Bentonite is an absorbent aluminium phyllosilicate generally impure clay consisting mostly of montmorillonite. There are a few types of bentonites and their names depend on the dominant elements, such as potassium, sodium, calcium, and aluminium. As noted in several places in the geologic literature, there are some nomenclatorial problems with the classification of bentonite clays.
Bentonite usually forms from weathering of volcanic ash, most often in the presence of water. However, the term bentonite, as well as a similar clay called tonstein, have been used for clay beds of uncertain origin. For industrial purposes, two main classes of bentonite exist: sodium bentonite and calcium bentonite.
In stratigraphy and tephrochronology, completely devitrified (weathered volcanic glass) ash-fall beds are commonly referred to as K-bentonites when the dominant clay species is illite. Other common clay species, and sometimes dominant, are montmorillonite and kaolinite. Kaolinite dominated clays are commonly referred to as tonsteins and are typically associated with coal.
This is a list of countries by bentonite production (tonnes) in 2006 mostly based on British Geological Survey accessed in June 2008.
* indicates "Natural resources of COUNTRY or TERRITORY" links.
Country (or area) | Production |
---|---|
World | 14,600,000 |
United States | 4,620,000 |
China * | 3,200,000 |
Greece | 1,100,000 |
India * | [1] 1,081,000 |
Turkey * | 600,000 |
Russia * | 500,000 |
Italy * | 470,000 |
Mexico | 435,273 |
Brazil * | 419,214 |
Germany | 363,998 |
Argentina * | 256,165 |
Czech Republic | 220,000 |
Iran * | 186,323 |
Spain | 160,000 |
Cyprus | 150,620 |
Australia | 135,000 |
Bulgaria | 134,500 |
Slovakia | 95,700 |
Poland * | 93,880 |
South Korea * | 61,137 |
Azerbaijan * | 40,600 |
South Africa * | 32,878 |
Algeria | 27,110 |
Ukraine * | 25,000 |
Bosnia and Herzegovina * | 24,050 |
North Macedonia * | 20,353 |
Romania * | 20,229 |
Pakistan * | 20,000 |
Vietnam * | 20,000 |
Denmark * | 19,011 |
Croatia | 16,410 |
Uzbekistan * | 15,000 |
Peru * | 14,590 |
Colombia * | 8,500 |
Hungary * | 6,635 |
Egypt * | 6,300 |
Nicaragua | 6,300 |
Indonesia * | 5,000 |
Georgia | 4,487 |
Philippines * | 3,600 |
New Zealand | 3,028 |
Thailand * | 1,200 |
Burma * | 800 |
Armenia * | 720 |
Mozambique * | 610 |
Bauxite is a sedimentary rock with a relatively high aluminium content. It is the world's main source of aluminium and gallium. Bauxite consists mostly of the aluminium minerals gibbsite (Al(OH)3), boehmite (γ-AlO(OH)) and diaspore (α-AlO(OH)), mixed with the two iron oxides goethite (FeO(OH)) and haematite (Fe2O3), the aluminium clay mineral kaolinite (Al2Si2O5(OH)4) and small amounts of anatase (TiO2) and ilmenite (FeTiO3 or FeO.TiO2). Bauxite appears dull in luster and is reddish-brown, white, or tan.
Kaolinite ( KAY-ə-lə-nete, -lih-; also called kaolin) is a clay mineral, with the chemical composition Al2Si2O5(OH)4. It is a layered silicate mineral, with one tetrahedral sheet of silica (SiO4) linked through oxygen atoms to one octahedral sheet of alumina (AlO6).
Clay is a type of fine-grained natural soil material containing clay minerals (hydrous aluminium phyllosilicates, e.g. kaolinite, Al2Si2O5(OH)4). Clays develop plasticity when wet but can be hardened through firing. Most pure clay minerals are white or light-colored, but natural clays show a variety of colors from impurities, such as a reddish or brownish color from small amounts of iron oxide.
Feldspar is a group of rock-forming aluminium tectosilicate minerals, also containing other cations such as sodium, calcium, potassium, or barium. The most common members of the feldspar group are the plagioclase (sodium-calcium) feldspars and the alkali (potassium-sodium) feldspars. Feldspars make up about 60% of the Earth's crust, and 41% of the Earth's continental crust by weight.
Weathering is the deterioration of rocks, soils and minerals through contact with water, atmospheric gases, sunlight, and biological organisms. Weathering occurs in situ, and so is distinct from erosion, which involves the transport of rocks and minerals by agents such as water, ice, snow, wind, waves and gravity.
Bentonite is an absorbent swelling clay consisting mostly of montmorillonite which can either be Na-montmorillonite or Ca-montmorillonite. Na-montmorillonite has a considerably greater swelling capacity than Ca-montmorillonite.
Fuller's earth is a term for various clays used as an absorbent, filter, or bleaching agent. Products labeled Fuller's earth typically consist of palygorskite (attapulgite) or bentonite. Primary modern uses include as absorbents for oil, grease, and animal waste, and as a carrier for pesticides and fertilizers. Minor uses include filtering, clarifying, and decolorizing; as an active and inactive ingredient in beauty products; and as a filler in paint, plaster, adhesives, and pharmaceuticals. It also has a number of uses in the film industry and on stage.
Montmorillonite is a very soft phyllosilicate group of minerals that form when they precipitate from water solution as microscopic crystals, known as clay. It is named after Montmorillon in France. Montmorillonite, a member of the smectite group, is a 2:1 clay, meaning that it has two tetrahedral sheets of silica sandwiching a central octahedral sheet of alumina. The particles are plate-shaped with an average diameter around 1 μm and a thickness of 0.96 nm; magnification of about 25,000 times, using an electron microscope, is required to resolve individual clay particles. Members of this group include saponite, nontronite, beidellite, and hectorite.
Palygorskite or attapulgite is a magnesium aluminium phyllosilicate with the chemical formula (Mg,Al)2Si4O10(OH)·4(H2O) that occurs in a type of clay soil common to the Southeastern United States. It is one of the types of fuller's earth. Some smaller deposits of this mineral can be found in Mexico, where its use is tied to the manufacture of Maya blue in pre-Columbian times.
A smectite is a mineral mixture of various swelling sheet silicates (phyllosilicates), which have a three-layer 2:1 (TOT) structure and belong to the clay minerals. Smectites mainly consist of montmorillonite, but can often contain secondary minerals such as quartz and calcite.
Halloysite is an aluminosilicate clay mineral with the empirical formula Al2Si2O5(OH)4. Its main constituents are oxygen (55.78%), silicon (21.76%), aluminium (20.90%), and hydrogen (1.56%). It is a member of the kaolinite group. Halloysite typically forms by hydrothermal alteration of alumino-silicate minerals. It can occur intermixed with dickite, kaolinite, montmorillonite and other clay minerals. X-ray diffraction studies are required for positive identification. It was first described in 1826, and subsequently named after, the Belgian geologist Omalius d'Halloy.
Seatearth is a British coal mining term that is used in the geological literature. As noted by Jackson, a seatearth is the layer of sedimentary rock underlying a coal seam. Seatearths have also been called seat earth, "seat rock", or "seat stone" in the geologic literature. Depending on its physical characteristics, a number of different names, such as underclay, fireclay, flint clay, and ganister, can be applied to a specific seatearth.
Zeolite facies describes the mineral assemblage resulting from the pressure and temperature conditions of low-grade metamorphism.
Hectorite is a rare soft, greasy, white clay mineral with a chemical formula of Na0.3(Mg,Li)3Si4O10(OH)2.
Alkali, or Alkaline, soils are clay soils with high pH, a poor soil structure and a low infiltration capacity. Often they have a hard calcareous layer at 0.5 to 1 metre depth. Alkali soils owe their unfavorable physico-chemical properties mainly to the dominating presence of sodium carbonate, which causes the soil to swell and difficult to clarify/settle. They derive their name from the alkali metal group of elements, to which sodium belongs, and which can induce basicity. Sometimes these soils are also referred to as alkaline sodic soils.
Alkaline soils are basic, but not all basic soils are alkaline.
This glossary of geology is a list of definitions of terms and concepts relevant to geology, its sub-disciplines, and related fields. For other terms related to the Earth sciences, see Glossary of geography terms.
Tonstein is a hard, compact sedimentary rock that is composed mainly of kaolinite or, less commonly, other clay minerals such as montmorillonite and illite. The clays often are cemented by iron oxide minerals, carbonaceous matter, or chlorite. Tonsteins form from volcanic ash deposited in swamps. Tonsteins occur as distinctive, thin, and laterally extensive layers in coal seams throughout the world. They are often used as key beds to correlate the strata in which they are found. The regional persistence of tonsteins and relict phenocrysts indicate that they formed as the result of the diagenetic alteration of volcanic ash falls in an acidic and low-salinity environment, consistent with a freshwater swamp. In contrast, the alteration of a volcanic ashfall deposit in a marine environment typically produces a bentonite layer.
The Benton Shale is a geologic formation name historically used in Montana, Wyoming, North Dakota, South Dakota, Colorado, Kansas, and Nebraska. In the "mile high" plains in the center of the continent, the named layers preserve marine fossils from the Late Cretaceous Period. The term Benton Limestone has also been used to refer to the chalky portions of the strata, especially the beds of the strata presently classified as Greenhorn Limestone, particularly the Fencepost limestone.
Bauxite mining in the United States produced an estimated 128,000 metric tonnes of bauxite in 2013. Although the United States was an important source of bauxite in the early 20th century, it now supplies less than one percent of world bauxite production.
The soil matrix is the solid phase of soils, and comprise the solid particles that make up soils. Soil particles can be classified by their chemical composition (mineralogy) as well as their size. The particle size distribution of a soil, its texture, determines many of the properties of that soil, in particular hydraulic conductivity and water potential, but the mineralogy of those particles can strongly modify those properties. The mineralogy of the finest soil particles, clay, is especially important.