Mercury(I) fluoride

Last updated
Mercury(I) fluoride
Mercury(I)-fluoride-3D-vdW.png
Names
IUPAC name
Dimercury difluoride
Other names
Mercury(I) fluoride
Mercurous fluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.302 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-747-9
PubChem CID
UNII
  • InChI=1S/2FH.2Hg/h2*1H;;/q;;2*+1/p-2
    Key: FQZUXVBMUHSNRN-UHFFFAOYSA-L
  • F[Hg][Hg]F
Properties
Hg2F2
Molar mass 439.177 g/mol
Appearanceyellow cubic crystals
Density 8.73 g/cm3, solid
decomposes [1]
3.1×106 [2]
26.5·10−6 cm3/mol
Hazards [3]
GHS labelling:
GHS-pictogram-skull.svg GHS-pictogram-silhouette.svg GHS-pictogram-pollu.svg
Danger
H300, H310, H330, H373, H410
NFPA 704 (fire diamond)
NFPA 704.svgHealth 4: Very short exposure could cause death or major residual injury. E.g. VX gasFlammability 0: Will not burn. E.g. waterInstability 0: Normally stable, even under fire exposure conditions, and is not reactive with water. E.g. liquid nitrogenSpecial hazards (white): no code
4
0
0
Flash point non-flammable
Related compounds
Other anions
Mercury(I) chloride
Mercury(I) bromide
Mercury(I) iodide
Other cations
Zinc fluoride
Cadmium fluoride
Related compounds
Mercury(II) fluoride
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
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Mercury(I) fluoride or mercurous fluoride is the chemical compound composed of mercury and fluorine with the formula Hg2F2. It consists of small yellow cubic crystals, which turn black when exposed to light. [1]

Contents

Synthesis

Mercury(I) fluoride is prepared by the reaction of mercury(I) carbonate with hydrofluoric acid:

Hg2CO3 + 2 HF → Hg2F2 + CO2 + H2O

Reactions

When added to water, mercury(I) fluoride hydrolyzes to elemental liquid mercury, mercury(II) oxide, and hydrofluoric acid: [1]

Hg2F2 + H2O → Hg + HgO + 2 HF

It can be used in the Swarts reaction to convert alkyl halides into alkyl fluorides: [4]

2 R-X + Hg2F2 → 2 R-F + Hg2X2
where X = Cl, Br, I

Structure

Unit cell of Hg2F2, with F from adjacent molecules coordinating the Hg atoms Unit cell of Hg2F2.png
Unit cell of Hg2F2, with F from adjacent molecules coordinating the Hg atoms

In common with other Hg(I) (mercurous) compounds which contain linear X-Hg-Hg-X units, Hg2F2 contains linear FHg2F units with an Hg-Hg bond length of 251 pm (Hg-Hg in the metal is 300 pm) and an Hg-F bond length of 214 pm. [5] The overall coordination of each Hg atom is a distorted octahedron; in addition to the bonded F and other Hg of the molecule, there are four other F atoms at 272 pm. [5] The compound is often formulated as Hg2+
2
[F]2
. [6]

Related Research Articles

<span class="mw-page-title-main">Hydrofluoric acid</span> Solution of hydrogen fluoride in water

Hydrofluoric acid is a solution of hydrogen fluoride (HF) in water. Solutions of HF are colorless, acidic and highly corrosive. It is used to make most fluorine-containing compounds; examples include the commonly used pharmaceutical antidepressant medication fluoxetine (Prozac) and the material PTFE (Teflon). Elemental fluorine is produced from it. It is commonly used to etch glass and silicon wafers.

Calcium fluoride is the inorganic compound of the elements calcium and fluorine with the formula CaF2. It is a white solid that is practically insoluble in water. It occurs as the mineral fluorite (also called fluorspar), which is often deeply coloured owing to impurities.

<span class="mw-page-title-main">Mercury(I) chloride</span> Chemical compound

Mercury(I) chloride is the chemical compound with the formula Hg2Cl2. Also known as the mineral calomel (a rare mineral) or mercurous chloride, this dense white or yellowish-white, odorless solid is the principal example of a mercury(I) compound. It is a component of reference electrodes in electrochemistry.

<span class="mw-page-title-main">Caesium fluoride</span> Chemical compound

Caesium fluoride or cesium fluoride is an inorganic compound with the formula CsF and it is a hygroscopic white salt. Caesium fluoride can be used in organic synthesis as a source of the fluoride anion. Caesium also has the highest electropositivity of all known elements and fluorine has the highest electronegativity of all known elements.

Boron trifluoride is the inorganic compound with the formula BF3. This pungent, colourless, and toxic gas forms white fumes in moist air. It is a useful Lewis acid and a versatile building block for other boron compounds.

<span class="mw-page-title-main">Phosphorous acid</span> Chemical compound (H3PO4)

Phosphorous acid is the compound described by the formula H3PO3. This acid is diprotic, not triprotic as might be suggested by this formula. Phosphorous acid is an intermediate in the preparation of other phosphorus compounds. Organic derivatives of phosphorous acid, compounds with the formula RPO3H2, are called phosphonic acids.

<span class="mw-page-title-main">Hydrogen fluoride</span> Chemical compound

Hydrogen fluoride (fluorane) is an inorganic compound with chemical formula HF. It is a very poisonous, colorless gas or liquid that dissolves in water to yield an aqueous solution termed hydrofluoric acid. It is the principal industrial source of fluorine, often in the form of hydrofluoric acid, and is an important feedstock in the preparation of many important compounds including pharmaceuticals and polymers, e.g. polytetrafluoroethylene (PTFE). HF is also widely used in the petrochemical industry as a component of superacids. Due to strong and extensive hydrogen bonding, it boils at near room temperature, much higher than other hydrogen halides.

<span class="mw-page-title-main">Ammonium bifluoride</span> Chemical compound

Ammonium bifluoride is the inorganic compound with the formula [NH4][HF2] or [NH4]F·HF. It is produced from ammonia and hydrogen fluoride. This colourless salt is a glass-etchant and an intermediate in a once-contemplated route to hydrofluoric acid.

<span class="mw-page-title-main">Aluminium fluoride</span> Chemical compound

Aluminium fluoride is an inorganic compound with the formula AlF3. It forms hydrates AlF3·xH2O. Anhydrous AlF3 and its hydrates are all colorless solids. Anhydrous AlF3 is used in the production of aluminium metal. Several occur as minerals.

The bifluoride ion is an inorganic anion with the chemical formula [HF2]. The anion is colorless. Salts of bifluoride are commonly encountered in the reactions of fluoride salts with hydrofluoric acid. The commercial production of fluorine involves electrolysis of bifluoride salts.

<span class="mw-page-title-main">Mercury(I) sulfate</span> Chemical compound

Mercury(I) sulfate, commonly called mercurous sulphate (UK) or mercurous sulfate (US) is the chemical compound Hg2SO4. Mercury(I) sulfate is a metallic compound that is a white, pale yellow or beige powder. It is a metallic salt of sulfuric acid formed by replacing both hydrogen atoms with mercury(I). It is highly toxic; it could be fatal if inhaled, ingested, or absorbed by skin.

<span class="mw-page-title-main">Mercury(I) iodide</span> Chemical compound

Mercury(I) iodide is a chemical compound of mercury and iodine. The chemical formula is Hg2I2. It is photosensitive and decomposes easily to mercury and HgI2.

Mercury(I) bromide or mercurous bromide is the chemical compound composed of mercury and bromine with the formula Hg2Br2. It changes color from white to yellow when heated and fluoresces a salmon color when exposed to ultraviolet light. It has applications in acousto-optical devices.

Mercury polycations are polyatomic cations that contain only mercury atoms. The best known example is the Hg2+
2
ion, found in mercury(I) (mercurous) compounds. The existence of the metal–metal bond in Hg(I) compounds was established using X-ray studies in 1927 and Raman spectroscopy in 1934 making it one of the earliest, if not the first, metal–metal covalent bonds to be characterised.

<span class="mw-page-title-main">Mercury(I) nitrate</span> Chemical compound

Mercury(I) nitrate is an inorganic compound, a salt of mercury and nitric acid with the formula Hg2(NO3)2. A yellow solid, the compound is used as a precursor to other Hg22+ complexes. The structure of the hydrate has been determined by X-ray crystallography. It consists of a [H2O-Hg-Hg-OH2]2+ center, with a Hg-Hg distance of 254 pm.

<span class="mw-page-title-main">Thionyl tetrafluoride</span> Chemical compound

Thionyl tetrafluoride, also known as sulfur tetrafluoride oxide, is an inorganic compound with the formula SOF4. It is a colorless gas.

<span class="mw-page-title-main">Germanium tetrafluoride</span> Chemical compound

Germanium tetrafluoride (GeF4) is a chemical compound of germanium and fluorine. It is a colorless gas.

In chemistry, molecular oxohalides (oxyhalides) are a group of chemical compounds in which both oxygen and halogen atoms are attached to another chemical element A in a single molecule. They have the general formula AOmXn, where X is a halogen. Known oxohalides have fluorine (F), chlorine (Cl), bromine (Br), and/or iodine (I) in their molecules. The element A may be a main group element, a transition element, a rare earth element or an actinide. The term oxohalide, or oxyhalide, may also refer to minerals and other crystalline substances with the same overall chemical formula, but having an ionic structure.

<span class="mw-page-title-main">Actinium(III) fluoride</span> Chemical compound

Actinium(III) fluoride (AcF3) is an inorganic compound, a salt of actinium and fluorine.

<span class="mw-page-title-main">Lutetium(III) fluoride</span> Chemical compound

Lutetium(III) fluoride is an inorganic compound with a chemical formula LuF3.

References

  1. 1 2 3 Perry, Dale L.; Phillips, Sidney L. (1995), Handbook of Inorganic Compounds, CRC Press, p. 256, ISBN   0-8493-8671-3 , retrieved 2008-06-17
  2. John Rumble (June 18, 2018). CRC Handbook of Chemistry and Physics (99 ed.). CRC Press. pp. 5–189. ISBN   978-1138561632.
  3. 339318 Mercury(I) fluoride technical grade, Sigma-Aldrich, retrieved 2008-06-17
  4. Beyer, Hans; Walter, Wolfgang; Lloyd, Douglas (1997), Organic Chemistry, Horwood Publishing, p. 136, ISBN   1-898563-37-3 , retrieved 2008-06-17
  5. 1 2 Wells A.F. (1984) Structural Inorganic Chemistry 5th edition Oxford Science Publications ISBN   0-19-855370-6
  6. Cotton, F. Albert; Wilkinson, Geoffrey; Murillo, Carlos A.; Bochmann, Manfred (1999), Advanced Inorganic Chemistry (6th ed.), New York: Wiley-Interscience, ISBN   0-471-19957-5