Cleaning agent

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Using a mix of acidic vinegar and soap to clean a plastic surface Vacuum Clean.jpg
Using a mix of acidic vinegar and soap to clean a plastic surface

Cleaning agents or hard-surface cleaners are substances (usually liquids, powders, sprays, or granules) used to remove dirt, including dust, stains, foul odors, and clutter on surfaces. [1] Purposes of cleaning agents include health, beauty, removing offensive odor, and avoiding the spread of dirt and contaminants to oneself and others. Some cleaning agents can kill bacteria (e.g. door handle bacteria, as well as bacteria on worktops and other metallic surfaces) and clean at the same time. Others, called degreasers, contain organic solvents to help dissolve oils and fats. [2]

Contents

Chemical agents

Acidic

Acidic cleaning agents are mainly used for removal of deposits like scaling. The active ingredients are normally strong mineral acids and chelants. Often, surfactants and corrosion inhibitors are added to the acid.

Hydrochloric acid is a common mineral acid typically used for concrete. Vinegar can also be used to clean hard surfaces and remove calcium deposits. Sulphuric acid is used in acidic drain cleaners to unblock clogged pipes by dissolving organic materials, like greases, proteins, and even carbohydrate-containing substances such as toilet tissue.

Alkaline

Alkaline cleaning agents contain strong bases like sodium hydroxide or potassium hydroxide. Bleach (pH 12) and ammonia (pH 11) are common alkaline cleaning agents. Often, dispersants, to prevent redeposition of dissolved dirt, and chelants, to attack rust, are added to the alkaline agent.

Alkaline cleaners can dissolve fats (including grease), oils, and protein-based substances.

Neutral

Neutral washing agents are pH-neutral and based on non-ionic surfactants that disperse different types.

Scouring agents

Scouring agents are mixtures of the usual cleaning chemicals (surfactants, water softeners) as well as abrasive powders. The abrasive powder must be of a uniform particle size.

Particles are usually smaller than 0.05 mm. Pumice, calcium carbonate (limestone, chalk, dolomite), kaolinite, quartz, soapstone or talc are often used as abrasives, i.e. polishing agents.

Special bleaching powders contain compounds that release sodium hypochlorite, the classical household bleaching agent. These precursor agents include trichloroisocyanuric acid and mixtures of sodium hypochlorite ("chlorinated orthophosphate").

Examples of notable products include: Ajax, Bar Keepers Friend, Bon Ami, Comet, Vim, Zud, and others.

Purposes

Oven cleaners

Traditional oven cleaners contain sodium hydroxide (lye), solvents, and other ingredients, [3] They work best when used in a slightly warm (not hot) oven. If used in a self-cleaning oven, the lye can cause permanent damage to the oven.

Some oven cleaners are based on ingredients other than lye. These products must be used in a cold oven. Most new-style oven cleaners can be used in self-cleaning ovens.

One popular oven cleaner brand in the US is "Easy-Off", sold by Reckitt Benckiser. Popular choices in the UK include "Zep Oven Brite" and "Mr Muscle Oven Cleaner".

All-purpose cleaners

Fabuloso multipurpose cleaner and generic surface cleaners Fabuloso multipurpose cleaner.jpg
Fabuloso multipurpose cleaner and generic surface cleaners

All-purpose cleansers contain mixtures of anionic and nonionic surfactants, polymeric phosphates or other sequestering agents, solvents, hydrotropic substances, polymeric compounds, corrosion inhibitors, skin-protective agents, and sometimes perfumes and colorants. [4] Aversive agents, such as denatonium, are occasionally added to cleaning products to discourage animals and small children from consuming them.

Some cleaners contain water-soluble organic solvents like glycol ethers and fatty alcohols, which ease the removal of oil, fat and paint. Disinfectant additives include quaternary ammonium compounds, phenol derivatives, terpene alcohols (pine oil), aldehydes, and aldehyde-amine condensation products.

All-purpose cleaners are usually concentrated solutions of surfactants and water softeners, which enhance the behavior of surfactant in hard water. Typical surfactants are alkylbenzene sulfonates, an anionic detergent, and modified fatty alcohols. A typical water softener is sodium triphosphate.

All-purpose cleansers are effective with most common kinds of dirt. Their dilute solutions are neutral or weakly alkaline, and are safe for use on most surfaces.

Dishwashing agents

Manual dishwashing detergent

  • DELENEX DTR dishwasher detergent is an alkaline detergent for manual dishwashing dishwashers, with controlled foam, formulated to clean dish-ware and glassware. [5]

Automatic dishwashing detergents (ADDs)

Laundry detergents

Floor cleaners

Carpet cleaners

Toilet cleaners / hygiene / deodorant products

Toilet bowl cleaning often is aimed at removal of calcium carbonate deposits, which are attacked by acids. Powdered cleaners contain acids that come in the form of solid salts, such as sodium hydrogen sulfate. Liquid toilet bowl cleaners contain other acids, typically dilute hydrochloric, phosphoric, or formic acids. These convert the calcium carbonate into salts that are soluble in water or are easily rinsed away.

Drain cleaners

Metal cleaners

Metal cleaners are used for cleaning stainless steel sinks, faucets, metal trim, silverware, etc. These products contain abrasives (e.g., siliceous chalk, diatomaceous earth, alumina) with a particle size < 20 μm. Fatty alcohol or alkylphenol polyglycol ethers with 7-12 ethylene oxide (EO) units are used as surfactants. [4]

For ferrous metals, the cleaners contain chelating agents, abrasives, and surfactants. These agents include citric and phosphoric acids, which are nonaggressive. Surfactants are usually modified fatty alcohols. Silver cleaning is a specialty since silver is noble but tends to tarnish via formation of black silver sulfide, which is removable via silver-specific complexants such as thiourea.

Stainless steel, nickel, and chromium cleaners contain lactic, citric, or phosphoric acid. A solvent (mineral spirits) may be added.

Nonferrous metal cleaners contain ammonia, ammonium soaps (ammonium oleate, stearate) and chelating agents (ammonium citrate, oxalate).

For special type of precious metals especially those used for luxury watches and high-end jewelry, special type of cleaning agents are usually used to clean and protect them from the Elements. Some examples of these cleaners include jewelry cleaner from Weiman, [6] watch cleaning solution from HOROCD [7] & even cleaning metal plates from Holland Hallmark.

Glass cleaners

Light duty hard surface cleaners are not intended to handle heavy dirt and grease. Because these products are expected to clean without rinsing and result in a streak-free shine, they contain no salts. Typical window cleaning items consist of alcohols, either ethanol or isopropanol like Windex, and surfactants for dissolving grease. Other components include small amounts of ammonia as well as dyes and perfumes. [1]

These are composed of organic, water-miscible solvent such as isopropyl alcohol and an alkaline detergent. Some glass cleaners also contain a fine, mild abrasive. Most glass cleaners are available as sprays or liquid. They are sprayed directly onto windows, mirrors and other glass surfaces or applied on with a soft cloth and rubbed off using a soft, lint-free duster. A glass cloth ideal for the purpose and soft water to which some methylated spirit or vinegar is added which is an inexpensive glass cleaner.

Silverware can be freed of silver sulfide tarnish with thiourea, and either hydrochloric or sulfuric acid.

Building facade cleaners

For acid-resistant building facades, such as brick, acids are typically used. These include mixtures of phosphoric and hydrofluoric acids as well as surfactants. For acid-sensitive facades such as concrete, strongly alkaline cleaners are used such as sodium hydroxide and thickeners. Both types of cleaners require a rinsing and often special care since the solutions are aggressive toward skin.

Environmental impacts

Common cleaning agents

See also

Related Research Articles

<span class="mw-page-title-main">Sodium hydroxide</span> Chemical compound with formula NaOH

Sodium hydroxide, also known as lye and caustic soda, is an inorganic compound with the formula NaOH. It is a white solid ionic compound consisting of sodium cations Na+ and hydroxide anions OH−.

<span class="mw-page-title-main">Detergent</span> Surfactants with cleansing properties

A detergent is a surfactant or a mixture of surfactants with cleansing properties when in dilute solutions. There are a large variety of detergents, a common family being the alkylbenzene sulfonates, which are soap-like compounds that are more soluble in hard water, because the polar sulfonate is less likely than the polar carboxylate to bind to calcium and other ions found in hard water.

<span class="mw-page-title-main">Surfactant</span> Substance that lowers the surface tension between a liquid and another material

Surfactants are chemical compounds that decrease the surface tension or interfacial tension between two liquids, a liquid and a gas, or a liquid and a solid. The word "surfactant" is a blend of surface-active agent, coined c. 1950. As they consist of a water-repellent and a water-attracting part, they enable water and oil to mix; they can form foam and facilitate the detachment of dirt.

<span class="mw-page-title-main">Base (chemistry)</span> Type of chemical substance

In chemistry, there are three definitions in common use of the word "base": Arrhenius bases, Brønsted bases, and Lewis bases. All definitions agree that bases are substances that react with acids, as originally proposed by G.-F. Rouelle in the mid-18th century.

<span class="mw-page-title-main">Sodium carbonate</span> Chemical compound

Sodium carbonate is the inorganic compound with the formula Na2CO3 and its various hydrates. All forms are white, odourless, water-soluble salts that yield alkaline solutions in water. Historically, it was extracted from the ashes of plants grown in sodium-rich soils, and because the ashes of these sodium-rich plants were noticeably different from ashes of wood, sodium carbonate became known as "soda ash". It is produced in large quantities from sodium chloride and limestone by the Solvay process, as well as by carbonating sodium hydroxide which is made using the Chlor-alkali process.

<span class="mw-page-title-main">Sodium hypochlorite</span> Chemical compound (known in solution as bleach)

Sodium hypochlorite is an alkaline inorganic chemical compound with the formula NaOCl. It is commonly known in a dilute aqueous solution as bleach or chlorine bleach. It is the sodium salt of hypochlorous acid, consisting of sodium cations and hypochlorite anions.

<span class="mw-page-title-main">Trisodium phosphate</span> Chemical compound

Trisodium phosphate (TSP) is an inorganic compound with the chemical formula Na3PO4. It is a white, granular or crystalline solid, highly soluble in water, producing an alkaline solution. TSP is used as a cleaning agent, builder, lubricant, food additive, stain remover, and degreaser.

Ammonia solution, also known as ammonia water, ammonium hydroxide, ammoniacal liquor, ammonia liquor, aqua ammonia, aqueous ammonia, or (inaccurately) ammonia, is a solution of ammonia in water. It can be denoted by the symbols NH3(aq). Although the name ammonium hydroxide suggests a salt with the composition [NH+
4][OH−
], it is actually impossible to isolate samples of NH4OH. The ions NH+
4 and OH− do not account for a significant fraction of the total amount of ammonia except in extremely dilute solutions.

<span class="mw-page-title-main">Paint stripper</span> Chemical product that removes paint, finishes, and coatings

Paint stripper or paint remover is a chemical product designed to remove paint, finishes, and coatings, while also cleaning the underlying surface.

<span class="mw-page-title-main">Glass Plus</span>

Glass Plus is a glass and multi-surface cleaner.

<span class="mw-page-title-main">Sulfamic acid</span> Chemical compound

Sulfamic acid, also known as amidosulfonic acid, amidosulfuric acid, aminosulfonic acid, sulphamic acid and sulfamidic acid, is a molecular compound with the formula H3NSO3. This colourless, water-soluble compound finds many applications. Sulfamic acid melts at 205 °C before decomposing at higher temperatures to water, sulfur trioxide, sulfur dioxide and nitrogen.

<span class="mw-page-title-main">Household chemicals</span>

Household chemicals are non-food chemicals that are commonly found and used in and around the average household. They are a type of consumer goods, designed particularly to assist cleaning, house and yard maintenance, cooking, pest control and general hygiene purposes often stored in the kitchen or garage.

<span class="mw-page-title-main">Laundry detergent</span> Type of detergent used for cleaning laundry

Laundry detergent is a type of detergent used for cleaning dirty laundry (clothes). Laundry detergent is manufactured in powder and liquid form.

<span class="mw-page-title-main">Carpet cleaning</span> Process of removing dirt and stains from carpets

Carpet cleaning is performed to remove stains, dirt, and allergens from carpets. Common methods include hot water extraction, dry-cleaning, and vacuuming.

<span class="mw-page-title-main">Bleach</span> Chemicals used to whiten or disinfect

Bleach is the generic name for any chemical product that is used industrially or domestically to remove colour (whitening) from fabric or fiber or to disinfect after cleaning. It often refers specifically to a dilute solution of sodium hypochlorite, also called "liquid bleach".

Stain removal is the process of removing a mark or spot left by one substance on a specific surface like a fabric. A solvent or detergent is generally used to conduct stain removal and many of these are available over the counter.

<span class="mw-page-title-main">Dishwasher detergent</span> Type of detergent specifically used to wash dishes in a dishwasher

Dishwasher detergent is a detergent made for washing dishes in a dishwasher. Dishwasher detergent is different from dishwashing liquid made to wash dishes by hand.

Scouring powder is a household cleaning product consisting of an abrasive powder mixed with a dry soap or detergent, soda, and possibly dry bleach.

<span class="mw-page-title-main">Fabric treatment</span>

Fabric treatments are processes that make fabric softer, or water resistant, or enhance dye penetration after they are woven. Fabric treatments get applied when the textile itself cannot add other properties. Treatments include, scrim, foam lamination, fabric protector or stain repellent, anti microbial and flame retardant.

References

  1. 1 2 Christian Nitsch; Hans-Joachim Heitland; Horst Marsen; Hans-Joachim Schlüussler (2005). "Cleansing Agents". Ullmann's Encyclopedia of Industrial Chemistry . Weinheim: Wiley-VCH. doi:10.1002/14356007.a07_137. ISBN   978-3527306732.
  2. ↑ Wisniewski, Karen (2007). "All-Purpose Cleaners and their Formulation". In Tsoler, Uri (ed.). Handbook of detergents, Part 2. Surfactant science series. CRC Press. ISBN   978-1-57444-757-6.
  3. ↑ https://www.mountsinai.org/health-library/poison/oven-cleaner-poisoning Oven cleaner poisoning, The Mount Sinai Health System, retrieved April 18th, 2021
  4. 1 2 Christian Nitsch; Hans-Joachim Heitland; Horst Marsen; Hans-Joachim Schlüssler (2007), "Cleansing Agents", Ullmann's Encyclopedia of Industrial Chemistry (7th ed.), Wiley
  5. ↑ "Dishwashing Detergent". at Azoss.
  6. ↑ Chan, Tim (13 May 2020). "After Washing Your Hands, Here's How to Clean and Disinfect Your Watches and Jewelry". Rolling Stone.
  7. ↑ DEBBY KWONG, HAYDEN NG. "How to take care of your watches and jewellery". Her World Singapore. Her World Singapore.
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