Hadean zircon is the oldest-surviving crustal material from the Earth's earliest geological time period, the Hadean eon, about 4 billion years ago. Zircon is a mineral that is commonly used for radiometric dating because it is highly resistant to chemical changes and appears in the form of small crystals or grains in most igneous and metamorphic host rocks. [1]
Hadean zircon has very low abundance around the globe because of recycling of material by plate tectonics. When the rock at the surface is buried deep in the Earth it is heated and can recrystallise or melt. [1] In the Jack Hills, Australia, scientists obtained a relatively comprehensive record of Hadean zircon crystals in contrast to other locations. The Jack Hills zircons are found in metamorphosed sediments that were initially deposited around 3 billion years ago, [1] or during the Archean Eon. However, the zircon crystals there are older than the rocks that contain them. Many investigations have been carried out to find the absolute age and properties of zircon, for example the isotope ratios, mineral inclusions, and geochemistry of zircon. The characteristics of Hadean zircons show early Earth history and the mechanism of Earth's processes in the past. [1] Based on the properties of these zircon crystals, many different geological models were proposed.
The geological history of the Hadean eon of early earth is poorly known due to the lack of rock record older than 4.02 Ga (giga-annum or billion years). [2] [3] [4] Most scientists accept that the plate recycling mechanism has melted almost all pieces of Earth's crust. [2] However, some tiny parts of the crust have not been melted, as some rare Hadean zircon grains included in much younger host rock were discovered. [2] The examination of Hadean detrital or inherited grains of zircon can give evidence of geophysical conditions of the early earth. [4]
Since there is no strong evidence depicting the early Earth's true environment, many models are generated to explain early Earth history. [1] The high value of Hadean heat production and impact flux proved that continental crust did not exist, which is very different from the modern process. In the absence of large amount of undistributed data and within the constraints of analytical methods, calculation on geophysics and planetary science has been rapidly developed to explore this new area of knowledge. [1]
Less than 1% of zircons detected around the world are over four billion years old. [1] The probability of discovering so much as a single zircon over four billion years in age is very low. [1] The abundance of over four billion-year-old zircon in the Jack Hills is anomalously high for most Archean quartzites and thus abundances probabilities of other spots are extremely low (0.2–0.02%). [5] [ failed verification ]
By adopting uranium-lead dating (U-Pb) together with other analytical methods, more geochemical information can be obtained. Only 3% out of over 200,000 detrital zircon grains dated by U-Pb analysis are over four billion years old. [6] [7]
Due to different content of uranium and trace element concentration, four clusters of zircons are identified as below [1]
Low crystallisation temperatures and trace element characteristics are the two major characteristics that differentiate mantle derived zircon or oceanic crust-derived zircon. [8] [9] [10] Lunar and meteoritic zircons are unique because of their REE signature for example, lack of a cerium anomaly. [11] The crystallization temperature ranges from 900 to 1100 °C. In contrast, terrestrial Hadean zircons are restricted to 600 to 780 °C. [12] Hadean Jack Hills zircon has a wide range of oxygen fraction comparing to meteoritic zircons. [12] No extraterrestrial zircons were found in any terrestrial locality. The textural characteristics like the growth zoning and inclusion mineralogy shows that Hadean zircon from the Jack Hills all come from igneous sources. [13] [14]
The unspecified samples used for analyses below were Jack Hills zircon in Australia because of the high abundances and data available.
U-Pb dating in the U-Pb zircon system has long been viewed as the crustal geochronometer because zircon is chemically resistant and enriched in U and Th compared to the daughter product Pb. [16] Trace element and isotopic composition of zircon is important to determine the crystallisation environment. [16]
Results from detrital zircons from the Erawondoo Hill discovery site conglomerate [17] [18] generally show the zircons to have a bimodal age distribution with major peaks at c. 3.4 and 4.1 Ga.
However, zircon is sensitive to radiation damage and can degrade into amorphous material. [19] The Hadean zircon with original uranium concentrations greater than 600 ppm is challenged by the effect of post-crystallization alteration.
Stable isotope data, indicating that the original host rocks to the zircon related to a significant amount of material formed on or near the Earth's surface and subsequently transferred to a middle- to lower-crustal level where they melted to generate the host magmas from which zircon crystallised. [6] [13]
Data type | Observation | Interpretation | Limitation |
---|---|---|---|
Oxygen isotope ratios | Granitoids with lower ઠ18O values | There were hydrothermal interactions with meteoric water instead of weathering. [20] [21] | There is a lack of comprehensive record of the analysed areas within the grains, which leads to difficulty in relating ages of specifically dated parts of the zircon grains to their oxygen and hafnium isotope systematics and trace element concentrations. [22] |
Ratios of oxygen isotopes have been measured in Hadean zircons. High value of 18ઠSMOW observed in Hadean Jack Hills zircons led to two different ideas about the source of Hadean zircon. [22] [6] 18O-enriched clay minerals were found in the host rock of zircon grains. | Water was present on the Earth's surface around 4.3 Ga. [6] | ||
Hadean Jack Hills zircons contain more 18O-enrichments than the mantle zircon about 5.3%. [23] I-type granitoids protoliths give relatively low ઠ18O values while those derived by S type metasedimentary rocks have higher ઠ18O values. | The presence in the protolith of recycled crustal material that had interacted with liquid water under surface, or near surface, condition. [23] | ||
Lutetium-hafnium | The ratio of isotopes of hafnium 176Hf/177Hf data in crustal rocks being consistent with the formation of crust since 4.5 Ga. [24] [25] | Lu-Hf systematics potentially indicating existence of an early formed reservoir, similar to continental crust in its degree of Lu depletion relative to Hf. [24] [25] | Most of the data matches the formation of crust at 4.5 Ga while some zircon data is unreasonable requiring the removal of protolith from chrondritic uniform reservoir (CHUR). Since these extra findings, studies cannot conform the positive value of EHf(T) due to the complication of Hf isotope analysis and lack of U-Pb date being simultaneously available. [24] |
Cluster of results along a line corresponding to a Lu/Hf ~0.01, low reservoir at ~4Ga [26] | The data is consistent with either early extraction of very felsic crust or by remelting of a primordial basaltic reservoir, but in either case extrapolation of this trend yields a present-day εHf(T) of approximately −100 [25] [26] | A recycling event c. 3.9–3.7 Ga which resembles the Hf isotope evolution of modern subduction-related orogens and so may have additional tectonic significance. [26] | |
Plutonium-xenon | Some Hadean zircon grains originally contained plutonium, an element that has since disappeared from the natural environment. In the meteorite record, the abundance ratio of initial plutonium to uranium (Pu/U) was about 0.007 and 244Pu was present in the early Solar System. [27] | The result of the ratio can be interpreted as xenon loss during later metamorphism. Uranium became oxidised to soluble uranyl ion (UO22+) while the solubility of plutonium compounds is low, variations in Pu/U are regarded as an effective indicator of aqueous alteration in Jack Hills protoliths. [28] | Only Nd/U has correlations expected from aqueous processes excluding analysis of Xe isotopic ratios, U-Pb age, trace element contents, and δ18O [27] [28] |
The initial Pu/U ratios of Jack Hills zircon ranges from c. 0.007 to zero. [28] | Due to Xe loss during later metamorphism. Variation in Pu/U has been suggested as a potential indicator of aqueous alteration in the Jack Hills zircon protoliths [28] | ||
High-Nd/U zircons display only low Pu/U, while Nd/U zircons show more heterogeneous Pu/U [28] | High-Nd/U group appears less magmatically evolved than other Hadean zircons, has REE patterns suggestive of some degree of alteration, either by hydrothermal fluid interaction or phosphate replacement, and consists of solely low-Pu/U zircons with a range of Hadean to Proterozoic U-Xe ages [27] [28] | ||
Lithium | Lithium isotopes significantly vary in Hadean zircon. The 7Li isotope result of Hadean Jack Hills zircons gave highly negative values. [29] | The environment of forming zircon as highly weathered. [29] | A high lithium diffusion rate in zircon at low temperature [30] and exchange with hydrogen during metamorphism are two examples of subsequent variations to lithium that may limit the usefulness of the measurements [30] |
Li is homogeneously distributed within single growth zones of the zircons. Jack Hills zircons are zoned in both 7Li and Li concentration. [31] | These values correlate with igneous growth zoning. [32] [31] |
The development of textural criteria for identifying primary inclusions [33] opens up possibilities for recognising zircons' changing provenance with time and investigating their post-depositional alteration history. There are two common inclusion assemblages that are consistent with their forming in "I-type" (hornblende, quartz, biotite, plagioclase, apatite, ilmenite) and "S-type" (quartz, K-feldspar, muscovite, monazite) granitoids. [33] Dominated by quartz with less abundant K-feldspar, plagioclase, muscovite, biotite, and phosphates, that are interpreted to have formed under relatively low geothermal gradient similar to that pertaining to modern subduction zones. [14] [33]
Data type | Observation | Interpretation |
---|---|---|
Muscovite | Quartz and muscovite are the principal inclusion phases, potentially pointing to an aluminous granitic source. [14] [34] Hopkins (2010) used a thermodynamic solution model for celadonite substitution in muscovite [35] to estimate pressures for muscovite inclusions in magmatic zircons. The result revealed that the pressure conditions for over 1700 inclusion samples is greater than 5 kbar, coupled with a relatively low host zircons crystallization temperature. [35] | Muscovite inclusion coupled with a thermodynamic model implied that the Earth surface had a remarkably low heat flow. This result led scientists to suggest formation in an underthrust or subduction-like environment as found on the modern Earth [14] [34] |
Iron oxides | Cerium anomaly of a zircon (Ce/Ce*) is a quantitative investigation for host magma fO2. [36] Hadean Jack Hills zircons show a range in fO2 with an average near the fayalite-magnetite-quartz (FMQ) buffer. [37] | The Hadean geological setting is similar to the modern upper mantle [36] [37] |
Biotite | Composition of biotite differ among granitoids. FeO, MgO and Al2O3 content isolate calc-alkaline, peraluminous and alkaline granitoids. [38] [ full citation needed ] | The nature of Hadean melt compositions can be known. [38] |
Sulfide and carbonaceous phases have been revealed in Hadean zircon though the number of cases is small. [38] | The rare phases have deleted the volatile contents in Hadean magmas and source materials. [38] | |
Graphite | By knowing the occurrence of carbon, existence of life can be revealed in the aspect of timing, conditions and mechanisms. [39] [40] | Isotopic result identified the zircon was 3.8 to 3.5 billion years age and metabolism has occurred within the host microbiota. [39] [40] |
By analysing the content of zircon, some zircon show the presence of titanium, rare earth minerals, lithium, aluminium and carbon. Certain ratio and normal distribution give evidence of zircon's origin and the source of magma.
Data type | Observation | Interpretation | Limitation |
---|---|---|---|
Titanium | The content of Ti-in-zircon serves as a crystallization thermometer given knowledge of the melt aSiO2 and aTiO2. [41] [42] The Ti measurements were applied to grains ranging from 3.91 to 4.35 Ga and the majority of the data plots a normal distribution graph. [41] | Crystallisation of Ti-in-zircon grains are from evolved melts [41] | It yielded an extremely high temperature 680±25 °C. Since the crystallisation of rutile is unknown, researchers can only estimate the temperature by calculation. [43] |
Rare-earth mineral | Cerium anomaly of a zircon (Ce/Ce*) is a quantitative investigation for host magma fO2. [42] The result showed low value of Ce/Ce* ratio. | Diversity of source materials [42] | REE signatures in some zircon grains that have been interpreted to indicate crystallisation of these grains from evolved melts. [41] [42] [43] |
In EDS analysis, magnetite was dominant in the inclusion instead of ilmenite in granitoids. [44] | Hydrothermal alternation of zircon is often determined by high, flat light rare-earth mineral (LREE) pattern. [44] | ||
Lithium | Li zoning in zircon serve as a peak temperature indicator while examining retention of primary remanent magnetic signals. [32] Jack Hills zircon containing c. 5up-wide Li concentration band which required below 500 °C peak heating temperature of zircon. | The grains can be applied to study primary magnetism because it did not exceed the Curie temperature which is 585 °C for magnetite. [32] | The metaconglomerates at Erawondoo Hill did not experience temperature greater than 500 °C. [31] The result showed that there is variation of data and thermal history in different occurrences. [31] |
Aluminium | Peraluminous granitoids contain around 10 ppm aluminium in Jack Hills zircon [32] while the I-type and A-type zircon obtained average 1.3 ppm. The molar value of Al2O3/(CaO+Na2O+K2O) greater than 1. [45] | The origin is from recycled pelitic material. [45] | Small amount of sample zircon contains high Al contents suggests that metaluminous crustal rocks is more common than peraluminous rocks in the Hadean. However, the c. 20% overlap of low Al (i.e., < 5 ppm) in S-type zircons somewhat obscures this inference. [46] |
Some of the grains show high aluminium content [45] | Metaluminous crustal rocks may be more common than peraluminous rocks in the Hadean. [45] | ||
Carbon | Scientists measured concentration of carbon in the form of graphite in zircon by using secondary ion mass spectrometer (SIMS). Detecting Hadean crustal carbon could ensure that there was a transfer of carbon from mantle reservoirs [47] | Allow the selection among models of the early earth. [48] | Quite a few early earth models contain this property which cannot confirm which model is correct [47] [48] |
Ion microprobe (or secondary ion mass spectrometry, SIMS) and uranium-thorium-lead geochronology are two common methods to measure isotope in specific time interval. [49] [50]
Highly precise in situ SIMS measurements of oxygen isotopes [51] and OH/O ratios, laser-ablation inductively-coupled mass spectrometry (LA-ICP-MS) determination of hafnium isotopes, [52] [53] and atom-probe tomography. [54] LA-ICP-MS is the most common method to date using isotopes but it lacks capacity to measure 204Pb. Therefore, there is a possibility that the occurrences of single zircons over 4 billion years old could be due to inclusion of non-radiogenic Pb.
U-Pb dating, delta 18O and Ti measurements can be tested by CAMECA ims 1270 ion microprobe. [51] Epoxy are applied on the sample. A flat surface of sample is needed to conduct an analysis. [55] U-Pb dating and T measurement uses a primary O− beam with low intensity (10-15 nA). U-Pb age standard AS3 was used for dating studies. The concentration of Ti can be determined based on analysis of Jack Hills zircon [55] and NIST610 glass.
For inclusions investigation, JEOL 8600 electron microprobe analyzer (EPMA) were used to chemically analyze zircon. [1] It is used to analyze the chemical composition of material. Electron beams are emitted to the mineral's surface and blow off ions and estimate the abundance of the elements within a very small sized sample. Many isotopes can be measured at once in this analysis for example Ti and Li. [32]
Occurrences | Analytic method and result | Interpretation |
---|---|---|
Australia | ||
Mt. Narryer [56] [57] | Ion microprobe dating of 80 detrital zircons from quartzites have disclosed that 2% to 12% grains >4.0Ga, with younger zircons ranging to ca.3 Ga. In the LA-ICP-MS study, Mt. Narryer zircons has higher U contents and lowest Ce/Ce* in contrast to Jack Hills zircons | Diversity of source rock. Magmatic origins. |
Churla Wells [58] | The grains are 4.14 to 4.18Ga by using 207Pb/206Pb dating. Core region has a much lower Hf, REE, Uand Th than other outer region. While U content in core is around 666ppm, Th/U is 0.6. | Granitic magma origin |
Maynard Hills [59] | Dating of greenstone belt revealed that the 207Pb/206Pb age is 4.35Ga. | / |
Mt Alfred [60] | The concordant zircon has the age 4.17Ga. No geochemistry data has been collected | / |
North America | ||
Northwest Territory, Canada [61] [62] [63] | The protolith crystallisation age is 3.96Ga analysed by U-Pb dating. Applying LA-ICP-MS, 4.20+0.06Ga zircon was being dated. The unaltered zircon under the above method obtained LREE pattern. | Magmatic origin. Derivation from a felsic melt by a process other than differentiation of a mafic magma |
Greenland [64] [65] | The crystallisation age is determined as 3.83±0.01Ga by ion microprobe dating. 4.08±0.02Ga was identified in U-Pb survey | / |
Asia | ||
Tibet [66] | In ion microprobe method, detrital grain's Th/U ratios is greater than 0.7 | Magmatic origin |
North Qinling [67] | The LA-ICP-MS age of xenocrystic zircon in North Qinling Orogenic Belt is 4.08Ga. Hf isotope also support the age data of LA-ICP-MS test | / |
North China Craton [68] | The zircon is 4.17±0.05Ga determined by LA-ICP-MS U-Pb dating method. Th/U ratio is 0.46 | Magmatic origin |
South China [69] | Conducting ion microprobe U-Pb dating, 207Pb/206Pb age is 4.13±0.01 Ga with 5.9±0.1% 18O isotope data. Positive Ce anomaly | early earth is a highly oxidizing environment and a high Ti-in-zircons crystallization temperature of 910'C. |
South America | ||
Southern Guyana [70] | 4.22Ga by LA-ICP-MS U-Pb dating method. No other geochemical analysis has been conducted | / |
Eastern Brazil [71] | The age of the rock is 4.22Ga and Th/U ratios of 0.8 and high U contents (up to 1400ppm) | Felsic magmatic origin |
Plate tectonic theory is widely accepted for the generation of crust. With the Hadean rock record, most of the scientists concluded that the hypothesis of a hellish early Earth devoid of ocean is incorrect. [1] Scientists have constructed different models to explain the thermal history in the early earth, such as the continental growth model, [72] Icelandic rhyolites, [73] intermediate igneous rocks, mafic igneous rocks, sagduction, [74] impact melt, [75] heat-pipe tectonics, [76] terrestrial KREEP [77] and multi-stage scenarios.
The most famous one is continental growth model which is similar to the modern tectonic dynamics. [1]
Relatively low crystallisation temperature and some are enriched in heavy oxygen, contain inclusion similar to modern crustal processes and show evidence of silicate differentiation at ~4.5 Ga. [1] Early terrestrial hydrosphere, early felsic crust in which granitoids were produced and later weathered under high water activity conditions and even the possible existence of plate boundary interactions. [1] [78]
The Precambrian is the earliest part of Earth's history, set before the current Phanerozoic Eon. The Precambrian is so named because it preceded the Cambrian, the first period of the Phanerozoic Eon, which is named after Cambria, the Latinized name for Wales, where rocks from this age were first studied. The Precambrian accounts for 88% of the Earth's geologic time.
Zircon is a mineral belonging to the group of nesosilicates and is a source of the metal zirconium. Its chemical name is zirconium(IV) silicate, and its corresponding chemical formula is ZrSiO4. An empirical formula showing some of the range of substitution in zircon is (Zr1–y, REEy)(SiO4)1–x(OH)4x–y. Zircon precipitates from silicate melts and has relatively high concentrations of high field strength incompatible elements. For example, hafnium is almost always present in quantities ranging from 1 to 4%. The crystal structure of zircon is tetragonal crystal system. The natural color of zircon varies between colorless, yellow-golden, red, brown, blue, and green.
The Hadean is the first and oldest of the four known geologic eons of Earth's history, starting with the planet's formation about 4.6 billion years ago, and ended 4.031 billion years ago. The interplanetary collision that created the Moon occurred early in this eon. The Hadean eon was succeeded by the Archean eon, with the Late Heavy Bombardment hypothesized to have occurred at the Hadean-Archean boundary.
The sensitive high-resolution ion microprobe is a large-diameter, double-focusing secondary ion mass spectrometer (SIMS) sector instrument that was produced by Australian Scientific Instruments in Canberra, Australia and now has been taken over by Chinese company Dunyi Technology Development Co. (DTDC) in Beijing. Similar to the IMS 1270-1280-1300 large-geometry ion microprobes produced by CAMECA, Gennevilliers, France and like other SIMS instruments, the SHRIMP microprobe bombards a sample under vacuum with a beam of primary ions that sputters secondary ions that are focused, filtered, and measured according to their energy and mass.
The Acasta Gneiss Complex, also called the Acasta Gneiss, is a body of felsic to ultramafic Archean basement rocks, gneisses, that form the northwestern edge of the Slave Craton in the Northwest Territories, Canada, about 300 km (190 mi) north of Yellowknife, Canada. This geologic complex consists largely of tonalitic and granodioritic gneisses and lesser amounts of mafic and ultramafic gneisses. It underlies and is largely concealed by thin, patchy cover of Quaternary glacial sediments over an area of about 13,000 km2 (5,000 sq mi). The Acasta Gneiss Complex contains fragments of the oldest known crust and record of more than a billion years of magmatism and metamorphism. The Acasta Gneiss Complex is exposed in a set of anticlinoriums within the foreland fold and thrust belt of the Paleoproterozoic Wopmay Orogen.
The Jack Hills are a range of hills in Mid West Western Australia. They are best known as the source of the oldest material of terrestrial origin found to date: Hadean zircons that formed around 4.404 billion years ago. These zircons have enabled deeper research into the conditions on Earth in the Hadean eon. Potentially biogenic carbon isotope ratios have been identified for graphite embedded within a 4.1 billion-year-old zircon from the site.
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The Isua Greenstone Belt is an Archean greenstone belt in southwestern Greenland, aged between 3.7 and 3.8 billion years. The belt contains variably metamorphosed mafic volcanic and sedimentary rocks, and is the largest exposure of Eoarchaean supracrustal rocks on Earth. Due to its age and low metamorphic grade relative to many Eoarchaean rocks, the Isua Greenstone Belt has become a focus for investigations on the emergence of life and the style of tectonics that operated on the early Earth.
The Grouse Creek block is a Precambrian basement province of 2.45 to 2.70 billion year old orthogneisses. The Grouse Creek block is one of several Proterozoic and Archean accreted terranes that lie to the north and west of the Wyoming craton, including the Farmington Canyon Complex, the Selway terrane, the Medicine Hat block and the Priest River complex. Together, these terranes comprise part of the basement rock of the North American continent and have been critical to studies of crustal accretion in the Precambrian. Ongoing study of the Grouse Creek block will contribute to understanding the paleogeography of the Wyoming craton prior to its incorporation into the supercontinent Laurentia approximately 1.86 billion years ago. The name was proposed by David Foster and others.
The Chaotian is a proposed time division of the geologic time scale. First proposed in 2010 as an eon, it is named after Chaos, the primeval void in Greek mythology. This proposal defines the Chaotian eon as a Solar System-wide time between the initiation of planetary formation and the hypothesised collision of the trojan dwarf planet Theia with the proto-Earth.
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Titanium in zircon geothermometry is a form of a geothermometry technique by which the crystallization temperature of a zircon crystal can be estimated by the amount of titanium atoms which can only be found in the crystal lattice. In zircon crystals, titanium is commonly incorporated, replacing similarly charged zirconium and silicon atoms. This process is relatively unaffected by pressure and highly temperature dependent, with the amount of titanium incorporated rising exponentially with temperature, making this an accurate geothermometry method. This measurement of titanium in zircons can be used to estimate the cooling temperatures of the crystal and infer conditions during which it crystallized. Compositional changes in the crystals growth rings can be used to estimate the thermodynamic history of the entire crystal. This method is useful as it can be combined with radiometric dating techniques that are commonly used with zircon crystals, to correlate quantitative temperature measurements with specific absolute ages. This technique can be used to estimate early Earth conditions, determine metamorphic facies, or to determine the source of detrital zircons, among other uses.
Detrital zircon geochronology is the science of analyzing the age of zircons deposited within a specific sedimentary unit by examining their inherent radioisotopes, most commonly the uranium–lead ratio. Zircon is a common accessory or trace mineral constituent of most granite and felsic igneous rocks. Due to its hardness, durability and chemical inertness, zircon persists in sedimentary deposits and is a common constituent of most sands. Zircons contain trace amounts of uranium and thorium and can be dated using several modern analytical techniques.
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Lutetium–hafnium dating is a geochronological dating method utilizing the radioactive decay system of lutetium–176 to hafnium–176. With a commonly accepted half-life of 37.1 billion years, the long-living Lu–Hf decay pair survives through geological time scales, thus is useful in geological studies. Due to chemical properties of the two elements, namely their valences and ionic radii, Lu is usually found in trace amount in rare-earth element loving minerals, such as garnet and phosphates, while Hf is usually found in trace amount in zirconium-rich minerals, such as zircon, baddeleyite and zirkelite.
The Eastern Block of the North China Craton is one of the Earth's oldest pieces of continent. It is separated from the Western Block by the Trans-North China Orogen. It is situated in northeastern China and North Korea. The Block contains rock exposures older than 2.5 billion years. It serves as an ideal place to study how the crust was formed in the past and the related tectonic settings.
The Dharwar Craton is an Archean continental crust craton formed between 3.6-2.5 billion years ago (Ga), which is located in southern India and considered the oldest part of the Indian peninsula.
John Williams Valley is an American geochemist and petrologist. He is an expert on stable isotope geochemistry, especially as applied to understanding the evolution of the Earth's crust.
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