Photosensitive glass, also called photostructurable glass (PSG) or photomachinable glass, is a glass in the lithium-silicate family of glasses onto which images can be etched using shortwave radiations, such as ultraviolet. [1] Photosensitive glass was first discovered by S. Donald Stookey in 1937. [2] [3] [4]
When the glass is exposed to UV light with wavelengths between 280–320 nm, a latent image is formed. The glass remains transparent at this stage, but its ability to absorb UV light increases. This increased absorption is only detectable using UV transmission spectroscopy and is caused by an oxidation reduction reaction that occurs inside the glass during exposure. This reaction causes cerium ions to oxidize to a more stable state, and silver ions are reduced to silver. [5]
The latent image captured in the glass is made visible by heating. [6] [2] [4] This heat treatment is done by raising the temperature to about 500 °C to allow the oxidation-reduction reaction to form silver nanoclusters. Following this, the temperature is raised to 550–560 °C and lithium metasilicate (Li2SiO3) forms on the silver nanoclusters. This material forms in the crystalline phase. [6]
The lithium metasilicate in the exposed regions of the glass can be etched by hydrofluoric acid (HF). This forms glass microstructures with a roughness in the range of 5 μm, resulting in a three-dimensional image of the mask to be produced. [1] to 0.7 μm. [6]
Glass is a non-crystalline solid that is often transparent, brittle and chemically inert. It has widespread practical, technological, and decorative use in, for example, window panes, tableware, and optics.
MEMS is the technology of microscopic devices incorporating both electronic and moving parts. MEMS are made up of components between 1 and 100 micrometres in size, and MEMS devices generally range in size from 20 micrometres to a millimetre, although components arranged in arrays can be more than 1000 mm2. They usually consist of a central unit that processes data and several components that interact with the surroundings.
Corrosion is a natural process that converts a refined metal into a more chemically stable oxide. It is the gradual deterioration of materials by chemical or electrochemical reaction with their environment. Corrosion engineering is the field dedicated to controlling and preventing corrosion.
Glass-ceramics are polycrystalline materials produced through controlled crystallization of base glass, producing a fine uniform dispersion of crystals throughout the bulk material. Crystallization is accomplished by subjecting suitable glasses to a carefully regulated heat treatment schedule, resulting in the nucleation and growth of crystal phases. In many cases, the crystallization process can proceed to near completion, but in a small proportion of processes, the residual glass phase often remains.
Fused quartz, fused silica or quartz glass is a glass consisting of almost pure silica (silicon dioxide, SiO2) in amorphous (non-crystalline) form. This differs from all other commercial glasses, such as soda-lime glass, lead glass, or borosilicate glass, in which other ingredients are added which change the glasses' optical and physical properties, such as lowering the melt temperature, the spectral transmission range, or the mechanical strength. Fused quartz, therefore, has high working and melting temperatures, making it difficult to form and less desirable for most common applications, but is much stronger, more chemically resistant, and exhibits lower thermal expansion, making it more suitable for many specialized uses such as lighting and scientific applications.
Many ceramic materials, both glassy and crystalline, have found use as optically transparent materials in various forms from bulk solid-state components to high surface area forms such as thin films, coatings, and fibers. Such devices have found widespread use for various applications in the electro-optical field including: optical fibers for guided lightwave transmission, optical switches, laser amplifiers and lenses, hosts for solid-state lasers and optical window materials for gas lasers, and infrared (IR) heat seeking devices for missile guidance systems and IR night vision. In commercial and general knowledge domains, it is commonly accepted that transparent ceramics or ceramic glass are varieties of strengthened glass, such as those used for the screen glass on an iPhone.
Silver bromide (AgBr) is a soft, pale-yellow, water-insoluble salt well known for its unusual sensitivity to light. This property has allowed silver halides to become the basis of modern photographic materials. AgBr is widely used in photographic films and is believed by some to have been used for making the Shroud of Turin. The salt can be found naturally as the mineral bromargyrite.
Silver chloride is an inorganic chemical compound with the chemical formula AgCl. This white crystalline solid is well known for its low solubility in water and its sensitivity to light. Upon illumination or heating, silver chloride converts to silver, which is signaled by grey to black or purplish coloration in some samples. AgCl occurs naturally as the mineral chlorargyrite.
Arsenic trisulfide is the inorganic compound with the formula As2S3. It is a dark yellow solid that is insoluble in water. It also occurs as the mineral orpiment, which has been used as a pigment called King's yellow. It is produced in the analysis of arsenic compounds. It is a group V/VI, intrinsic p-type semiconductor and exhibits photo-induced phase-change properties.
Sodium oxide is a chemical compound with the formula Na2O. It is used in ceramics and glasses. It is a white solid but the compound is rarely encountered. Instead "sodium oxide" is used to describe components of various materials such as glasses and fertilizers which contain oxides that include sodium and other elements. Sodium oxide is a component.
ZBLAN is the most stable, and consequently the most used, fluoride glass, a subcategory of the heavy metal fluoride glass (HMFG) group. Typically its composition is 53% ZrF4, 20% BaF2, 4% LaF3, 3% AlF3 and 20% NaF. ZBLAN is not a single material but rather has a spectrum of compositions, many of which are still untried. The biggest library in the world of ZBLAN glass compositions is currently owned by Le Verre Fluore, the oldest company working on HMFG technology. Other current ZBLAN fiber manufacturers are Thorlabs and KDD Fiberlabs. Hafnium fluoride is chemically similar to zirconium fluoride, and is sometimes used in place of it.
A photochromic lens is an optical lens that darkens on exposure to light of sufficiently high frequency, most commonly ultraviolet (UV) radiation. In the absence of activating light, the lenses return to their clear state. Photochromic lenses may be made of polycarbonate, or another plastic. Glass lenses use visible light to darken. They are principally used in glasses that are dark in bright sunlight, but clear, or more rarely, lightly tinted in low ambient light conditions. They darken significantly within about a minute of exposure to bright light and take somewhat longer to clear. A range of clear and dark transmittances is available.
Stanley Donald Stookey was an American inventor. He had 60 patents in his name related to glass and ceramics, some patents solely his and others shared as joint patents with other inventors. His discoveries and inventions have contributed to the development of ceramics, eyeglasses, sunglasses, cookware, defense systems, and electronics.
Glass-to-metal seals are a type of mechanical seal which joins glass and metal surfaces. They are very important elements in the construction of vacuum tubes, electric discharge tubes, incandescent light bulbs, glass-encapsulated semiconductor diodes, reed switches, glass windows in metal cases, and metal or ceramic packages of electronic components.
Lithium cobalt oxide, sometimes called lithium cobaltate or lithium cobaltite, is a chemical compound with formula LiCoO
2. The cobalt atoms are formally in the +3 oxidation state, hence the IUPAC name lithium cobalt(III) oxide.
Glass coloring and color marking may be obtained in several ways.
Pyroceram is the original glass-ceramic material developed and trademarked by Corning Glass in the 1950s. Pyroceram is an opaque, white, glass material, commonly used in kitchenware, glass stove tops, wood stove doors, etc.. It has high heat tolerance and low thermal expansion.
Nanoclusters are atomically precise, crystalline materials most often existing on the 0-2 nanometer scale. They are often considered kinetically stable intermediates that form during the synthesis of comparatively larger materials such as semiconductor and metallic nanocrystals. The majority of research conducted to study nanoclusters has focused on characterizing their crystal structures and understanding their role in the nucleation and growth mechanisms of larger materials.
Foturan is a photosensitive glass by SCHOTT Corporation developed in 1984. It is a technical glass-ceramic which can be structured without photoresist when it is exposed to shortwave radiation such as ultraviolet light and subsequently etched.
Optical glass refers to a quality of glass suitable for the manufacture of optical systems such as optical lenses, prisms or mirrors. Unlike window glass or crystal, whose formula is adapted to the desired aesthetic effect, optical glass contains additives designed to modify certain optical or mechanical properties of the glass: refractive index, dispersion, transmittance, thermal expansion and other parameters. Lenses produced for optical applications use a wide variety of materials, from silica and conventional borosilicates to elements such as germanium and fluorite, some of which are essential for glass transparency in areas other than the visible spectrum.
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