Methanesulfonate monooxygenase

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Methanesulfonate monooxygenase
Identifiers
EC no. 1.14.13.111
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Methanesulfonate monooxygenase (EC 1.14.13.111, mesylate monooxygenase, mesylate,reduced-FMN:oxygen oxidoreductase, MsmABCD, methanesulfonic acid monooxygenase, MSA monooxygenase, MSAMO) is an enzyme with systematic name methanesulfonate,NADH:oxygen oxidoreductase. [1] [2] This enzyme catalyses the following chemical reaction

methanesulfonate + NADH + H+ + O2 formaldehyde + NAD+ + sulfite + H2O

Methanesulfonate monooxygenase is a flavoprotein.

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<span class="mw-page-title-main">Methanesulfonic acid</span> Organosulfur compound (CH₃SO₂OH)

Methanesulfonic acid (MsOH) or methanesulphonic acid is an organosulfuric, colorless liquid with the molecular formula CH3SO3H and structure H3C−S(=O)2−OH. It is the simplest of the alkylsulfonic acids. Salts and esters of methanesulfonic acid are known as mesylates. It is hygroscopic in its concentrated form. Methanesulfonic acid can dissolve a wide range of metal salts, many of them in significantly higher concentrations than in hydrochloric acid (HCl) or sulfuric acid.

6-Hydroxynicotinate 3-monooxygenase (EC 1.14.13.114, NicC, 6HNA monooxygenase, HNA-3-monooxygenase) is an enzyme with systematic name 6-hydroxynicotinate,NADH:oxygen oxidoreductase (3-hydroxylating, decarboxylating). This enzyme catalyses the following chemical reaction

Dimethyl-sulfide monooxygenase (EC 1.14.13.131, dimethylsulfide monooxygenase) is an enzyme with systematic name dimethyl sulfide,NADH:oxygen oxidoreductase. This enzyme catalyses the following chemical reaction

References

  1. ↑ de Marco P, Moradas-Ferreira P, Higgins TP, McDonald I, Kenna EM, Murrell JC (April 1999). "Molecular analysis of a novel methanesulfonic acid monooxygenase from the methylotroph Methylosulfonomonas methylovora". Journal of Bacteriology. 181 (7): 2244–51. PMC   93639 . PMID   10094704.
  2. ↑ Higgins TP, Davey M, Trickett J, Kelly DP, Murrell JC (February 1996). "Metabolism of methanesulfonic acid involves a multicomponent monooxygenase enzyme". Microbiology. 142 ( Pt 2): 251–60. doi: 10.1099/13500872-142-2-251 . PMID   8932698.
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