Ecological impacts of explosives are the effects that both unexploded explosives and post-explosion by-products have on the environment. [1] Explosive derived contaminants may have adverse effects on the environmental as well as human health.
In addition to their military use in warfare, explosives are also used in construction and demolition. Of greatest concern to the environment are secondary explosives, such as TNT, RDX, and HMX because they are produced and used in the greatest quantities. [2]
Explosives and their residual post explosion products can partition between multiple environmental compartments including aquatic, soil, atmosphere, and the biosphere. [2] [3]
Explosives have important applications in the military and in both mining and construction work. In fact, the manufacture of explosives comprises a large amount of the chemical industry. [4] In the course of their production, handling, loading, and disposal, explosives are released into the environment. It is there that they are dispersed by mechanical processes or dissolved or volatilized and partially converted to secondary products. [4] Over the past 150 years, millions of tons of explosives have been produced for military applications and other activities that have led to the accidental contamination of energetic materials in the soil and groundwater. [5] Exact numbers cannot be obtained and estimations are generally conservative, because people make their own bombs, which is not a small activity in regions dealing with armed conflict. The United States Army had estimated that over 1.2 million tons of soils have been contaminated with explosives on their training grounds alone. In the year 2004, it was estimated that 2,520,000 metric tons of explosive agents were sold for consumption in the United States alone. [6] Figure 1 shows the world consumption of explosives in 2008. [7]
Generally, explosives are dispersed mainly when used in combat. Most explosives are used as warfare agents by militaries globally. However, modern uses for 2,4,6-trinitrotoluene (TNT) are associated with construction and demolition, rather than combat. Because of its use in construction and demolition, it has become perhaps the most widespread explosive, and thus its toxicity is the most characterized and reported. The concentration of TNT in contaminated soil can reach 50 g kg−1 of soil, where the highest concentrations can be found on or near the surface. In the last decade, the United States Environmental Protection Agency (USEPA) has declared TNT a pollutant whose removal is priority. [8] The USEPA maintains that TNT levels in soil should not exceed 17.2 gram per kilogram of soil and 0.01 milligrams per liter of water. [5]
Explosives and their post-explosion by-products may be degraded by abiotic processes that include hydrolysis, oxidation, or photolysis. Explosives may also be broken down through metabolism by microorganisms. [2]
RDX (abbreviation of "Research Department eXplosive" or Royal Demolition eXplosive) or hexogen, among other names, is an organic compound with the formula (CH2N2O2)3. It is white, odorless, and tasteless, widely used as an explosive. Chemically, it is classified as a nitroamine alongside HMX, which is a more energetic explosive than TNT. It was used widely in World War II and remains common in military applications.
Trinitrotoluene, more commonly known as TNT (and more specifically 2,4,6-trinitrotoluene, and by its preferred IUPAC name 2-methyl-1,3,5-trinitrobenzene), is a chemical compound with the formula C6H2(NO2)3CH3. TNT is occasionally used as a reagent in chemical synthesis, but it is best known as an explosive material with convenient handling properties. The explosive yield of TNT is considered to be the standard comparative convention of bombs and asteroid impacts. In chemistry, TNT is used to generate charge transfer salts.
2,4,6-Trinitrophenylmethylnitramine or tetryl (C7H5N5O8) is an explosive compound used to make detonators and explosive booster charges.
HMX, also called octogen, is a powerful and relatively insensitive nitroamine high explosive chemically related to RDX. The compound's name is the subject of much speculation, having been variously listed as High Melting Explosive, High-velocity Military Explosive, or High-Molecular-weight RDX.
Ammonium nitrate is a chemical compound with the formula NH4NO3. It is a white crystalline salt consisting of ions of ammonium and nitrate. It is highly soluble in water and hygroscopic as a solid, although it does not form hydrates. It is predominantly used in agriculture as a high-nitrogen fertilizer.
Environmental remediation is the cleanup of hazardous substances dealing with the removal, treatment and containment of pollution or contaminants from environmental media such as soil, groundwater, sediment. Remediation may be required by regulations before development of land revitalization projects. Developers who agree to voluntary cleanup may be offered incentives under state or municipal programs like New York State's Brownfield Cleanup Program. If remediation is done by removal the waste materials are simply transported off-site for disposal at another location. The waste material can also be contained by physical barriers like slurry walls. The use of slurry walls is well-established in the construction industry. The application of (low) pressure grouting, used to mitigate soil liquefaction risks in San Francisco and other earthquake zones, has achieved mixed results in field tests to create barriers, and site-specific results depend upon many variable conditions that can greatly impact outcomes.
Bioremediation broadly refers to any process wherein a biological system, living or dead, is employed for removing environmental pollutants from air, water, soil, flue gasses, industrial effluents etc., in natural or artificial settings. The natural ability of organisms to adsorb, accumulate, and degrade common and emerging pollutants has attracted the use of biological resources in treatment of contaminated environment. In comparison to conventional physicochemical treatment methods bioremediation may offer advantages as it aims to be sustainable, eco-friendly, cheap, and scalable.
Project Chariot was a 1958 United States Atomic Energy Commission proposal to construct an artificial harbor at Cape Thompson on the North Slope of the U.S. state of Alaska by burying and detonating a string of nuclear devices.
Phytoremediation technologies use living plants to clean up soil, air and water contaminated with hazardous contaminants. It is defined as "the use of green plants and the associated microorganisms, along with proper soil amendments and agronomic techniques to either contain, remove or render toxic environmental contaminants harmless". The term is an amalgam of the Greek phyto (plant) and Latin remedium. Although attractive for its cost, phytoremediation has not been demonstrated to redress any significant environmental challenge to the extent that contaminated space has been reclaimed.
Soil contamination, soil pollution, or land pollution as a part of land degradation is caused by the presence of xenobiotic (human-made) chemicals or other alteration in the natural soil environment. It is typically caused by industrial activity, agricultural chemicals or improper disposal of waste. The most common chemicals involved are petroleum hydrocarbons, polynuclear aromatic hydrocarbons, solvents, pesticides, lead, and other heavy metals. Contamination is correlated with the degree of industrialization and intensity of chemical substance. The concern over soil contamination stems primarily from health risks, from direct contact with the contaminated soil, vapour from the contaminants, or from secondary contamination of water supplies within and underlying the soil. Mapping of contaminated soil sites and the resulting clean ups are time-consuming and expensive tasks, and require expertise in geology, hydrology, chemistry, computer modelling, and GIS in Environmental Contamination, as well as an appreciation of the history of industrial chemistry.
TNT equivalent is a convention for expressing energy, typically used to describe the energy released in an explosion. The ton of TNT is a unit of energy defined by convention to be 4.184 gigajoules, which is the approximate energy released in the detonation of a metric ton of TNT. In other words, for each gram of TNT exploded, 4.184 kilojoules of energy are released.
Weldon Spring Ordnance Works (WSOW) was a 17,323-acre (70.10 km2) U.S. Government-owned, contractor-operated (GOCO) facility in St. Charles County, Missouri, 55 km west of St. Louis. The site was originally operated by the Atlas Powder Company during World War II from 1941 to 1945 to produce explosives. The Atomic Energy Commission acquired part of the property in 1955, and Mallinckrodt, Inc. processed uranium ore from 1957 to 1966 under contract. The site has been divided into several parcels, and ownership has transferred over the years. Two portions of the original WSOW property are now Superfund sites that require substantial cleanup efforts. The environmental remediation of the WSOW site is currently designated as a major project of the Defense Environmental Restoration Program of the United States Department of Defense. Part of the original property is still used by the Army Reserve as the Weldon Spring Training Area.
The environment of Russia
Environmental impact of mining can occur at local, regional, and global scales through direct and indirect mining practices. Mining can cause erosion, sinkholes, loss of biodiversity, or the contamination of soil, groundwater, and surface water by chemicals emitted from mining processes. These processes also affect the atmosphere through carbon emissions which contributes to climate change.
The Louisiana Army Ammunition Plant, formerly known as the Louisiana Ordnance Plant or as The Shell Plant, is an inactive 14,974-acre (60.60 km2) plant to load, assemble and pack ammunitions items. During production from 1942 to 1994, the Army disposed of untreated explosives-laden wastewater in on-site lagoons, contaminating soil, sediments and groundwater with hazardous chemicals. It is a government-owned, contractor-operated facility located off U.S. Highway 80 in Webster Parish near Doyline between Minden and Bossier City, Louisiana. Part of LAAP is known as Camp Minden, a training center for the Louisiana Army National Guard. LAAP and Camp Minden have become nearly interchangeable terms, with most references to Camp Minden.
In situ chemical oxidation (ISCO), a form of advanced oxidation process, is an environmental remediation technique used for soil and/or groundwater remediation to lower the concentrations of targeted environmental contaminants to acceptable levels. ISCO is accomplished by introducing strong chemical oxidizers into the contaminated medium to destroy chemical contaminants in place. It can be used to remediate a variety of organic compounds, including some that are resistant to natural degradation. The in situ in ISCO is just Latin for "in place", signifying that ISCO is a chemical oxidation reaction that occurs at the site of the contamination.
Brownfields are defined by the Environmental Protection Agency (EPA) as properties that are complicated by the potential presence of pollutants or otherwise hazardous substances. The pollutants such as heavy metals, polychlorinated biphenyls (PCB), poly- and per-fluoroalkyl substances (PFAS), and volatile organic compounds (VOCs) contaminating these sites are typically due to commercial or industrial work that was previously done on the land. This includes locations such as abandoned gas stations, laundromats, factories, and mills. By a process called land revitalization, these once polluted sites can be remediated into locations that can be utilized by the public.
Pollution-induced community tolerance (PICT) is an approach to measuring the response of pollution-induced selective pressures on a community. It is an eco-toxicological tool that approaches community tolerance to pollution from a holistic standpoint. Community Tolerance can increase in one of three ways: physical adaptations or phenotypic plasticity, selection of favorable genotypes, and the replacement of sensitive species by tolerant species in a community.
Persistent, bioaccumulative and toxic substances (PBTs) are a class of compounds that have high resistance to degradation from abiotic and biotic factors, high mobility in the environment and high toxicity. Because of these factors PBTs have been observed to have a high order of bioaccumulation and biomagnification, very long retention times in various media, and widespread distribution across the globe. Most PBTs in the environment are either created through industry or are unintentional byproducts.
Contaminants of emerging concern (CECs) is a term used by water quality professionals to describe pollutants that have been detected in environmental monitoring samples, that may cause ecological or human health impacts, and typically are not regulated under current environmental laws. Sources of these pollutants include agriculture, urban runoff and ordinary household products and pharmaceuticals that are disposed to sewage treatment plants and subsequently discharged to surface waters.
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