| No. | Name | Start | End | Head of government | 
|---|
| 16 | Antônio Francisco de Paula de Holanda Cavalcanti de Albuquerque | 24 July 1840 | 23 March 1841 | Pedro II (also head of state)
 | 
| 17 | Francisco Vilela Barbosa | 23 March 1841 | 26 August 1841 | 
| — | José Clemente Pereira | 26 August 1841 | 13 September 1841 | 
| Francisco Vilela Barbosa | 13 September 1841 | 20 January 1843 | 
| 18 | Joaquim José Rodrigues Torres | 20 January 1843 | 24 January 1843 | 
| — | Salvador José Maciel | 24 January 1843 | 2 February 1843 | 
| 19 | Joaquim José Rodrigues Torres | 2 February 1843 | 2 February 1844 | 
| 20 | Jerônimo Francisco Coelho | 2 February 1844 | 23 May 1844 | 
| 21 | Antônio Francisco de Paula de Holanda Cavalcanti de Albuquerque | 23 May 1844 | 17 May 1847 | 
| — | João Paulo dos Santos Barreto | 17 May 1847 | 22 May 1847 | 
| 22 | Cândido Batista de Oliveira | 22 May 1847 | 8 March 1848 | Manuel Alves Branco | 
| — | Manuel Felizardo de Sousa e Melo | 8 March 1848 | 14 May 1848 | José de Almeida Torres | 
| 23 | Joaquim Antão Fernandes Leão | 14 May 1848 | 29 September 1848 | José de Almeida Torres Sousa e Melo
 | 
| 24 | Manuel Felizardo de Sousa e Melo | 29 September 1848 | 23 July 1849 | Pedro de Araújo Lima | 
| 25 | Manuel Vieira Tosta | 23 July 1849 | 11 May 1852 | Pedro de Araújo Lima José da Costa Carvalho
 | 
| 26 | Zacarias de Góis e Vasconcelos | 11 May 1852 | 6 September 1853 | Joaquim Rodrigues Torres | 
| — | Pedro de Alcântara Bellegarde | 6 September 1853 | 15 December 1853 | Honório Carneiro Leão | 
| 27 | José Maria da Silva Paranhos | 15 February 1853 | 14 June 1855 | 
| 28 | João Maurício Wanderley | 14 June 1855 | 8 October 1856 | Honório Carneiro Leão Luís Alves de Lima e Silva
 | 
| — | José Maria da Silva Paranhos | 8 October 1856 | 4 May 1857 | Luís Alves de Lima e Silva | 
| 29 | José Antônio Saraiva | 4 May 1857 | 12 December 1858 | Pedro de Araújo Lima | 
| 30 | Antônio Paulino Limpo de Abreu | 12 December 1858 | 10 August 1859 | Antônio Limpo de Abreu | 
| 31 | Francisco Xavier Pais Barreto | 10 August 1859 | 2 March 1861 | Ângelo da Silva Ferraz | 
| 32 | Joaquim José Inácio | 2 March 1861 | 24 May 1862 | Luís Alves de Lima e Silva | 
| — | José Bonifácio de Andrada e Silva | 24 May 1862 | 30 May 1862 | Zacarias de Góis | 
| 33 | Joaquim Raimundo de Lamare | 30 May 1862 | 15 January 1864 | Pedro de Araújo Lima | 
| 34 | João Pedro Dias Vieira | 15 January 1864 | 31 March 1864 | Zacarias de Góis | 
| 35 | Francisco Carlos de Araújo Brusque | 31 March 1864 | 31 August 1864 | 
| 36 | Francisco Xavier Pinto de Lima | 31 August 1864 | 12 May 1865 | Francisco José Furtado | 
| — | José Antônio Saraiva | 12 May 1865 | 27 June 1865 | Pedro de Araújo Lima | 
| 37 | Francisco de Paula da Silveira Lobo | 27 June 1865 | 27 January 1866 | 
| — | José Antônio Saraiva | 27 January 1866 | 17 February 1866 | 
| 38 | Francisco de Paula da Silveira Lobo | 17 February 1866 | 3 August 1866 | 
| 39 | Afonso Celso de Assis Figueiredo | 3 August 1866 | 16 July 1868 | Zacarias de Góis | 
| 40 | João Maurício Wanderley | 16 July 1868 | 29 September 1870 | Joaquim Rodrigues Torres | 
| 41 | Luís Antônio Pereira Franco | 29 September 1870 | 7 March 1871 | Pimenta Bueno | 
| 42 | Manuel Antônio Duarte de Azevedo | 7 March 1871 | 18 May 1872 | José Paranhos | 
| 43 | Joaquim Delfino Ribeiro da Luz | 18 May 1872 | 25 June 1875 | 
| 44 | Luís Antônio Pereira Franco | 25 June 1875 | 5 January 1878 | Luís Alves de Lima e Silva | 
| 45 | Eduardo de Andrade Pinto | 5 January 1878 | 24 December 1878 | Cansanção de Sinimbu | 
| 46 | João Ferreira de Moura | 24 December 1878 | 9 December 1879 | 
| — | João Lustosa da Cunha Paranaguá | 9 December 1879 | 24 January 1880 | 
| 47 | João Ferreira de Moura | 24 January 1880 | 28 March 1880 | 
| — | Pedro Luís Pereira de Sousa | 28 March 1880 | 30 March 1880 | José Antônio Saraiva | 
| 48 | José Rodrigues de Lima Duarte | 30 March 1880 | 21 January 1882 | 
| — | Afonso Augusto Moreira Pena | 21 January 1882 | 28 January 1882 | Martinho Campos | 
| 49 | Bento Francisco de Paula Sousa | 28 January 1882 | 6 May 1882 | 
| 50 | Antônio Carneiro da Rocha | 6 May 1882 | 3 July 1882 | 
| 51 | João Florentino Meira de Vasconcelos | 3 July 1882 | 24 May 1883 | João da Cunha Paranaguá | 
| 52 | Antônio de Almeida e Oliveira | 24 May 1883 | 6 June 1884 | Lafayette Rodrigues Pereira | 
| 53 | Joaquim Raimundo de Lamare | 6 June 1884 | 6 May 1885 | Manuel de Sousa Dantas | 
| 54 | Luís Filipe de Sousa Leão | 6 May 1885 | 20 August 1885 | José Antônio Saraiva | 
| 55 | Alfredo Rodrigues Fernandes Chaves | 20 August 1885 | 12 June 1886 | João Maurício Wanderley | 
| 56 | Samuel Wallace MacDowell | 12 June 1886 | 10 May 1887 | 
| 57 | Carlos Frederico Castrioto | 10 May 1887 | 10 March 1888 | 
| 58 | Luís Antônio Vieira da Silva | 10 March 1888 | 4 January 1889 | João Correia de Oliveira | 
| — | Tomás José Coelho de Almeida | 4 January 1889 | 8 February 1889 | 
| 59 | Joaquim Elísio Pereira Marinho | 8 February 1889 | 7 June 1889 | 
| 60 | José da Costa Azevedo | 7 June 1889 | 15 November 1889 | Afonso Celso |