Thoriated glass is a glass material used in the manufacture of optical systems, specifically photographic lenses. It is useful to this process due to its high refractive index. Thoriated glass is radioactive due to the inclusion of thorium dioxide, oxide of radioactive element thorium. It has therefore been succeeded as a material of choice by glass including lanthanum oxide. Thoriated glass can contain up to 30% by weight of thorium. [1] The thoriated glass elements in lenses over time develop a brown tint reducing transmission and interfering with neutral color reproduction.
Many Kodak, Fuji and Asahi Takumar lenses that were produced prior to the 1970s are radioactive. [2]
Over extended time periods, thoriated glass may develop significant discoloration. This is due to induced F-centers forming in the glass as the radioactive decay of the thorium progresses. [3] The formation of F-centers is due to the ionizing effect of the high energy thorium decay products. This process can potentially be reversed by annealing the glass or exposing it to light. [4]
Neodymium is a chemical element; it has symbol Nd and atomic number 60. It is the fourth member of the lanthanide series and is considered to be one of the rare-earth metals. It is a hard, slightly malleable, silvery metal that quickly tarnishes in air and moisture. When oxidized, neodymium reacts quickly producing pink, purple/blue and yellow compounds in the +2, +3 and +4 oxidation states. It is generally regarded as having one of the most complex spectra of the elements. Neodymium was discovered in 1885 by the Austrian chemist Carl Auer von Welsbach, who also discovered praseodymium. It is present in significant quantities in the minerals monazite and bastnäsite. Neodymium is not found naturally in metallic form or unmixed with other lanthanides, and it is usually refined for general use. Neodymium is fairly common—about as common as cobalt, nickel, or copper—and is widely distributed in the Earth's crust. Most of the world's commercial neodymium is mined in China, as is the case with many other rare-earth metals.
Thorium is a chemical element. It has the symbol Th and atomic number 90. Thorium is a weakly radioactive light silver metal which tarnishes olive gray when it is exposed to air, forming thorium dioxide; it is moderately soft and malleable and has a high melting point. Thorium is an electropositive actinide whose chemistry is dominated by the +4 oxidation state; it is quite reactive and can ignite in air when finely divided.
Uranium is a chemical element; it has symbol U and atomic number 92. It is a silvery-grey metal in the actinide series of the periodic table. A uranium atom has 92 protons and 92 electrons, of which 6 are valence electrons. Uranium radioactively decays, usually by emitting an alpha particle. The half-life of this decay varies between 159,200 and 4.5 billion years for different isotopes, making them useful for dating the age of the Earth. The most common isotopes in natural uranium are uranium-238 and uranium-235. Uranium has the highest atomic weight of the primordially occurring elements. Its density is about 70% higher than that of lead and slightly lower than that of gold or tungsten. It occurs naturally in low concentrations of a few parts per million in soil, rock and water, and is commercially extracted from uranium-bearing minerals such as uraninite.
Radioactive waste is a type of hazardous waste that contains radioactive material. Radioactive waste is a result of many activities, including nuclear medicine, nuclear research, nuclear power generation, nuclear decommissioning, rare-earth mining, and nuclear weapons reprocessing. The storage and disposal of radioactive waste is regulated by government agencies in order to protect human health and the environment.
Monazite is a primarily reddish-brown phosphate mineral that contains rare-earth elements. Due to variability in composition, monazite is considered a group of minerals. The most common species of the group is monazite-(Ce), that is, the cerium-dominant member of the group. It occurs usually in small isolated crystals. It has a hardness of 5.0 to 5.5 on the Mohs scale of mineral hardness and is relatively dense, about 4.6 to 5.7 g/cm3. There are five different most common species of monazite, depending on the relative amounts of the rare earth elements in the mineral:
An incandescent gas mantle, gas mantle or Welsbach mantle is a device for generating incandescent bright white light when heated by a flame. The name refers to its original heat source in gas lights which illuminated the streets of Europe and North America in the late 19th century. Mantle refers to the way it hangs like a cloak above the flame. Gas mantles were also used in portable camping lanterns, pressure lanterns and some oil lamps.
Thorium dioxide (ThO2), also called thorium(IV) oxide, is a crystalline solid, often white or yellow in colour. Also known as thoria, it is mainly a by-product of lanthanide and uranium production. Thorianite is the name of the mineralogical form of thorium dioxide. It is moderately rare and crystallizes in an isometric system. The melting point of thorium oxide is 3300 °C – the highest of all known oxides. Only a few elements (including tungsten and carbon) and a few compounds (including tantalum carbide) have higher melting points. All thorium compounds, including the dioxide, are radioactive because there are no stable isotopes of thorium.
Gas tungsten arc welding is an arc welding process that uses a non-consumable tungsten electrode to produce the weld. The weld area and electrode are protected from oxidation or other atmospheric contamination by an inert shielding gas. A filler metal is normally used, though some welds, known as 'autogenous welds', or 'fusion welds' do not require it. A constant-current welding power supply produces electrical energy, which is conducted across the arc through a column of highly ionized gas and metal vapors known as a plasma.
Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion, making them more resistant to thermal shock than any other common glass. Such glass is subjected to less thermal stress and can withstand temperature differentials without fracturing of about 165 °C (300 °F). It is commonly used for the construction of reagent bottles and flasks, as well as lighting, electronics, and cookware.
Thorium (90Th) has seven naturally occurring isotopes but none are stable. One isotope, 232Th, is relatively stable, with a half-life of 1.405×1010 years, considerably longer than the age of the Earth, and even slightly longer than the generally accepted age of the universe. This isotope makes up nearly all natural thorium, so thorium was considered to be mononuclidic. However, in 2013, IUPAC reclassified thorium as binuclidic, due to large amounts of 230Th in deep seawater. Thorium has a characteristic terrestrial isotopic composition and thus a standard atomic weight can be given.
In vacuum tubes and gas-filled tubes, a hot cathode or thermionic cathode is a cathode electrode which is heated to make it emit electrons due to thermionic emission. This is in contrast to a cold cathode, which does not have a heating element. The heating element is usually an electrical filament heated by a separate electric current passing through it. Hot cathodes typically achieve much higher power density than cold cathodes, emitting significantly more electrons from the same surface area. Cold cathodes rely on field electron emission or secondary electron emission from positive ion bombardment, and do not require heating. There are two types of hot cathode. In a directly heated cathode, the filament is the cathode and emits the electrons. In an indirectly heated cathode, the filament or heater heats a separate metal cathode electrode which emits the electrons.
Spent nuclear fuel, occasionally called used nuclear fuel, is nuclear fuel that has been irradiated in a nuclear reactor. It is no longer useful in sustaining a nuclear reaction in an ordinary thermal reactor and, depending on its point along the nuclear fuel cycle, it will have different isotopic constituents than when it started.
The Canon FD 35mm f/2.0 lens was manufactured by Canon for the FD lens mount. It was sold in a number of variations over the years, and was the fastest Canon lens in the 35mm focal length before the debut of the EF 35mm f1.4.
Low-dispersion glass is a type of glass with a reduction in chromatic aberration. Crown glass is an example of a relatively inexpensive low-dispersion glass.
Precision glass moulding is a replicative process that allows the production of high precision optical components from glass without grinding and polishing. The process is also known as ultra-precision glass pressing. It is used to manufacture precision glass lenses for consumer products such as digital cameras, and high-end products like medical systems. The main advantage over mechanical lens production is that complex lens geometries such as aspheres can be produced cost-efficiently.
Cerium is a chemical element; it has symbol Ce and atomic number 58. Cerium is a soft, ductile, and silvery-white metal that tarnishes when exposed to air. Cerium is the second element in the lanthanide series, and while it often shows the oxidation state of +3 characteristic of the series, it also has a stable +4 state that does not oxidize water. It is also considered one of the rare-earth elements. Cerium has no known biological role in humans but is not particularly toxic, except with intense or continued exposure.
Nuclear transmutation is the conversion of one chemical element or an isotope into another chemical element. Nuclear transmutation occurs in any process where the number of protons or neutrons in the nucleus of an atom is changed.
Yttralox is a transparent ceramic consisting of yttria (Y2O3) containing approximately 10% thorium dioxide (ThO2). It was one of the first transparent ceramics produced, and was invented in 1966 by Richard C. Anderson at the General Electric Research Laboratory while sintering mixtures of rare earth minerals.
The Canon FD 55mm ƒ/1.2 AL is a camera lens made by Canon, first introduced alongside the Canon F-1 single-lens reflex camera in March 1971. It was the first lens for any 35mm SLR system to incorporate an aspherical element. The lens was manufactured until 1980.
Optical glass refers to a quality of glass suitable for the manufacture of optical systems such as optical lenses, prisms or mirrors. Unlike window glass or crystal, whose formula is adapted to the desired aesthetic effect, optical glass contains additives designed to modify certain optical or mechanical properties of the glass: refractive index, dispersion, transmittance, thermal expansion and other parameters. Lenses produced for optical applications use a wide variety of materials, from silica and conventional borosilicates to elements such as germanium and fluorite, some of which are essential for glass transparency in areas other than the visible spectrum.
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