Chemically strengthened glass

Last updated

Chemically strengthened glass is a type of glass that has increased strength as a result of a post-production chemical process. When broken, it still shatters in long pointed splinters similar to float glass. For this reason, it is not considered a safety glass and must be laminated if a safety glass is required. However, chemically strengthened glass is typically six to eight times the strength of float glass. The most common trademark for this kind of glass is Gorilla glass.

Contents

Glass

The glass is chemically strengthened by a surface finishing process. Glass is submersed in a bath of a molten potassium salt (typically potassium nitrate) at temperatures of 334 °C (630 °F) or greater [1] . This causes sodium ions in the glass surface to be replaced by potassium ions from the bath.

These potassium ions are larger than the sodium ions and therefore wedge into the gaps left by the smaller sodium ions when they migrate to the molten potassium nitrate. This replacement of ions causes the surface of the glass to be in a state of compression and the core in compensating tension. The surface compression of chemically strengthened glass may reach up to 690 megapascals (100,000 psi).

The strengthening mechanism depends on the fact that the compressive strength of glass is significantly higher than its tensile strength. With both surfaces of the glass already in compression, it takes a certain amount of bending before one of the surfaces can even go into tension. More bending is required to reach the tensile strength. The other surface simply experiences more and more compressive stress. But since the compressive strength is so much larger, no compressive failure is experienced.

Because the surface of chemically strengthened glass is in compression, it is also significantly more scratch resistant than untreated glass. This is why cell phone screens are typically made this way. Since phones are commonly carried in a pocket or purse with other items such as keys, scratch resistance is important.

There also exists a more advanced two-stage process for making chemically strengthened glass, in which the glass article is first immersed in a sodium nitrate bath at 450 °C (842 °F), which enriches the surface with sodium ions. This leaves more sodium ions on the glass for the immersion in potassium nitrate to replace with potassium ions. In this way, the use of a sodium nitrate bath increases the potential for surface compression in the finished article.

Chemical strengthening results in a strengthening similar to toughened glass. However, the process does not use extreme variations of temperature and therefore chemically strengthened glass has little or no bow or warp, optical distortion or strain pattern. This differs from toughened glass, in which slender pieces can be significantly bowed.

Also unlike toughened glass, chemically strengthened glass may be cut after strengthening, but loses its added strength within the region of approximately 20 mm of the cut. Similarly, when the surface of chemically strengthened glass is deeply scratched, this area loses its additional strength.

Another negative of chemically strengthened glass is the added cost. While tempered glass can be made cheaply through the fabrication process, chemically strengthened glass has a much more expensive route to the market. These costs make the product prohibitive for use in many applications. [2]

Chemically strengthened glass was used for the aircraft canopy of some fighter aircraft.

See also

Related Research Articles

<span class="mw-page-title-main">Reinforced concrete</span> Concrete with rebar

Reinforced concrete, also called ferroconcrete, is a composite material in which concrete's relatively low tensile strength and ductility are compensated for by the inclusion of reinforcement having higher tensile strength or ductility. The reinforcement is usually, though not necessarily, steel bars (rebar) and is usually embedded passively in the concrete before the concrete sets. However, post-tensioning is also employed as a technique to reinforce the concrete. In terms of volume used annually, it is one of the most common engineering materials. In corrosion engineering terms, when designed correctly, the alkalinity of the concrete protects the steel rebar from corrosion.

<span class="mw-page-title-main">Potassium nitrate</span> Chemical compound

Potassium nitrate is a chemical compound with a sharp, salty, bitter taste and the chemical formula KNO
3
. It is an ionic salt of potassium ions K+ and nitrate ions NO3, and is therefore an alkali metal nitrate. It occurs in nature as a mineral, niter (or nitre in the UK). It is a source of nitrogen, and nitrogen was named after niter. Potassium nitrate is one of several nitrogen-containing compounds collectively referred to as saltpeter (or saltpetre in the UK).

<span class="mw-page-title-main">Glass fiber</span> Material consisting of numerous extremely fine fibers of glass

Glass fiber is a material consisting of numerous extremely fine fibers of glass.

Fiberglass or fibreglass is a common type of fiber-reinforced plastic using glass fiber. The fibers may be randomly arranged, flattened into a sheet called a chopped strand mat, or woven into glass cloth. The plastic matrix may be a thermoset polymer matrix—most often based on thermosetting polymers such as epoxy, polyester resin, or vinyl ester resin—or a thermoplastic.

<span class="mw-page-title-main">Float glass</span> Material; type of glass

Float glass is a sheet of glass made by floating molten glass on a bed of molten metal of a low melting point, typically tin, although lead was used for the process in the past. This method gives the sheet uniform thickness and a very flat surface. The float glass process is also known as the Pilkington process, named after the British glass manufacturer Pilkington, which pioneered the technique in the 1950s at their production site in St Helens, Merseyside.

<span class="mw-page-title-main">Compressive strength</span> Capacity of a material or structure to withstand loads tending to reduce size

In mechanics, compressive strength is the capacity of a material or structure to withstand loads tending to reduce size. In other words, compressive strength resists compression, whereas tensile strength resists tension. In the study of strength of materials, tensile strength, compressive strength, and shear strength can be analyzed independently.

Fibre-reinforced plastic is a composite material made of a polymer matrix reinforced with fibres. The fibres are usually glass, carbon, aramid, or basalt. Rarely, other fibres such as paper, wood, boron, or asbestos have been used. The polymer is usually an epoxy, vinyl ester, or polyester thermosetting plastic, though phenol formaldehyde resins are still in use.

<span class="mw-page-title-main">Tempering (metallurgy)</span> Process of heat treating used to increase the toughness of iron-based alloys

Tempering is a process of heat treating, which is used to increase the toughness of iron-based alloys. Tempering is usually performed after hardening, to reduce some of the excess hardness, and is done by heating the metal to some temperature below the critical point for a certain period of time, then allowing it to cool in still air. The exact temperature determines the amount of hardness removed, and depends on both the specific composition of the alloy and on the desired properties in the finished product. For instance, very hard tools are often tempered at low temperatures, while springs are tempered at much higher temperatures.

<span class="mw-page-title-main">Residual stress</span> Stresses which remain in a solid material after the original cause is removed

In materials science and solid mechanics, residual stresses are stresses that remain in a solid material after the original cause of the stresses has been removed. Residual stress may be desirable or undesirable. For example, laser peening imparts deep beneficial compressive residual stresses into metal components such as turbine engine fan blades, and it is used in toughened glass to allow for large, thin, crack- and scratch-resistant glass displays on smartphones. However, unintended residual stress in a designed structure may cause it to fail prematurely.

Bluing, sometimes spelled as blueing, is a passivation process in which steel is partially protected against rust using a black oxide coating. It is named after the blue-black appearance of the resulting protective finish. Bluing involves an electrochemical conversion coating resulting from an oxidizing chemical reaction with iron on the surface selectively forming magnetite, the black oxide of iron. In comparison, rust, the red oxide of iron, undergoes an extremely large volume change upon hydration; as a result, the oxide easily flakes off, causing the typical reddish rusting away of iron. Black oxide provides minimal protection against corrosion, unless also treated with a water-displacing oil to reduce wetting and galvanic action. In colloquial use, thin coatings of black oxide are often termed 'gun bluing', while heavier coatings are termed 'black oxide'. Both refer to the same chemical process for providing true gun bluing.

<span class="mw-page-title-main">Architectural glass</span>

Architectural glass is glass that is used as a building material. It is most typically used as transparent glazing material in the building envelope, including windows in the external walls. Glass is also used for internal partitions and as an architectural feature. When used in buildings, glass is often of a safety type, which include reinforced, toughened and laminated glasses.

<span class="mw-page-title-main">Sight glass</span>

A sight glass or water gauge is a type of level sensor, a transparent tube through which the operator of a tank or boiler can observe the level of liquid contained within.

<span class="mw-page-title-main">Tempered glass</span> Type of safety glass processed to increase its strength

Tempered or toughened glass is a type of safety glass processed by controlled thermal or chemical treatments to increase its strength compared with normal glass. Tempering puts the outer surfaces into compression and the interior into tension. Such stresses cause the glass, when broken, to shatter into small granular chunks instead of splintering into jagged shards as ordinary annealed glass does. The granular chunks are less likely to cause injury.

A Bologna bottle, also known as a Bologna phial or philosophical vial, is a glass bottle which has great external strength, often used in physics demonstrations and magic tricks. The exterior is generally strong enough that one could pound a nail into a block of wood using the bottle as a hammer; however, even a small scratch on the interior would cause it to crumble.

Methods have been devised to modify the yield strength, ductility, and toughness of both crystalline and amorphous materials. These strengthening mechanisms give engineers the ability to tailor the mechanical properties of materials to suit a variety of different applications. For example, the favorable properties of steel result from interstitial incorporation of carbon into the iron lattice. Brass, a binary alloy of copper and zinc, has superior mechanical properties compared to its constituent metals due to solution strengthening. Work hardening has also been used for centuries by blacksmiths to introduce dislocations into materials, increasing their yield strengths.

Glass production involves two main methods – the float glass process that produces sheet glass, and glassblowing that produces bottles and other containers. It has been done in a variety of ways during the history of glass.

Concrete has relatively high compressive strength, but significantly lower tensile strength. The compressive strength is typically controlled with the ratio of water to cement when forming the concrete, and tensile strength is increased by additives, typically steel, to create reinforced concrete. In other words we can say concrete is made up of sand, ballast, cement and water.

<span class="mw-page-title-main">Gorilla Glass</span> Chemically strengthened glass made by Corning

Gorilla Glass is a brand of chemically strengthened glass developed and manufactured by Corning. It is in its eighth generation. Designed to be thin, light and damage-resistant, the glass gains its surface strength, ability to contain flaws, and crack-resistance by being immersed in a hot, potassium-salt, ion-exchange bath.

Glass typically has a tensile strength of 7 megapascals (1,000 psi). However, the theoretical upper bound on its strength is orders of magnitude higher: 17 gigapascals (2,500,000 psi). This high value is due to the strong chemical Si–O bonds of silicon dioxide. Imperfections of the glass, such as bubbles, and in particular surface flaws, such as scratches, have a great effect on the strength of glass and decrease it even more than for other brittle materials. The chemical composition of the glass also impacts its tensile strength. The processes of thermal and chemical toughening can increase the tensile strength of glass.

References

  1. PubChem. "Potassium Nitrate". pubchem.ncbi.nlm.nih.gov. Retrieved 2024-04-23.
  2. Munden, Jacob (23 June 2018). "What is Chemical Tempering?". Barrett Limited.