Barium chloride fluoride

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Barium chloride fluoride
Barium chloride fluoride structure.png
Names
Other names
Barium chlorofluoride
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.033.874 OOjs UI icon edit-ltr-progressive.svg
EC Number
  • 237-277-4
PubChem CID
  • InChI=1S/Ba.ClH.FH/h;2*1H/q+2;;/p-2
    Key: RBRFDGCVTRKUEW-UHFFFAOYSA-L
  • [F-].[Cl-].[Ba+2]
Properties
BaClF
Molar mass 191.78 g·mol−1
Appearancewhite crystals
Density g/cm3
Poorly soluble
Structure
Tetragonal
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).

Barium chloride fluoride is an inorganic chemical compound of barium, chlorine, and fluorine. [1] Its chemical formula is BaClF. [2] [3] The compound naturally occurs as zhangpeishanite mineral of the matlockite group. [4] One of the deposits where the mineral is mined is Bayan Obo in China. [5]

Contents

Synthesis

Barium fluoride can be prepared by precipitating barium chloride and ammonium fluoride in a solution.

Physical properties

Barium chloride fluoride forms white crystals. [6] The crystal structure of BaClF is a tetragonal distortion of that of fluoride type BaF
2
. [7]

The compound is poorly soluble in water. [8]

Related Research Articles

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<span class="mw-page-title-main">Caesium</span> Chemical element, symbol Cs and atomic number 55

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<span class="mw-page-title-main">Barium carbonate</span> Chemical compound

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<span class="mw-page-title-main">Barium chloride</span> Chemical compound

Barium chloride is an inorganic compound with the formula BaCl2. It is one of the most common water-soluble salts of barium. Like most other water-soluble barium salts, it is a white powder, highly toxic, and imparts a yellow-green coloration to a flame. It is also hygroscopic, converting to the dihydrate BaCl2·2H2O, which are colourless crystals with a bitter salty taste. It has limited use in the laboratory and industry.

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Barium fluoride is an inorganic compound with the formula BaF2. It is a colorless solid that occurs in nature as the rare mineral frankdicksonite. Under standard conditions it adopts the fluorite structure and at high pressure the PbCl2 structure. Like CaF2, it is resilient to and insoluble in water.

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<span class="mw-page-title-main">Barium ferrate</span> Chemical compound

Barium ferrate is the chemical compound of formula BaFeO4. This is a rare compound containing iron in the +6 oxidation state. The ferrate(VI) ion has two unpaired electrons, making it paramagnetic. It is isostructural with BaSO4, and contains the tetrahedral [FeO4]2− anion.

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Zhangpeishanite is a mineral named after Zhang Peishan, a Chinese mineralogist at the Institute of Geology of the Chinese Academy of Sciences, in recognition of his contributions to studying the mineralogy Bayan Obo deposit, where the mineral is mined. The Bayan Obo deposit is also known for being a world class deposit. The mineral got approved by the IMA in 2006 but was published two years after its approval. The mineral consists of barium chloride fluoride.

References

  1. Hagemann, H.; D’Anna, V.; Lawson Daku, M.; Kubel, F. (7 March 2012). "Crystal Chemistry in the Barium Fluoride Chloride System". Crystal Growth & Design . 12 (3): 1124–1131. doi:10.1021/cg201588s. ISSN   1528-7483 . Retrieved 26 March 2023.
  2. "System of Registries | US EPA". United States Environmental Protection Agency . Retrieved 26 March 2023.
  3. "CAS 13718-55-3 Barium chloride fluoride - Alfa Chemistry". Alfa Chemistry. Retrieved 26 March 2023.
  4. 英彦, 島崎; 律郎, 宮脇; 一己, 横山; 聰, 松原; 主明, 楊 (2007). "中国内モンゴル白雲鄂博産の新鉱物,張培善石". 日本鉱物科学会年会講演要旨集. 2007: 198. doi:10.14824/jakoka.2007.0.198.0 . Retrieved 27 March 2023.
  5. "Zhangpeishanite". mindat.org. Retrieved 27 March 2023.
  6. Lide, David R. (19 June 2003). 1998 Freshman Achievement Award. CRC Press. pp. 4–49. ISBN   978-0-8493-0594-8 . Retrieved 26 March 2023.
  7. Marcus, Philippe; Maurice, Vincent (25 May 2006). Passivation of Metals and Semiconductors, and Properties of Thin Oxide Layers: A Selection of Papers from the 9th International Symposium, Paris, France, 27 June - 1 July 2005. Elsevier. p. 150. ISBN   978-0-08-046152-6 . Retrieved 26 March 2023.
  8. Comey, Arthur Messinger (1896). A Dictionary of chemical solubilities. Macmillan and Company. p. 47. Retrieved 26 March 2023.