Condensed matter physics |
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Diamagnetism is the property of materials that are repelled by a magnetic field; an applied magnetic field creates an induced magnetic field in them in the opposite direction, causing a repulsive force. In contrast, paramagnetic and ferromagnetic materials are attracted by a magnetic field. Diamagnetism is a quantum mechanical effect that occurs in all materials; when it is the only contribution to the magnetism, the material is called diamagnetic. In paramagnetic and ferromagnetic substances, the weak diamagnetic force is overcome by the attractive force of magnetic dipoles in the material. The magnetic permeability of diamagnetic materials is less than the permeability of vacuum, μ0. In most materials, diamagnetism is a weak effect which can be detected only by sensitive laboratory instruments, but a superconductor acts as a strong diamagnet because it entirely expels any magnetic field from its interior (the Meissner effect).
Diamagnetism was first discovered when Anton Brugmans observed in 1778 that bismuth was repelled by magnetic fields. [1] In 1845, Michael Faraday demonstrated that it was a property of matter and concluded that every material responded (in either a diamagnetic or paramagnetic way) to an applied magnetic field. On a suggestion by William Whewell, Faraday first referred to the phenomenon as diamagnetic (the prefix dia- meaning through or across), then later changed it to diamagnetism. [2] [3]
A simple rule of thumb is used in chemistry to determine whether a particle (atom, ion, or molecule) is paramagnetic or diamagnetic: [4] If all electrons in the particle are paired, then the substance made of this particle is diamagnetic; If it has unpaired electrons, then the substance is paramagnetic.
Diamagnetism is a property of all materials, and always makes a weak contribution to the material's response to a magnetic field. However, other forms of magnetism (such as ferromagnetism or paramagnetism) are so much stronger such that, when different forms of magnetism are present in a material, the diamagnetic contribution is usually negligible. Substances where the diamagnetic behaviour is the strongest effect are termed diamagnetic materials, or diamagnets. Diamagnetic materials are those that some people generally think of as non-magnetic, and include water, wood, most organic compounds such as petroleum and some plastics, and many metals including copper, particularly the heavy ones with many core electrons, such as mercury, gold and bismuth. The magnetic susceptibility values of various molecular fragments are called Pascal's constants (named after Paul Pascal ).
Diamagnetic materials, like water, or water-based materials, have a relative magnetic permeability that is less than or equal to 1, and therefore a magnetic susceptibility less than or equal to 0, since susceptibility is defined as χv = μv − 1. This means that diamagnetic materials are repelled by magnetic fields. However, since diamagnetism is such a weak property, its effects are not observable in everyday life. For example, the magnetic susceptibility of diamagnets such as water is χv = −9.05×10−6. The most strongly diamagnetic material is bismuth, χv = −1.66×10−4, although pyrolytic carbon may have a susceptibility of χv = −4.00×10−4 in one plane. Nevertheless, these values are orders of magnitude smaller than the magnetism exhibited by paramagnets and ferromagnets. Because χv is derived from the ratio of the internal magnetic field to the applied field, it is a dimensionless value.
In rare cases, the diamagnetic contribution can be stronger than paramagnetic contribution. This is the case for gold, which has a magnetic susceptibility less than 0 (and is thus by definition a diamagnetic material), but when measured carefully with X-ray magnetic circular dichroism, has an extremely weak paramagnetic contribution that is overcome by a stronger diamagnetic contribution. [5]
Material | χv [× 10−5 (SI units)] |
---|---|
Superconductor | −105 |
Pyrolytic carbon | −40.9 |
Bismuth | −16.6 |
Neon | −6.74 |
Mercury | −2.9 |
Silver | −2.6 |
Carbon (diamond) | −2.1 |
Lead | −1.8 |
Carbon (graphite) | −1.6 |
Copper | −1.0 |
Water | −0.91 |
Superconductors may be considered perfect diamagnets (χv = −1), because they expel all magnetic fields (except in a thin surface layer) due to the Meissner effect. [7]
If a powerful magnet (such as a supermagnet) is covered with a layer of water (that is thin compared to the diameter of the magnet) then the field of the magnet significantly repels the water. This causes a slight dimple in the water's surface that may be seen by a reflection in its surface. [8] [9]
Diamagnets may be levitated in stable equilibrium in a magnetic field, with no power consumption. Earnshaw's theorem seems to preclude the possibility of static magnetic levitation. However, Earnshaw's theorem applies only to objects with positive susceptibilities, such as ferromagnets (which have a permanent positive moment) and paramagnets (which induce a positive moment). These are attracted to field maxima, which do not exist in free space. Diamagnets (which induce a negative moment) are attracted to field minima, and there can be a field minimum in free space.
A thin slice of pyrolytic graphite, which is an unusually strongly diamagnetic material, can be stably floated in a magnetic field, such as that from rare earth permanent magnets. This can be done with all components at room temperature, making a visually effective and relatively convenient demonstration of diamagnetism.
The Radboud University Nijmegen, the Netherlands, has conducted experiments where water and other substances were successfully levitated. Most spectacularly, a live frog (see figure) was levitated. [11]
In September 2009, NASA's Jet Propulsion Laboratory (JPL) in Pasadena, California announced it had successfully levitated mice using a superconducting magnet, [12] an important step forward since mice are closer biologically to humans than frogs. [13] JPL said it hopes to perform experiments regarding the effects of microgravity on bone and muscle mass.
Recent experiments studying the growth of protein crystals have led to a technique using powerful magnets to allow growth in ways that counteract Earth's gravity. [14]
A simple homemade device for demonstration can be constructed out of bismuth plates and a few permanent magnets that levitate a permanent magnet. [15]
The electrons in a material generally settle in orbitals, with effectively zero resistance and act like current loops. Thus it might be imagined that diamagnetism effects in general would be common, since any applied magnetic field would generate currents in these loops that would oppose the change, in a similar way to superconductors, which are essentially perfect diamagnets. However, since the electrons are rigidly held in orbitals by the charge of the protons and are further constrained by the Pauli exclusion principle, many materials exhibit diamagnetism, but typically respond very little to the applied field.
The Bohr–Van Leeuwen theorem proves that there cannot be any diamagnetism or paramagnetism in a purely classical system. However, the classical theory of Langevin for diamagnetism gives the same prediction as the quantum theory. [16] The classical theory is given below.
Paul Langevin's theory of diamagnetism (1905) [17] applies to materials containing atoms with closed shells (see dielectrics). A field with intensity B, applied to an electron with charge e and mass m, gives rise to Larmor precession with frequency ω = eB / 2m. The number of revolutions per unit time is ω / 2π, so the current for an atom with Z electrons is (in SI units) [16]
The magnetic moment of a current loop is equal to the current times the area of the loop. Suppose the field is aligned with the z axis. The average loop area can be given as , where is the mean square distance of the electrons perpendicular to the z axis. The magnetic moment is therefore
If the distribution of charge is spherically symmetric, we can suppose that the distribution of x,y,z coordinates are independent and identically distributed. Then , where is the mean square distance of the electrons from the nucleus. Therefore, . If is the number of atoms per unit volume, the volume diamagnetic susceptibility in SI units is [18]
In atoms, Langevin susceptibility is of the same order of magnitude as Van Vleck paramagnetic susceptibility.
The Langevin theory is not the full picture for metals because there are also non-localized electrons. The theory that describes diamagnetism in a free electron gas is called Landau diamagnetism, named after Lev Landau, [19] and instead considers the weak counteracting field that forms when the electrons' trajectories are curved due to the Lorentz force. Landau diamagnetism, however, should be contrasted with Pauli paramagnetism, an effect associated with the polarization of delocalized electrons' spins. [20] [21] For the bulk case of a 3D system and low magnetic fields, the (volume) diamagnetic susceptibility can be calculated using Landau quantization, which in SI units is
where is the Fermi energy. This is equivalent to , exactly times Pauli paramagnetic susceptibility, where is the Bohr magneton and is the density of states (number of states per energy per volume). This formula takes into account the spin degeneracy of the carriers (spin-1/2 electrons).
In doped semiconductors the ratio between Landau and Pauli susceptibilities may change due to the effective mass of the charge carriers differing from the electron mass in vacuum, increasing the diamagnetic contribution. The formula presented here only applies for the bulk; in confined systems like quantum dots, the description is altered due to quantum confinement. [22] [23] Additionally, for strong magnetic fields, the susceptibility of delocalized electrons oscillates as a function of the field strength, a phenomenon known as the De Haas–Van Alphen effect, also first described theoretically by Landau.
Magnetism is the class of physical attributes that occur through a magnetic field, which allows objects to attract or repel each other. Because both electric currents and magnetic moments of elementary particles give rise to a magnetic field, magnetism is one of two aspects of electromagnetism.
Paramagnetism is a form of magnetism whereby some materials are weakly attracted by an externally applied magnetic field, and form internal, induced magnetic fields in the direction of the applied magnetic field. In contrast with this behavior, diamagnetic materials are repelled by magnetic fields and form induced magnetic fields in the direction opposite to that of the applied magnetic field. Paramagnetic materials include most chemical elements and some compounds; they have a relative magnetic permeability slightly greater than 1 and hence are attracted to magnetic fields. The magnetic moment induced by the applied field is linear in the field strength and rather weak. It typically requires a sensitive analytical balance to detect the effect and modern measurements on paramagnetic materials are often conducted with a SQUID magnetometer.
Superparamagnetism is a form of magnetism which appears in small ferromagnetic or ferrimagnetic nanoparticles. In sufficiently small nanoparticles, magnetization can randomly flip direction under the influence of temperature. The typical time between two flips is called the Néel relaxation time. In the absence of an external magnetic field, when the time used to measure the magnetization of the nanoparticles is much longer than the Néel relaxation time, their magnetization appears to be in average zero; they are said to be in the superparamagnetic state. In this state, an external magnetic field is able to magnetize the nanoparticles, similarly to a paramagnet. However, their magnetic susceptibility is much larger than that of paramagnets.
A magnet is a material or object that produces a magnetic field. This magnetic field is invisible but is responsible for the most notable property of a magnet: a force that pulls on other ferromagnetic materials, such as iron, steel, nickel, cobalt, etc. and attracts or repels other magnets.
In physics and materials science, the Curie temperature (TC), or Curie point, is the temperature above which certain materials lose their permanent magnetic properties, which can (in most cases) be replaced by induced magnetism. The Curie temperature is named after Pierre Curie, who showed that magnetism was lost at a critical temperature.
In electromagnetism, the magnetic susceptibility is a measure of how much a material will become magnetized in an applied magnetic field. It is the ratio of magnetization M to the applied magnetic field intensity H. This allows a simple classification, into two categories, of most materials' responses to an applied magnetic field: an alignment with the magnetic field, χ > 0, called paramagnetism, or an alignment against the field, χ < 0, called diamagnetism.
Earnshaw's theorem states that a collection of point charges cannot be maintained in a stable stationary equilibrium configuration solely by the electrostatic interaction of the charges. This was first proven by British mathematician Samuel Earnshaw in 1842. It is usually cited in reference to magnetic fields, but was first applied to electrostatic field.
In electromagnetism, the magnetic moment or magnetic dipole moment is the combination of strength and orientation of a magnet or other object or system that exerts a magnetic field. The magnetic dipole moment of an object determines the magnitude of torque the object experiences in a given magnetic field. When the same magnetic field is applied, objects with larger magnetic moments experience larger torques. The strength of this torque depends not only on the magnitude of the magnetic moment but also on its orientation relative to the direction of the magnetic field. Its direction points from the south pole to north pole of the magnet.
In electromagnetism, permeability is the measure of magnetization produced in a material in response to an applied magnetic field. Permeability is typically represented by the (italicized) Greek letter μ. It is the ratio of the magnetic induction to the magnetizing field as a function of the field in a material. The term was coined by William Thomson, 1st Baron Kelvin in 1872, and used alongside permittivity by Oliver Heaviside in 1885. The reciprocal of permeability is magnetic reluctivity.
In condensed matter physics, the Fermi surface is the surface in reciprocal space which separates occupied from unoccupied electron states at zero temperature. The shape of the Fermi surface is derived from the periodicity and symmetry of the crystalline lattice and from the occupation of electronic energy bands. The existence of a Fermi surface is a direct consequence of the Pauli exclusion principle, which allows a maximum of one electron per quantum state. The study of the Fermi surfaces of materials is called fermiology.
In solid-state physics, the free electron model is a quantum mechanical model for the behaviour of charge carriers in a metallic solid. It was developed in 1927, principally by Arnold Sommerfeld, who combined the classical Drude model with quantum mechanical Fermi–Dirac statistics and hence it is also known as the Drude–Sommerfeld model.
In magnetism, the Curie–Weiss law describes the magnetic susceptibility χ of a ferromagnet in the paramagnetic region above the Curie temperature:
In classical electromagnetism, magnetization is the vector field that expresses the density of permanent or induced magnetic dipole moments in a magnetic material. Accordingly, physicists and engineers usually define magnetization as the quantity of magnetic moment per unit volume. It is represented by a pseudovector M. Magnetization can be compared to electric polarization, which is the measure of the corresponding response of a material to an electric field in electrostatics.
In condensed matter physics, a spin wave is a propagating disturbance in the ordering of a magnetic material. These low-lying collective excitations occur in magnetic lattices with continuous symmetry. From the equivalent quasiparticle point of view, spin waves are known as magnons, which are bosonic modes of the spin lattice that correspond roughly to the phonon excitations of the nuclear lattice. As temperature is increased, the thermal excitation of spin waves reduces a ferromagnet's spontaneous magnetization. The energies of spin waves are typically only μeV in keeping with typical Curie points at room temperature and below.
In chemistry and physics, the exchange interaction is a quantum mechanical constraint on the states of indistinguishable particles. While sometimes called an exchange force, or, in the case of fermions, Pauli repulsion, its consequences cannot always be predicted based on classical ideas of force. Both bosons and fermions can experience the exchange interaction.
The Bohr–Van Leeuwen theorem states that when statistical mechanics and classical mechanics are applied consistently, the thermal average of the magnetization is always zero. This makes magnetism in solids solely a quantum mechanical effect and means that classical physics cannot account for paramagnetism, diamagnetism and ferromagnetism. Inability of classical physics to explain triboelectricity also stems from the Bohr–Van Leeuwen theorem.
For many paramagnetic materials, the magnetization of the material is directly proportional to an applied magnetic field, for sufficiently high temperatures and small fields. However, if the material is heated, this proportionality is reduced. For a fixed value of the field, the magnetic susceptibility is inversely proportional to temperature, that is
Magnetochemistry is concerned with the magnetic properties of chemical compounds. Magnetic properties arise from the spin and orbital angular momentum of the electrons contained in a compound. Compounds are diamagnetic when they contain no unpaired electrons. Molecular compounds that contain one or more unpaired electrons are paramagnetic. The magnitude of the paramagnetism is expressed as an effective magnetic moment, μeff. For first-row transition metals the magnitude of μeff is, to a first approximation, a simple function of the number of unpaired electrons, the spin-only formula. In general, spin–orbit coupling causes μeff to deviate from the spin-only formula. For the heavier transition metals, lanthanides and actinides, spin–orbit coupling cannot be ignored. Exchange interaction can occur in clusters and infinite lattices, resulting in ferromagnetism, antiferromagnetism or ferrimagnetism depending on the relative orientations of the individual spins.
Magnetic levitation (maglev) or magnetic suspension is a method by which an object is suspended with no support other than magnetic fields. Magnetic force is used to counteract the effects of the gravitational force and any other forces.
In condensed matter and atomic physics, Van Vleck paramagnetism refers to a positive and temperature-independent contribution to the magnetic susceptibility of a material, derived from second order corrections to the Zeeman interaction. The quantum mechanical theory was developed by John Hasbrouck Van Vleck between the 1920s and the 1930s to explain the magnetic response of gaseous nitric oxide and of rare-earth salts. Alongside other magnetic effects like Paul Langevin's formulas for paramagnetism and diamagnetism, Van Vleck discovered an additional paramagnetic contribution of the same order as Langevin's diamagnetism. Van Vleck contribution is usually important for systems with one electron short of being half filled and this contribution vanishes for elements with closed shells.
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