Organic electronics is a field of materials science concerning the design, synthesis, characterization, and application of organic molecules or polymers that show desirable electronic properties such as conductivity. Unlike conventional inorganic conductors and semiconductors, organic electronic materials are constructed from organic (carbon-based) molecules or polymers using synthetic strategies developed in the context of organic chemistry and polymer chemistry.
Pentacene is a polycyclic aromatic hydrocarbon consisting of five linearly-fused benzene rings. This highly conjugated compound is an organic semiconductor. The compound generates excitons upon absorption of ultra-violet (UV) or visible light; this makes it very sensitive to oxidation. For this reason, this compound, which is a purple powder, slowly degrades upon exposure to air and light.
Hybrid solar cells combine advantages of both organic and inorganic semiconductors. Hybrid photovoltaics have organic materials that consist of conjugated polymers that absorb light as the donor and transport holes. Inorganic materials in hybrid cells are used as the acceptor and electron transporter in the structure. The hybrid photovoltaic devices have a potential for not only low-cost by roll-to-roll processing but also for scalable solar power conversion.
The Staebler–Wronski Effect (SWE) refers to light-induced metastable changes in the properties of hydrogenated amorphous silicon.
Organic photovoltaic devices (OPVs) are fabricated from thin films of organic semiconductors, such as polymers and small-molecule compounds, and are typically on the order of 100 nm thick. Because polymer based OPVs can be made using a coating process such as spin coating or inkjet printing, they are an attractive option for inexpensively covering large areas as well as flexible plastic surfaces. A promising low cost alternative to conventional solar cells made of crystalline silicon, there is a large amount of research being dedicated throughout industry and academia towards developing OPVs and increasing their power conversion efficiency.
An organic solar cell (OSC) or plastic solar cell is a type of photovoltaic that uses organic electronics, a branch of electronics that deals with conductive organic polymers or small organic molecules, for light absorption and charge transport to produce electricity from sunlight by the photovoltaic effect. Most organic photovoltaic cells are polymer solar cells.
There are currently many research groups active in the field of photovoltaics in universities and research institutions around the world. This research can be categorized into three areas: making current technology solar cells cheaper and/or more efficient to effectively compete with other energy sources; developing new technologies based on new solar cell architectural designs; and developing new materials to serve as more efficient energy converters from light energy into electric current or light absorbers and charge carriers.
Donal Donat Conor Bradley is the Vice President for Research at King Abdullah University of Science and Technology (KAUST), Saudi Arabia. From 2015 until 2019, he was head of the Mathematical, Physical and Life Sciences Division of the University of Oxford and a Professor of Engineering Science and Physics at Jesus College, Oxford. From 2006 to 2015, he was the Lee-Lucas Professor of Experimental Physics at Imperial College London. He was the founding director of the Centre for Plastic Electronics and served as vice-provost for research at the college.
A perovskite solar cell (PSC) is a type of solar cell that includes a perovskite-structured compound, most commonly a hybrid organic–inorganic lead or tin halide-based material as the light-harvesting active layer. Perovskite materials, such as methylammonium lead halides and all-inorganic cesium lead halide, are cheap to produce and simple to manufacture.
Polymer-fullerene bulk heterojunction solar cells are a type of solar cell researched in academic laboratories. Polymer-fullerene solar cells are a subset of organic solar cells, also known as organic photovoltaic (OPV) cells, which use organic materials as their active component to convert solar radiation into electrical energy. The polymer, which functions as the donor material in these solar cells, and fullerene derivatives, which function as the acceptor material, are essential components. Specifically, fullerene derivatives act as electron acceptors for donor materials like P3HT, creating a polymer-fullerene based photovoltaic cell. The Polymer-fullerene BHJ forms two channels for transferring electrons and holes to the corresponding electrodes, as opposed to the planar architecture when the Acceptor (A) and Donor (D) materials were sequentially stacked on top of each other and could selectively touch the cathode and anode electrodes. Hence, the D and A domains are expected to form a bi-continuous network with Nano-scale morphology for efficient charge transport and collection after exciton dissociation. Therefore, in the BHJ device architecture, a mixture of D and A molecules in the same or different solvents was used to form a bi-continual layer, which serves as the active layer of the device that absorbs light for exciton generation. The bi-continuous three-dimensional interpenetrating network of the BHJ design generates a greater D-A interface, which is necessary for effective exciton dissociation in the BHJ due to short exciton diffusion. When compared to the prior bilayer design, photo-generated excitons may dissociate into free holes and electrons more effectively, resulting in better charge separation for improved performance of the cell.
Henry James Snaith is a professor in physics in the Clarendon Laboratory at the University of Oxford. Research from his group has led to the creation of a new research field, based on halide perovskites for use as solar absorbers. Many individuals who were PhD students and postdoctoral researchers in Snaith's group have now established research groups, independent research portfolios and commercial enterprises. He co-founded Oxford Photovoltaics in 2010 to commercialise perovskite based tandem solar cells.
Konstantinos Fostiropoulos is a Greek physicist who has been working in Germany in the areas nano-materials, solid-state physics, molecular physics, astrophysics, and thermodynamics. From 2003 to 2016 he has been founder and head of the Organic Solar Cells Group at the Institute Heterogeneous Materials Systems within the Helmholtz-Zentrum Berlin. His scientific works include novel energy materials and photovoltaic device concepts, carbon clusters in the Interstellar Medium, and intermolecular forces of real gases.
James Robert DurrantFRSC FLSW is a British photochemist. He is a professor of photochemistry at Imperial College London and Sêr Cymru Solar Professor at Swansea University. He serves as director of the centre for plastic electronics (CPE).
In organic chemistry, contorted aromatics, or more precisely contorted polycyclic aromatic hydrocarbons, are polycyclic aromatic hydrocarbons (PAHs) in which the fused aromatic molecules deviate from the usual planarity.
Natalie Stingelin, Fellow of the Materials Research Society and Royal Society of Chemistry, is a materials scientist and current chair of the School of Materials Science and Engineering at the Georgia Institute of Technology, the University of Bordeaux and Imperial College. She led the European Commission Marie Curie INFORM network and is Editor-in-Chief of the Journal of Materials Chemistry C and Materials Advances.
Light harvesting materials harvest solar energy that can then be converted into chemical energy through photochemical processes. Synthetic light harvesting materials are inspired by photosynthetic biological systems such as light harvesting complexes and pigments that are present in plants and some photosynthetic bacteria. The dynamic and efficient antenna complexes that are present in photosynthetic organisms has inspired the design of synthetic light harvesting materials that mimic light harvesting machinery in biological systems. Examples of synthetic light harvesting materials are dendrimers, porphyrin arrays and assemblies, organic gels, biosynthetic and synthetic peptides, organic-inorganic hybrid materials, and semiconductor materials. Synthetic and biosynthetic light harvesting materials have applications in photovoltaics, photocatalysis, and photopolymerization.
Samson Ally Jenekhe is the Boeing-Martin Professor of Chemical Engineering and Professor of Chemistry at the University of Washington. Jenekhe was previously a chemical engineer at the University of Rochester where his work focused on semiconducting polymers and quantum wires. He has authored over 300 research articles and 28 patents.
Sandrine Elizabeth Monique Heutz is a Professor of Functional Molecular Materials at Imperial College London. She works on organic and magnetically coupled molecular materials for spintronic applications. In 2008 Heutz was awarded the Institute of Materials, Minerals and Mining Silver Medal.
Giulia Grancini is an Italian physicist who is a Professor of Chemistry at the University of Pavia. Her work considers new materials for photovoltaic devices, including perovskites and polymer-based materials. In 2020, Grancini was named the Royal Society of Chemistry Journal of Materials Chemistry Lecturer.
Ellen Moons is a Belgian materials scientist who is a professor at Karlstad University. Her research considers the organisation of molecules and materials in thin films. She is mainly interested in organic and hybrid materials for solution processed photovoltaics.
