Dutch process cocoa

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Dutch processed cocoa
Dutch process and natural cocoa.jpg
Dutch process cocoa (left) compared to natural cocoa (right)
Alternative namesDutched cocoa
Type Cocoa
Place of origin Netherlands
Created by Coenraad Johannes van Houten
Main ingredientsCocoa powder, alkalizing agent

Dutch processed cocoa, Dutch cocoa, or alkalized cocoa, is cocoa solids that have been treated with an alkalizing agent to reduce the natural acidity of cocoa, giving it a less bitter taste (and darker colour) compared to "natural cocoa" extracted with the Broma process. It forms the basis for much of modern chocolate, and is used in ice cream, hot chocolate, and baking.

Contents

Alkalizing agents employed vary, but include potassium carbonate (E501), sodium carbonate (E500), and/or sodium hydroxide (E525).

Dutching greatly reduces the levels of certain phytochemicals in cocoa.

Baking chocolate, unsweetened, squares
Nutritional value per 100 g (3.5 oz)
Energy 922 kJ (220 kcal)
58.3 g
Sugars 1.76
Dietary fiber 29.8 g
Fat
13.1 g
18.1 g
Other constituentsQuantity
Water2.7 g
Caffeine 78 mg
Theobromine 2630 mg

Percentages estimated using US recommendations for adults, [1] except for potassium, which is estimated based on expert recommendation from the National Academies. [2]

History

The Dutch process was developed in the early 19th century by Dutch chocolate maker Coenraad Johannes van Houten, whose father Casparus was responsible for the development of the method of removing fat from cocoa beans by hydraulic press around 1828, forming the basis for cocoa powder. These developments greatly expanded the use of cocoa, and reduced the oiliness that was previously associated with cocoa. [3]

Colour

The quantity of alkalizing agent is not specified on the ingredients on cocoa powder. However, this may be figured out by comparing the brown shades between different products. Higher quantities of alkalizing agents will produce cocoa that is darker than cocoa with lower quantities.

Cooking properties

Dutch processed cocoa has a neutral pH, and is not acidic like natural cocoa, so in recipes that use sodium bicarbonate (baking soda) as the leavening agent (which relies on the acidity of the cocoa to activate it), an acid must be added to the recipe, such as cream of tartar or the use of buttermilk instead of fresh milk. There is no need to add acidity when natural cocoa is used in recipes that use baking powder instead of soda for leavening. [4]

Reduction of phytochemicals

Caffeine

Dutch cocoa contains 3 times less caffeine:

Antioxidants and flavonols

Compared to other processes, Dutch process cocoa contains lower amounts of flavonols (antioxidants). [7] The effect this has on nutritional value is disputed. Professor Irmgard Bitsch of the Institut für Ernährungswissenschaft, Justus-Liebig-University Giessen claims that the reduction of antioxidants due to the process is not significant and enough polyphenols and procyanidins remain in the cocoa. [8] One study determined that 60% of natural cocoa's original antioxidants were destroyed by light dutching and 90% were destroyed by heavy dutching. [9] Natural cocoa has such high levels of antioxidants that even a 60% reduction leaves it high on the list of antioxidant-rich foods. [10]

Related Research Articles

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Sodium bicarbonate (IUPAC name: sodium hydrogencarbonate), commonly known as baking soda or bicarbonate of soda, is a chemical compound with the formula NaHCO3. It is a salt composed of a sodium cation (Na+) and a bicarbonate anion (HCO3). Sodium bicarbonate is a white solid that is crystalline but often appears as a fine powder. It has a slightly salty, alkaline taste resembling that of washing soda (sodium carbonate). The natural mineral form is nahcolite. It is a component of the mineral natron and is found dissolved in many mineral springs.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Baking powder</span> Dry chemical leavening agent

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References

  1. United States Food and Drug Administration (2024). "Daily Value on the Nutrition and Supplement Facts Labels" . Retrieved 28 March 2024.
  2. National Academies of Sciences, Engineering, and Medicine; Health and Medicine Division; Food and Nutrition Board; Committee to Review the Dietary Reference Intakes for Sodium and Potassium (2019). Oria, Maria; Harrison, Meghan; Stallings, Virginia A. (eds.). Dietary Reference Intakes for Sodium and Potassium. The National Academies Collection: Reports funded by National Institutes of Health. Washington (DC): National Academies Press (US). ISBN   978-0-309-48834-1. PMID   30844154.{{cite book}}: CS1 maint: multiple names: authors list (link)
  3. Goldstein, D. (2015). The Oxford Companion to Sugar and Sweets. Oxford Companions. Oxford University Press. p. 762-763. ISBN   978-0-19-931339-6 . Retrieved 26 May 2023.
  4. "Cocoa Powder". Joyofbaking.com. Retrieved 27 May 2013.
  5. "FoodData Central". fdc.nal.usda.gov.
  6. "FoodData Central". fdc.nal.usda.gov.
  7. "Chocolate Terms". Thenibble.com. Retrieved 27 May 2013.
  8. "Kakao und Schokolade: Die geheimen Gesundmacher". medizinauskunft.de. Archived from the original on 14 May 2016. Retrieved 1 October 2016.
  9. "New study re-emphasizes natural cocoa powder has high antioxidant content". Eurekalert.org. 8 October 2008. Retrieved 27 May 2013.
  10. Crozier, S. J.; Preston, A. G.; Hurst, J. W.; Payne, M. J.; Mann, J.; Hainly, L.; Miller, D. L. (7 February 2011). "Cacao seeds are a "Super Fruit": A comparative analysis of various fruit powders and products". Chemistry Central Journal. 5 (5). Chem Cent J.: 5. doi: 10.1186/1752-153X-5-5 . PMC   3038885 . PMID   21299842.