A tailings dam is typically an earth-fill embankment dam used to store byproducts of mining operations after separating the ore from the gangue. Tailings can be liquid, solid, or a slurry of fine particles, and are usually highly toxic and potentially radioactive. Solid tailings are often used as part of the structure itself.
Tailings dams rank among the largest engineered structures on earth. The Syncrude Mildred Lake Tailings Dyke in Alberta, Canada, is an embankment dam about 18 kilometres (11 mi) long and from 40 to 88 metres (131 to 289 ft) high. The dam and the artificial lake within it are constructed and maintained as part of ongoing operations by Syncrude in extracting oil from the Athabasca oil sands; it is the largest dam structure on earth by volume, and as of 2001 it was believed to be the largest earth structure in the world by volume of fill. [1]
There are key differences between tailings dams and the more familiar hydroelectric dams. Tailings dams are designed for permanent containment, meaning they are intended to "remain there forever". [2] Copper, gold, uranium and other mining operations produce varied kinds of waste, much of it toxic, which pose varied challenges for long-term containment. [3]
An estimated 3,500 active tailings impoundments stand around the world, although there is no complete inventory, and the total number is disputed. In an average year, it would be expected that between two and five "major" tailings dam failures would occur, along with 35 "minor" failures. [4] Assuming the 3,500 figure is correct, this failure rate is "more than two orders of magnitude higher than the failure rate of conventional water retention dams". [5] A 2020 assessment of responsible mining practices by the Responsible Mining Foundation, found that companies have made little or no progress in improving the documentation and safety practices of these ponds. [6]
Unlike water retention dams, the height of a tailings dam is typically increased (raised) throughout the life of the particular mine. Typically, a base or starter dam is constructed, and as it fills with a mixture of tailings and water, it is raised. Material used to raise the dam can include the tailings (if their properties are suitable), earthfill, or rockfill. [7] It is increasingly common for barrier systems such as geomembranes to be incorporated into tailings dams. Impermeable barriers can prevent or reduce seepage thereby increasing the geotechnical and environmental stability of the dam. [8]
There are three types of dam raises, the upstream, downstream and centerline, named according to the relative position of the new crest of the dam to the previous. The specific design used is dependent upon topography, geology, climate, the type of tailings, and cost. An upstream tailings dam consists of trapezoidal embankments being constructed on top but toe to crest of another, moving the crest further upstream. This creates a relatively flat downstream side and a jagged upstream side which is supported by tailings slurry in the impoundment. The downstream design refers to the successive raising of the embankment that positions the fill and crest further downstream. A centerlined dam has sequential embankment dams constructed directly on top of another while fill is placed on the downstream side for support and slurry supports the upstream side. [9] [10]
Brazil and Chile have banned the construction of upstream dams, deemed too dangerous, and the fifty or so in the Brazilian state of Minas Gerais will have to be decommissioned by 2035. [11]
The extraction of economic minerals results in an accumulation of tailings on the surface, mostly in tailings ponds, that occupy a large amount of land. [12] Stratification is inherent to sedimentation, as the heavier particles settle before the lighter particles. Yet, tailings can also represent an untapped resource, as many tailings contain valuable secondary minerals. These could be recovered, contributing to the circular economy and reducing the need for new mining operations. Analysing the mineralogy of tailings can reveal the presence of economically valuable minerals, such as rare earth elements or aother metal resources. This is particularly important, as global demand for these resources continues to grow. A thorough understanding of tailings stratigraphy helps to identify the most promising areas for recovery and informs processing methods that allow mineral recovery to be maximized while minimizing environmental issues.
Tailings stratification is the layering of tailings due to the distribution in particle size as well as the difference in specific density. The compactness of the sandy to silty tailings [13] influences the permeability, which will influence the drainage ability of the tailings and thus the infiltration line. [14] The infiltration line is the pathway through which water can enter in a specific area, [14] and it affects the safety and stability of tailings ponds.
Furthermore, the tailings' compactness affects how much water they can hold. This also affects how strong and stiff they get to be. The more compact the tailings are, the smaller the permeability coefficient and the stronger the water-holding capacity. Rather than consisting of a single uniform body, tailings are usually composed of multiple layers of sediment that differ in grain size and mineralogical composition [15] The grain size of tailings can show great fluctuations due to the deposition of larger and finer particles, which influences the tailings stratification and shear strength. When more finer than larger particles settle, it weakens the tailings, which may result in the settled layer holding more water. This could create the saturation line, affecting how safely the tailings storage facility (TSF) can be operated.
Mineralogical composition in tailings causes the cementation of layers. Sulfide enriched layers can form protective cemented layers. These layers will usually not form in systems with a homogeneous distribution of Iron (Fe) bearing sulfide. Therefore, tailings stratification is greatly influenced by the presence of minerals which have a great influence in the cementation of the tailings' layers, by the grain size distribution which influences the compactness and density of the tailings. However, there are other factors that influence tailings' stratification, such as topography, geological setting, climate, tailings deposition process and lastly how long the tailings have been stored in the TSF.
Carbon mineralization is a natural process that occurs over hundreds or thousands of years, where certain minerals, such as in mine tailings, react with atmospheric carbon dioxide to form solid carbonates. This process effectively sequesters and removes carbon dioxide from the atmosphere. Ultramafic mine tailings, rich in magnesium-bearing minerals such as serpentine, olivine and brucite, are highly reactive due to their reduced grain size from crushing and have been historically and currently produced in substantial quantities facilitating carbon mineralization. [16] Using these tailings for carbon mineralization can reduce the costs associated with the extraction and processing of ultramafic rocks, which is often energy intensive. The mineralogy of these tailings can vary substantially depending on the type of commodity being mined. [17]
As an example, the Baptiste nickel project in British Columbia, Canada, is known for its potential to mineralize carbon in its tailings. Similarly, the Gahcho Kué diamond mine in the Northwest Territories, Canada, has kimberlite pipes with the potential for carbon mineralization. Tailings from this mine contain a mix of minerals that can facilitate carbon mineralization, contributing to the overall reduction of atmospheric carbon dioxide concnetrations. Ultramafic mine tailings are a promising avenue for carbon mineralization, providing both an effective means of Carbon dioxide storage and a way to utilize waste materials from mining operations.
Secondary mineralization in tailings involves the formation of new minerals from the alteration or weathering of primary minerals found in mine waste. These secondary minerals develop within tailings impoundments due to weathering processes following mining and milling activities. A key factor in this mineralization is the oxidation of sufide minerals, which alters dissolved species concentrations, porewater pH and the overall mineralogy. Within the oxidation zone, primary minerals such as sulfides and carbonates are depleted, leading to the formation of secondary minerals. These secondary minerals are critical, as they help to regulate the concentrations of dissolved species in the pore water. [18]
This study focused on tungsten secondary minerals in tailings generated during a two-year mining operation at the Mount Pleasant Tungsten Mine, approximately 60 km south of Fredericton, New Brunswick. Initially, the tailings were submerged but were exposed to atmospheric oxygen following a dam failure in 1997. The primary mineralogy of the deposit consists mainly of quartz, topaz, fluorite, micas, clays, chlorite, K-feldspars and opaque minerals including wolframite. While the tailings are not extensively oxidized, certain areas have elevated sulfate and metal concentrations including lower pH values.
Biomineralization in tailings refers to the process by which living organisms, particularly microbes, contribute to the formation of minerals through their metabolic activities. Acidophilic chemolithotrophic bacteria like Thiobacillus are vital to mineralization processes and play a critical role in biomineralization processes in mine tailings. Examples are those found at the abandoned Kam Kotia mine near Timmins, Ontario, Canada, which has been inactive for about 30 years. These bacteria catalyze the production of toxic, acidic metal leachates that can severely affect natural ecosystems. [19]
Under oxidizing conditions, acidophilic chemolithotrophs oxidize ferrous (Fe (II)) sulfides to produce sulfuric acid and ferric (Fe (III)) iron. These bacteria increase the rate of iron (Fe (II)) oxidation at low pH. Certain species, such as Acidithiobacillus ferrooxidans , can also reduce iron (Fe (III)) in both aerobic and anaerobic environments at very low pH. In addition, sulfate-reducing bacteria (SRB) can indirectly influence the iron cycle in mine tailings by reacting with soluble iron (Fe (II)) to form iron sulfide precipitates. Although sulfate-reducing bacteria (SRB) typically prefer neutral, reducing conditions, they have been found in acid mine drainage environments, indicating potential acid tolerance. Although oxygen generally inhibits their activity, recent studies suggest that sulfate-reducing bacteria (SRB) can remain viable in oxygenated conditions and even engage in aerobic sulfate reduction in well-oxygenated microbial mats.
The largest three tailings dams are:
Rank | Name [20] | Country | Year completed | Structure height [m] | Structure volume [21] [106 m3] | Reservoir volume [109 m3] | Installed capacity [MW] | Type |
---|---|---|---|---|---|---|---|---|
1 | Syncrude Tailings Dam Mildred MLSB [22] | Canada | 1995 | 88 | 540 [23] /720 | 0.35 | NA | TE |
2 | Syncrude Tailings Dam Mildred SWSS [24] | Canada | 2010 | 40–50 | 119 [23] | 0.25 [23] | NA | TE |
3 | ASARCO Mission Mine Tailings Dam | United States | 1973 | 30 [25] | 40.1 | 0 [26] | NA | ER |
Type: TE – Earth; ER – Rock-fill; PG – Concrete gravity; CFRD – Concrete face rock fill
This article's tone or style may not reflect the encyclopedic tone used on Wikipedia.(November 2024) |
Bioleaching is the extraction or liberation of metals from their ores through the use of living organisms. Bioleaching is one of several applications within biohydrometallurgy and several methods are used to treat ores or concentrates containing copper, zinc, lead, arsenic, antimony, nickel, molybdenum, gold, silver, and cobalt.
The mineral pyrite ( PY-ryte), or iron pyrite, also known as fool's gold, is an iron sulfide with the chemical formula FeS2 (iron (II) disulfide). Pyrite is the most abundant sulfide mineral.
Iron ores are rocks and minerals from which metallic iron can be economically extracted. The ores are usually rich in iron oxides and vary in color from dark grey, bright yellow, or deep purple to rusty red. The iron is usually found in the form of magnetite (Fe
3O
4, 72.4% Fe), hematite (Fe
2O
3, 69.9% Fe), goethite (FeO(OH), 62.9% Fe), limonite (FeO(OH)·n(H2O), 55% Fe), or siderite (FeCO3, 48.2% Fe).
Geomicrobiology is the scientific field at the intersection of geology and microbiology and is a major subfield of geobiology. It concerns the role of microbes on geological and geochemical processes and effects of minerals and metals to microbial growth, activity and survival. Such interactions occur in the geosphere, the atmosphere and the hydrosphere. Geomicrobiology studies microorganisms that are driving the Earth's biogeochemical cycles, mediating mineral precipitation and dissolution, and sorbing and concentrating metals. The applications include for example bioremediation, mining, climate change mitigation and public drinking water supplies.
In mining, tailings or tails are the materials left over after the process of separating the valuable fraction from the uneconomic fraction (gangue) of an ore. Tailings are different from overburden, which is the waste rock or other material that overlies an ore or mineral body and is displaced during mining without being processed.
Jarosite is a basic hydrous sulfate of potassium and ferric iron (Fe-III) with a chemical formula of KFe3(SO4)2(OH)6. This sulfate mineral is formed in ore deposits by the oxidation of iron sulfides. Jarosite is often produced as a byproduct during the purification and refining of zinc and is also commonly associated with acid mine drainage and acid sulfate soil environments.
Chromite is a crystalline mineral composed primarily of iron(II) oxide and chromium(III) oxide compounds. It can be represented by the chemical formula of FeCr2O4. It is an oxide mineral belonging to the spinel group. The element magnesium can substitute for iron in variable amounts as it forms a solid solution with magnesiochromite (MgCr2O4). Substitution of the element aluminium can also occur, leading to hercynite (FeAl2O4). Chromite today is mined particularly to make stainless steel through the production of ferrochrome (FeCr), which is an iron-chromium alloy.
Acid mine drainage, acid and metalliferous drainage (AMD), or acid rock drainage (ARD) is the outflow of acidic water from metal mines and coal mines.
Pyrrhotite is an iron sulfide mineral with the formula Fe(1-x)S. It is a nonstoichiometric variant of FeS, the mineral known as troilite. Pyrrhotite is also called magnetic pyrite, because the color is similar to pyrite and it is weakly magnetic. The magnetism decreases as the iron content increases, and troilite is non-magnetic. Pyrrhotite is generally tabular and brassy/bronze in color with a metallic luster. The mineral occurs with mafic igneous rocks like norites, and may form from pyrite during metamorphic processes. Pyrrhotite is associated and mined with other sulfide minerals like pentlandite, pyrite, chalcopyrite, and magnetite, and has been found globally.
The pedosphere is the outermost layer of the Earth that is composed of soil and subject to soil formation processes. It exists at the interface of the lithosphere, atmosphere, hydrosphere and biosphere. The pedosphere is the skin of the Earth and only develops when there is a dynamic interaction between the atmosphere, biosphere, lithosphere and the hydrosphere. The pedosphere is the foundation of terrestrial life on Earth.
Sulfate-reducing microorganisms (SRM) or sulfate-reducing prokaryotes (SRP) are a group composed of sulfate-reducing bacteria (SRB) and sulfate-reducing archaea (SRA), both of which can perform anaerobic respiration utilizing sulfate (SO2−
4) as terminal electron acceptor, reducing it to hydrogen sulfide (H2S). Therefore, these sulfidogenic microorganisms "breathe" sulfate rather than molecular oxygen (O2), which is the terminal electron acceptor reduced to water (H2O) in aerobic respiration.
Serpentinite is a metamorphic rock composed predominantly of serpentine group minerals formed by serpentinization of mafic or ultramafic rocks. The ancient origin of the name is uncertain, it may be from the similarity of its texture or color to snake skin. Greek pharmacologist Dioscorides recommended eating this rock to prevent snakebite.
Iron(II) sulfide or ferrous sulfide is one of a family of chemical compounds and minerals with the approximate formula FeS. Iron sulfides are often iron-deficient non-stoichiometric. All are black, water-insoluble solids.
Troilite is a rare iron sulfide mineral with the simple formula of FeS. It is the iron-rich endmember of the pyrrhotite group. Pyrrhotite has the formula Fe(1-x)S which is iron deficient. As troilite lacks the iron deficiency which gives pyrrhotite its characteristic magnetism, troilite is non-magnetic.
The important sulfur cycle is a biogeochemical cycle in which the sulfur moves between rocks, waterways and living systems. It is important in geology as it affects many minerals and in life because sulfur is an essential element (CHNOPS), being a constituent of many proteins and cofactors, and sulfur compounds can be used as oxidants or reductants in microbial respiration. The global sulfur cycle involves the transformations of sulfur species through different oxidation states, which play an important role in both geological and biological processes. Steps of the sulfur cycle are:
Various theories of ore genesis explain how the various types of mineral deposits form within Earth's crust. Ore-genesis theories vary depending on the mineral or commodity examined.
Lithotrophs are a diverse group of organisms using an inorganic substrate to obtain reducing equivalents for use in biosynthesis or energy conservation via aerobic or anaerobic respiration. While lithotrophs in the broader sense include photolithotrophs like plants, chemolithotrophs are exclusively microorganisms; no known macrofauna possesses the ability to use inorganic compounds as electron sources. Macrofauna and lithotrophs can form symbiotic relationships, in which case the lithotrophs are called "prokaryotic symbionts". An example of this is chemolithotrophic bacteria in giant tube worms or plastids, which are organelles within plant cells that may have evolved from photolithotrophic cyanobacteria-like organisms. Chemolithotrophs belong to the domains Bacteria and Archaea. The term "lithotroph" was created from the Greek terms 'lithos' (rock) and 'troph' (consumer), meaning "eaters of rock". Many but not all lithoautotrophs are extremophiles.
Iron Mountain Mine, also known as the Richmond Mine at Iron Mountain, is a mine near Redding in Northern California, US. Geologically classified as a "massive sulfide ore deposit", the site was mined for iron, silver, gold, copper, zinc, quartz, and pyrite intermittently from the 1860s until 1963. The mine is the source of extremely acidic mine drainage which also contains large amounts of zinc, copper, and cadmium. One of America's most toxic waste sites, it has been listed as a federal Superfund site since 1983.
Concrete degradation may have many different causes. Concrete is mostly damaged by the corrosion of reinforcement bars due to the carbonatation of hardened cement paste or chloride attack under wet conditions. Chemical damage is caused by the formation of expansive products produced by chemical reactions, by aggressive chemical species present in groundwater and seawater, or by microorganisms Other damaging processes can also involve calcium leaching by water infiltration, physical phenomena initiating cracks formation and propagation, fire or radiant heat, aggregate expansion, sea water effects, leaching, and erosion by fast-flowing water.
The gold cycle is the biogeochemical cycling of gold through the lithosphere, hydrosphere, atmosphere, and biosphere. Gold is a noble transition metal that is highly mobile in the environment and subject to biogeochemical cycling, driven largely by microorganisms. Gold undergoes processes of solubilization, stabilization, bioreduction, biomineralization, aggregation, and ligand utilization throughout its cycle. These processes are influenced by various microbial populations and cycling of other elements such as carbon, nitrogen, and sulfur. Gold exists in several forms in the Earth's surface environment including Au(I/III)-complexes, nanoparticles, and placer gold particles. The gold biogeochemical cycle is highly complex and strongly intertwined with cycling of other metals including silver, copper, iron, manganese, arsenic, and mercury. Gold is important in the biotech field for applications such as mineral exploration, processing and remediation, development of biosensors and drug delivery systems, industrial catalysts, and for recovery of gold from electronic waste.