Glass is a non-crystalline, often transparent amorphous solid, that has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics. Glass is most often formed by rapid cooling (quenching) of the molten form; some glasses such as volcanic glass are naturally occurring. The most familiar, and historically the oldest, types of manufactured glass are "silicate glasses" based on the chemical compound silica, the primary constituent of sand. Soda–lime glass, containing around 70% silica, accounts for around 90% of manufactured glass. The term glass, in popular usage, is often used to refer only to this type of material, although silica-free glasses often have desirable properties for applications in modern communications technology. Some objects, such as drinking glasses and eyeglasses, are so commonly made of silicate-based glass that they are simply called by the name of the material.
Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses to a carefully regulated heat treatment schedule, resulting in the nucleation and growth of crystal phases. In many cases, the crystallization process can proceed to near completion, but in a small proportion of processes, the residual glass phase often remains. Glass-ceramic materials share many properties with both glasses and ceramics. Glass-ceramics have an amorphous phase and one or more crystalline phases and are produced by a so-called "controlled crystallization" in contrast to a spontaneous crystallization, which is usually not wanted in glass manufacturing. Glass-ceramics have the fabrication advantage of glass, as well as special properties of ceramics. When used for sealing, some glass-ceramics do not require brazing but can withstand brazing temperatures up to 700 °C. Glass-ceramics usually have between 30% [m/m] and 90% [m/m] crystallinity and yield an array of materials with interesting properties like zero porosity, high strength, toughness, translucency or opacity, pigmentation, opalescence, low or even negative thermal expansion, high temperature stability, fluorescence, machinability, ferromagnetism, resorbability or high chemical durability, biocompatibility, bioactivity, ion conductivity, superconductivity, isolation capabilities, low dielectric constant and loss, corrosion resistance, high resistivity and break-down voltage. These properties can be tailored by controlling the base-glass composition and by controlled heat treatment/crystallization of base glass. In manufacturing, glass-ceramics are valued for having the strength of ceramic but the hermetic sealing properties of glass.
Fused quartz,fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses in which other ingredients are added which change the glasses' optical and physical properties, such as lowering the melt temperature. Fused quartz, therefore, has high working and melting temperatures, making it less desirable for most common applications.
Invar, also known generically as FeNi36, is a nickel–iron alloy notable for its uniquely low coefficient of thermal expansion. The name Invar comes from the word invariable, referring to its relative lack of expansion or contraction with temperature changes.
A superhard material is a material with a hardness value exceeding 40 gigapascals (GPa) when measured by the Vickers hardness test. They are virtually incompressible solids with high electron density and high bond covalency. As a result of their unique properties, these materials are of great interest in many industrial areas including, but not limited to, abrasives, polishing and cutting tools, disc brakes, and wear-resistant and protective coatings.
Maraging steels are steels that are known for possessing superior strength and toughness without losing ductility. Aging refers to the extended heat-treatment process. These steels are a special class of very-low-carbon ultra-high-strength steels that derive their strength not from carbon, but from precipitation of intermetallic compounds. The principal alloying element is 15 to 25 wt% nickel. Secondary alloying elements, which include cobalt, molybdenum and titanium, are added to produce intermetallic precipitates. Original development was carried out on 20 and 25 wt% Ni steels to which small additions of aluminium, titanium, and niobium were made; a rise in the price of cobalt in the late 1970s led to the development of cobalt-free maraging steels.
Thermal shock is a type of rapidly transient mechanical load. By definition, it is a mechanical load caused by a rapid change of temperature of a certain point. It can be also extended to the case of a thermal gradient, which makes different parts of an object expand by different amounts. This differential expansion can be more directly understood in terms of strain, than in terms of stress, as it is shown in the following. At some point, this stress can exceed the tensile strength of the material, causing a crack to form. If nothing stops this crack from propagating through the material, it will cause the object's structure to fail.
Borosilicate glass is a type of glass with silica and boron trioxide as the main glass-forming constituents. Borosilicate glasses are known for having very low coefficients of thermal expansion, making them more resistant to thermal shock than any other common glass. Such glass is subjected to less thermal stress and can withstand temperature differentials without fracturing of about 165 °C (300 °F). It is commonly used for the construction of reagent bottles and flasks as well as lighting, electronics, and cookware.
Thermal expansion is the tendency of matter to change its shape, area, volume, and density in response to a change in temperature, usually not including phase transitions.
Vycor is the brand name of Corning's high-silica, high-temperature glass. It provides very high thermal shock resistance. Vycor is approximately 96% silica and 4% boron trioxide, but unlike pure fused silica, it can be readily manufactured in a variety of shapes.
Titanium nitride is an extremely hard ceramic material, often used as a physical vapor deposition (PVD) coating on titanium alloys, steel, carbide, and aluminium components to improve the substrate's surface properties.
Negative thermal expansion (NTE) is an unusual physicochemical process in which some materials contract upon heating, rather than expand as most other materials do. The most well-known material with NTE is water at 0~4 °C. Water's NTE is the reason why ice floats, rather than sinks, in liquid water. Materials which undergo NTE have a range of potential engineering, photonic, electronic, and structural applications. For example, if one were to mix a negative thermal expansion material with a "normal" material which expands on heating, it could be possible to use it as a thermal expansion compensator what might allow for forming composites with tailored or even close to zero thermal expansion.
Aluminium oxynitride is a transparent ceramic composed of aluminium, oxygen and nitrogen. ALON is optically transparent (≥ 80%) in the near-ultraviolet, visible, and midwave-infrared regions of the electromagnetic spectrum. It is four times as hard as fused silica glass, 85% as hard as sapphire, and nearly 115% as hard as magnesium aluminate spinel. Since it has a cubic spinel structure, it can be fabricated to transparent windows, plates, domes, rods, tubes, and other forms using conventional ceramic powder processing techniques.
Aluminosilicate minerals are minerals composed of aluminium, silicon, and oxygen, plus countercations. They are a major component of kaolin and other clay minerals.
Zerodur, a registered trademark of Schott AG, is a lithium-aluminosilicate glass-ceramic produced by Schott AG since 1968. It has been used for a number of very large telescope mirrors including GTC, Keck I, Keck II, and SOFIA, as well as some smaller telescopes. With its very low coefficient of thermal expansion (CTE) it can be used to produce mirrors that retain acceptable figures in extremely cold environments such as deep space. Although it has advantages for applications requiring a coefficient of thermal expansion less than that of borosilicate glass, it remains very expensive as compared to borosilicate. The tight tolerance on CTE, ±0.007×10−6 K−1, allows for its use in high-precision applications.
Aluminum magnesium boride or Al3Mg3B56 colliqually known as BAM is a chemical compound of aluminium, magnesium and boron. Whereas its nominal formula is AlMgB14, the chemical composition is closer to Al0.75Mg0.75B14. It is a ceramic alloy that is highly resistive to wear and has an extremely low coefficient of sliding friction, reaching a record value of 0.04 in unlubricated and 0.02 in lubricated AlMgB14−TiB2 composites. First reported in 1970, BAM has an orthorhombic structure with four icosahedral B12 units per unit cell. This ultrahard material has a coefficient of thermal expansion comparable to that of other widely used materials such as steel and concrete.
Concrete has relatively high compressive strength, but significantly lower tensile strength. The compressive strength is typically controlled with the ratio of water to cement when forming the concrete, and tensile strength is increased by additives, typically steel, to create reinforced concrete. In other words we can say concrete is made up of sand, ballast, cement and water.
Sitall is a crystalline glass-ceramic with ultra-low coefficient of thermal expansion (CTE). It was originally manufactured in the former Soviet Union and was used in the making of primary mirrors for the Russian Maksutov telescopes, but since dissolution has diminished in quality. It has a CTE of only 0 ± 1.5×10−7 °C−1 in the temperature range −60 to 60 °C, placing it in a small group of transparent materials with low CTE such as Vycor, Zerodur, Cer‑Vit and fused quartz.
Macor is the trademark for a machinable glass-ceramic developed and sold by Corning Inc. It is a white material that looks somewhat like porcelain. Macor is a good thermal insulator and is stable up to temperatures of 1000 °C, with very little thermal expansion or outgassing. It can be machined using standard metalworking tools.
Optothermal stability describes the rate at which an optical element distorts due to a changing thermal environment. A changing thermal environment can cause an optic to bend due to either 1) changing thermal gradients on the optic and a non-zero coefficient of thermal expansion, or 2) coefficient of thermal expansion gradients in an optic and an average temperature change. Therefore, optothermal stability is an issue for optics that are present in a changing thermal environment. For example, a space telescope will experience variable heat loads from changes in spacecraft attitude, solar flux, planetary albedo, and planetary infrared emissions. Optothermal stability can be important when measuring the surface figure of optics, because thermal changes are typically low frequency which makes it difficult to use measurement averaging to remove errors. Also, optothermal stability is important for optical systems which require a high level of stability such as those that use a coronagraph.
