely. The technique was very dangerous in underground workings without adequate ventilation. The method became largely redundant with the growth in use of explosives.
Metallurgy in pre-Columbian America is the extraction, purification and alloying of metals and metal crafting by Indigenous peoples of the Americas prior to European contact in the late 15th century. Indigenous Americans had been using native metals from ancient times, with recent finds of gold artifacts in the Andean region dated to 2155–1936 BC, and North American copper finds being dated to approximately 5000 BC. The metal would have been found in nature without the need for smelting, and shaped into the desired form using hot and cold hammering without chemical alteration or alloying. To date "no one has found evidence that points to the use of melting, smelting and casting in prehistoric eastern North America."
Mining archaeology is a specific field well-developed in the British Isles during recent decades. A reason of ongoing interest in this field is the particular bond between regional history and the exploitation of metals. References to mines in the area exist in Strabo's works. However the first accomplished study on the topic was attempted by Oliver Davies in 1935. Other momentous researches were that of geologist John S. Jackson about mines in Ireland and Lewis, Jones in Dolaucothi goldmine in Wales, and the pioneering work of Ronald F. Tylecote. Moreover, in the 1980s and 1990s a new generation of amateurs and scientists began investigations in different locations in the British Isles, including Duncan James on the Great Orme's Head, Simon Timberlake with the Early Mines Research Group at sites in Wales and William O'Brien in Ireland.
Metals and metal working had been known to the people of modern Italy since the Bronze Age. By 53 BC, Rome had expanded to control an immense expanse of the Mediterranean. This included Italy and its islands, Spain, Macedonia, Africa, Asia Minor, Syria and Greece; by the end of the Emperor Trajan's reign, the Roman Empire had grown further to encompass parts of Britain, Egypt, all of modern Germany west of the Rhine, Dacia, Noricum, Judea, Armenia, Illyria, and Thrace. As the empire grew, so did its need for metals.
Archaeometallurgical slag is slag discovered and studied in the context of archaeology. Slag, the byproduct of iron-working processes such as smelting or smithing, is left at the iron-working site rather than being moved away with the product. As it weathers well, it is readily available for study. The size, shape, chemical composition and microstructure of slag are determined by features of the iron-working processes used at the time of its formation.
Experimental archaeometallurgy is a subset of experimental archaeology that specifically involves past metallurgical processes most commonly involving the replication of copper and iron objects as well as testing the methodology behind the production of ancient metals and metal objects. Metals and elements used primarily as alloying materials, such as tin, lead, and arsenic, are also a part of experimental research.
The conservation and restoration of copper and copper-alloy objects is the preservation and protection of objects of historical and personal value made from copper or copper alloy. When applied to items of cultural heritage, this activity is generally undertaken by a conservator-restorer.
Non-ferrous extractive metallurgy is one of the two branches of extractive metallurgy which pertains to the processes of reducing valuable, non-iron metals from ores or raw material. Metals like zinc, copper, lead, aluminium as well as rare and noble metals are of particular interest in this field, while the more common metal, iron, is considered a major impurity. Like ferrous extraction, non-ferrous extraction primarily focuses on the economic optimization of extraction processes in separating qualitatively and quantitatively marketable metals from its impurities (gangue).
The Vilabouly Complex is an archaeological site that is located in the Savannakhet Province in Laos which holds copper smelting and copper mining during the Iron Age. The Vilabouly Complex is significant since it puts archaeologists in a predicament of when did the origin of bronze metallurgy begin in Southeast Asia. It was estimated that the site was around 400BC - AD 500 as well as 1000 - 400BC reaching both the Iron Age and Bronze Age of Southeast Asia.