Atomic engineering

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Atomic engineering is an engineering discipline concerned with the scale of materials engineering at the atomic level, which is one order of magnitude lower than traditional nanoengineering. Atomic engineering is a subset of atom manipulation, which includes scanning tunneling microscopy (e.g. IBM atoms and STM lithography [1] ) and optical tweezer, but the main difference lies in the fact that atomic engineering emphasizes room-temperature and ambient stability. Recently developed atom control techniques based on electron microscopy, like atom hopping [2] , atom dynamic control [3] , atomic forge [4] , cast a silver lining in realizing atomic engineering. These techniques, instead of being additive manufacturing (like 3D printing), are considered to be a part of subtractive manufacturing, where atoms are knocked out from a pristine crystal, or substitutional manufacturing, where atoms could be replaced. Therefore, atomic engineering has overlap with other concepts like defect engineering [5] , but with the additional atomic spatial precision. The essence of harnessing electron irradiation in the above mentioned techniques also relates atomic engineering with nuclear engineering [6] . The term, "Atomic Engineering", was formally used to describe the room-temperature atom manipulation in 2020 [7] .

Origin

The term "Atomic engineering" appears to have been first used in 1946 by Theodore von Kármán: [8]

"And now it seems we are at the threshold of the new atomic age. I do not know whether or not this is true, but certainly, we shall have 'atomic engineering' in the fields of power and transportation. Are we prepared for the problems involved?

The definition of Atomic Engineering has evolved into two-fold: (1) The practices of changing the atomic structure of solid-state matter to the precision of single atoms at room temperature, and (2) Exploiting atomic structure, ideally stable in air and room temperature, for science and engineering applications. [9]

An inclusive definition is: "exploiting the atomic characters of matter for engineering applications." For example, an atomic clock and potential applications of ultra-cold atom belong to atomic engineering. The atomic character could be the atomic spin (e.g. in Nuclear magnetic resonance and quantum computing applications), atomic position (e.g. Optical lattice), atomic mass (e.g. atomic power), etc. [10]

Richard Feynman, in his famous 1959 lecture "There's Plenty of Room at the Bottom" on the trend of miniaturization, envisioned:

"But I am not afraid to consider the final question as to whether, ultimately – in the great future – we can arrange the atoms the way we want; the very atoms, all the way down! What would happen if we could arrange the atoms one by one the way we want them. … When we get to the very, very, small world – say circuits of seven atoms – we have a lot of new things that would happen that represent completely new opportunities for design. Atoms on a small scale behave like nothing on a large scale, for they satisfy the laws of quantum mechanics. So, as we go down and fiddle around with the atoms down there, we are working with different laws, and we can expect to do different things. We can manufacture in different ways. We can use, not just circuits, but some system involving the quantized energy levels, or the interactions of quantized spins, etc." [11]

Most practices of nanotechnology and materials science today have foci distinct from Feynman's ultimate vision of manipulating individual atomic position and spin, which may be better described by "Atomic engineering", that addresses characteristic length scales from 1 femtometer (the atomic nucleus size) to 1 nanometer (about 5 atoms across in linear dimension). Coherent quantum control of individual atomic defect like the Nitrogen-vacancy center, and the eventual "3D atom printing" ("2D atom printing" was realized in 1990 by IBM [12] using a scanning tunneling microscope), fit Feynman's ultimate vision [13] . Recent demonstration of atomic level manipulation using STM of hydrogen on silicon surface leads to atomic lithography [14] .

Electron microscope has been discovered to an alternative for modifying the atomic structure of crystals. Electron irradiation damage (see Radiation Damage) has been a disadvantage of electron-microscope-based characterization, but when harnessed in a controllable fashion, could be used for modifying atomic structure in atomic precision [15] .

Sergei V. Kalinin proposed Atom Forge, where electron beam is used to manipulate individual atom and build atomic structures [16] [17] [18] . Cong Su et al. from MIT has used electron irradiation to affect single-atom momentum after collision on 2D materials and control the configuration of individual point defects in real time. [19]

In 2019, Department of Energy (DOE) initiate Atomically Precise Manufacturing (APM) program which recognize the importance of atomic control for room-temperature applications [20] .

Related Research Articles

In condensed matter physics and materials science, an amorphous solid is a solid that lacks the long-range order that is characteristic of a crystal. The terms "glass" and "glassy solid" are sometimes used synonymously with amorphous solid; however, these terms refer specifically to amorphous materials that undergo a glass transition. Examples of amorphous solids include glasses, metallic glasses, and certain types of plastics and polymers.

<span class="mw-page-title-main">Nanotechnology</span> Field of science involving control of matter on atomic and (supra)molecular scales

Nanotechnology was defined by the National Nanotechnology Initiative as the manipulation of matter with at least one dimension sized from 1 to 100 nanometers (nm). At this scale, commonly known as the nanoscale, surface area and quantum mechanical effects become important in describing properties of matter. The definition of nanotechnology is inclusive of all types of research and technologies that deal with these special properties. It is therefore common to see the plural form "nanotechnologies" as well as "nanoscale technologies" to refer to the broad range of research and applications whose common trait is size. An earlier description of nanotechnology referred to the particular technological goal of precisely manipulating atoms and molecules for fabrication of macroscale products, also now referred to as molecular nanotechnology.

<span class="mw-page-title-main">There's Plenty of Room at the Bottom</span> 1959 lecture by Richard Feynman

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<span class="mw-page-title-main">Atomic force microscopy</span> Type of microscopy

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<span class="mw-page-title-main">Thermal scanning probe lithography</span>

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<span class="mw-page-title-main">Sergei V. Kalinin</span>

Sergei V. Kalinin is a corporate fellow at the Center for Nanophase Materials Sciences (CNMS) at Oak Ridge National Laboratory (ORNL). He is also the Weston Fulton Professor at the Department of Materials Science and Engineering at the University of Tennessee-Knoxville.

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