Pultrusion

Last updated

Pultrusion is a continuous process for manufacture of fibre-reinforced plastics with constant cross-section. The term is a portmanteau word, combining "pull" and "extrusion". As opposed to extrusion, which pushes the material, pultrusion pulls the material.

Contents

A very early pultrusions type patent was filed by J.H. Watson in 1944. This was followed by M.J. Meek's filing of 1950. The first commercial pultrusions were provided by Glastic Company of Cleveland, Ohio under the patent filed in 1952 by Rodger B. White. The patent issued to W. B. Goldsworthy in 1959 helped initiate the promotion and knowledge spread within the industry. W. Brandt Goldsworthy is widely regarded as the inventor of pultrusion. [1]

Parallel to the work of Goldsworthy, who concentrated his work on unsaturated polyester resins, Ernst Kühne in Germany developed a quite similar process in 1954 based on epoxy resin.

Invention, development and the issuance of patents continue in the pultrusion field through today. A later innovation in this field has been developed and patented by Thomas GmbH + Co. Technik + Innovation KG in Germany 2008 and is described below.

Process

Diagram of the pultrusion process.
Continuous roll of reinforced fibers/woven fiber mat
Tension roller
Resin impregnator
Resin soaked fiber
Die and heat source
Pull mechanism
Finished hardened fiber reinforced polymer Pultrusion process 01.png
Diagram of the pultrusion process.
  1. Continuous roll of reinforced fibers/woven fiber mat
  2. Tension roller
  3. Resin impregnator
  4. Resin soaked fiber
  5. Die and heat source
  6. Pull mechanism
  7. Finished hardened fiber reinforced polymer

In the standard pultrusion process the reinforcement materials like fibers or woven or braided strands are impregnated with resin, possibly followed by a separate preforming system, and pulled through a heated stationary die where the resin undergoes polymerization. The impregnation is either done by pulling the reinforcement through a bath or by injecting the resin into an injection chamber which typically is connected to the die. Many resin types may be used in pultrusion including polyester, polyurethane, vinylester and epoxy. Resin provides the resistance to the environment, (i.e., the corrosion resistance, the UV resistance, the impact resistance, etc.) and the glass provides strength, in addition to safety from fire.

A surface veil can also be added to protect against erosion or “fiber bloom” and provide corrosion resistance and ultraviolet resistance. [2]

The technology is not limited to thermosetting polymers. More recently, pultrusion has been successfully used with thermoplastic matrices such as polybutylene terephthalate (PBT), polyethylene terephthalate (PET) either by powder impregnation of the glass fiber or by surrounding it with sheet material of the thermoplastic matrix, which is then heated. Engineered Composites Ltd in the UK has led the improvements in the process over the last 38 years working with major production houses and universities.

Ecological cleanness of manufactured products, in contrast to composites on thermosetting resins base, as well as practically unlimited possibilities of recycling (processing) after the resource depletion appear to be forcible arguments in favor of reinforced thermoplastics. For these reasons the industrial output and use of the given materials in highly industrialized countries have increased by 8–10% per year in recent decades. New developments (see process modifications) which enable the manufacturing not only of straight but also curved profiles are actually pushing the demand for this technology, especially in the automotive sector.

Pultrusion technology of manufacturing of fiber composites with polymer matrix appears to be energy-efficient and resource-saving.

Economic and environmental factors favor use of a thermoplastic matrix but due to the high viscosity of melts it is difficult to achieve high productivity and high quality of fiberfills impregnation with this type of matrix.

Products manufactured under this technology are widely used in the following industries:

Process modifications

As the materials are pulled through a die in the standard pultrusion process the process is only suited to manufacture straight profiles.

In a recently developed modification of the process, developed and patented by Thomas GmbH + Co. Technik + Innovation KG, the die is no longer stationary but moving back and forth along the profile to be manufactured. This modified process, known as "Radius-Pultrusion" allows also to manufacture two- and three-dimensional curved profiles. It also is beneficiary for a number of tasks in the linear process especially if quite complex textile reinforcements with a low rate of distortion are needed.

Flexible pultruded 3D-profile Flexible pultruded profile.png
Flexible pultruded 3D-profile

Process Steps Radius-Pultrusion.png

Equipment

The design of pultrusion machines varies. Two often used types are reciprocating (hand-over-hand) and continuous (cat-track).

For the radius pultrusion process the layout of the machines has two moving stages similar to the hand over hand pulling unit, but as the process is intermittent with only one puller and the mould mounted on the stage of other one. Whether the stages are moving linear or circular depends on the type of profiles to be manufactured. The minimum radius for a linear machine with rotating stages is approx. 2 m. For smaller radii a circular movement of the mould and gripper stage is necessary.

Related Research Articles

<span class="mw-page-title-main">Composite material</span> Material made from a combination of two or more unlike substances

A composite material is a material which is produced from two or more constituent materials. These constituent materials have notably dissimilar chemical or physical properties and are merged to create a material with properties unlike the individual elements. Within the finished structure, the individual elements remain separate and distinct, distinguishing composites from mixtures and solid solutions. Composite materials with more than one distinct layer are called composite laminates.

Fiberglass or fibreglass is a common type of fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth. The plastic matrix may be a thermoset polymer matrix—most often based on thermosetting polymers such as epoxy, polyester resin, or vinyl ester resin—or a thermoplastic.

<span class="mw-page-title-main">Epoxy</span> Type of material

Epoxy is the family of basic components or cured end products of epoxy resins. Epoxy resins, also known as polyepoxides, are a class of reactive prepolymers and polymers which contain epoxide groups. The epoxide functional group is also collectively called epoxy. The IUPAC name for an epoxide group is an oxirane.

<span class="mw-page-title-main">Thermosetting polymer</span> Polymer obtained by irreversibly hardening (curing) a resin

In materials science, a thermosetting polymer, often called a thermoset, is a polymer that is obtained by irreversibly hardening ("curing") a soft solid or viscous liquid prepolymer (resin). Curing is induced by heat or suitable radiation and may be promoted by high pressure or mixing with a catalyst. Heat is not necessarily applied externally, and is often generated by the reaction of the resin with a curing agent. Curing results in chemical reactions that create extensive cross-linking between polymer chains to produce an infusible and insoluble polymer network.

Fibre-reinforced plastic is a composite material made of a polymer matrix reinforced with fibres. The fibres are usually glass, carbon, aramid, or basalt. Rarely, other fibres such as paper, wood, boron, or asbestos have been used. The polymer is usually an epoxy, vinyl ester, or polyester thermosetting plastic, though phenol formaldehyde resins are still in use.

<span class="mw-page-title-main">Pre-preg</span> Composite material

Pre-preg is a composite material made from "pre-impregnated" fibers and a partially cured polymer matrix, such as epoxy or phenolic resin, or even thermoplastic mixed with liquid rubbers or resins. The fibers often take the form of a weave and the matrix is used to bond them together and to other components during manufacture. The thermoset matrix is only partially cured to allow easy handling; this B-Stage material requires cold storage to prevent complete curing. B-Stage pre-preg is always stored in cooled areas since heat accelerates complete polymerization. Hence, composite structures built of pre-pregs will mostly require an oven or autoclave to cure. The main idea behind a pre-preg material is the use of anisotropic mechanical properties along the fibers, while the polymer matrix provides filling properties, keeping the fibers in a single system.

Filament winding is a fabrication technique mainly used for manufacturing open (cylinders) or closed end structures. This process involves winding filaments under tension over a rotating mandrel. The mandrel rotates around the spindle while a delivery eye on a carriage traverses horizontally in line with the axis of the rotating mandrel, laying down fibers in the desired pattern or angle to the rotational axis. The most common filaments are glass or carbon and are impregnated with resin by passing through a bath as they are wound onto the mandrel. Once the mandrel is completely covered to the desired thickness, the resin is cured. Depending on the resin system and its cure characteristics, often the mandrel is autoclaved or heated in an oven or rotated under radiant heaters until the part is cured. Once the resin has cured, the mandrel is removed or extracted, leaving the hollow final product. For some products such as gas bottles, the 'mandrel' is a permanent part of the finished product forming a liner to prevent gas leakage or as a barrier to protect the composite from the fluid to be stored.

<span class="mw-page-title-main">Polyester</span> Category of polymers, in which the monomers are joined together by ester links

Polyester is a category of polymers that contain one or two ester linkages in every repeat unit of their main chain. As a specific material, it most commonly refers to a type called polyethylene terephthalate (PET). Polyesters include naturally occurring chemicals, such as in plants and insects, as well as synthetics such as polybutyrate. Natural polyesters and a few synthetic ones are biodegradable, but most synthetic polyesters are not. Synthetic polyesters are used extensively in clothing.

Polyester resins are synthetic resins formed by the reaction of dibasic organic acids and polyhydric alcohols. Maleic anhydride is a commonly used raw material with diacid functionality in unsaturated polyester resins. Unsaturated polyester resins are used in sheet moulding compound, bulk moulding compound and the toner of laser printers. Wall panels fabricated from polyester resins reinforced with fiberglass—so-called fiberglass reinforced plastic (FRP)—are typically used in restaurants, kitchens, restrooms and other areas that require washable low-maintenance walls. They are also used extensively in cured-in-place pipe applications. Departments of Transportation in the USA also specify them for use as overlays on roads and bridges. In this application they are known AS Polyester Concrete Overlays (PCO). These are usually based on isophthalic acid and cut with styrene at high levels—usually up to 50%. Polyesters are also used in anchor bolt adhesives though epoxy based materials are also used. Many companies have and continue to introduce styrene free systems mainly due to odor issues, but also over concerns that styrene is a potential carcinogen. Drinking water applications also prefer styrene free. Most polyester resins are viscous, pale coloured liquids consisting of a solution of a polyester in a reactive diluent which is usually styrene, but can also include vinyl toluene and various acrylates.

Polymer engineering is generally an engineering field that designs, analyses, and modifies polymer materials. Polymer engineering covers aspects of the petrochemical industry, polymerization, structure and characterization of polymers, properties of polymers, compounding and processing of polymers and description of major polymers, structure property relations and applications.

A thermoset polymer matrix is a synthetic polymer reinforcement where polymers act as binder or matrix to secure in place incorporated particulates, fibres or other reinforcements. They were first developed for structural applications, such as glass-reinforced plastic radar domes on aircraft and graphite-epoxy payload bay doors on the Space Shuttle.

Carbon fiber-reinforced polymers, carbon-fibre-reinforced polymers, carbon-fiber-reinforced plastics, carbon-fiber reinforced-thermoplastic, also known as carbon fiber, carbon composite, or just carbon, are extremely strong and light fiber-reinforced plastics that contain carbon fibers. CFRPs can be expensive to produce, but are commonly used wherever high strength-to-weight ratio and stiffness (rigidity) are required, such as aerospace, superstructures of ships, automotive, civil engineering, sports equipment, and an increasing number of consumer and technical applications.

Fiberglass reinforced plastic grating is a composite material manufactured by combining a matrix of resin and fiberglass. Fiberglass grating does not corrode like steel grating and is therefore used in corrosive environments to reduce maintenance costs. It is used in a variety of applications including walkways and overhead platforms. FRP grating is a structural product that can be weight-bearing between spans.

In materials science, advanced composite materials (ACMs) are materials that are generally characterized by unusually high strength fibres with unusually high stiffness, or modulus of elasticity characteristics, compared to other materials, while bound together by weaker matrices. These are termed "advanced composite materials" in comparison to the composite materials commonly in use such as reinforced concrete, or even concrete itself. The high strength fibers are also low density while occupying a large fraction of the volume.

Glass-filled polymer, is a mouldable composite material. It comprises short glass fibers in a matrix of a polymer material. It is used to manufacture a wide range of structural components by injection or compression moulding. It is an ideal glass alternative that offers flexibility in the part, chemical resistance, shatter resistance and overall better durability.

A void or a pore is three-dimensional region that remains unfilled with polymer and fibers in a composite material. Voids are typically the result of poor manufacturing of the material and are generally deemed undesirable. Voids can affect the mechanical properties and lifespan of the composite. They degrade mainly the matrix-dominated properties such as interlaminar shear strength, longitudinal compressive strength, and transverse tensile strength. Voids can act as crack initiation sites as well as allow moisture to penetrate the composite and contribute to the anisotropy of the composite. For aerospace applications, a void content of approximately 1% is still acceptable, while for less sensitive applications, the allowance limit is 3-5%. Although a small increase in void content may not seem to cause significant issues, a 1-3% increase in void content of carbon fiber reinforced composite can reduce the mechanical properties by up to 20%

Transfer molding is a manufacturing process in which casting material is forced into a mold. Transfer molding is different from compression molding in that the mold is enclosed rather than open to the fill plunger resulting in higher dimensional tolerances and less environmental impact. Compared to injection molding, transfer molding uses higher pressures to uniformly fill the mold cavity. This allows thicker reinforcing fiber matrices to be more completely saturated by resin. Furthermore, unlike injection molding, the transfer mold casting material may start the process as a solid. This can reduce equipment costs and time dependency. The transfer process may have a slower fill rate than an equivalent injection molding process.

In materials science, a polymer matrix composite (PMC) is a composite material composed of a variety of short or continuous fibers bound together by a matrix of organic polymers. PMCs are designed to transfer loads between fibers of a matrix. Some of the advantages with PMCs include their light weight, high resistance to abrasion and corrosion, and high stiffness and strength along the direction of their reinforcements.

Implant resistance welding is a method used in welding to join thermoplastics and thermoplastic composites.

The Ensinger Group is a manufacturer engaged in the development and manufacture of compounds, semi-finished products, technical parts, composite materials and profiles made of engineering and high-performance plastics. The family-owned enterprise is represented in major industrial regions with manufacturing facilities or sales offices. The main office is located in Nufringen/Baden-Württemberg, Germany.

References

  1. "Brandt Goldsworthy: Composites Visionary"
  2. "Pultrusion Process | Pultrusion Manufacturing | Liberty Pultrusions".