Phosphate phosphite

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A phosphate phosphite is a chemical compound or salt that contains phosphate and phosphite anions (PO33- and PO43-). These are mixed anion compounds or mixed valence compounds. Some have third anions.

Contents

Phosphate phosphites frequently occur as metal organic framework (MOF) compounds which are of research interest for gas storage, detection or catalysis. In these phosphate and phosphite form bridging ligands to hard metal ions. Protonated amines are templates. [1]

Naming

An phosphate phosphite compound may also be called a phosphite phosphate.

Production

Phosphate phosphite compounds are frequently produced by hydrothermal synthesis, in which a water solution of ingredients is enclosed in a sealed container and heated. Phosphate may be reduced to phosphite or phosphite oxidised to phosphate in this process.

Properties

On heating,

Related to these are the nitrite nitrates and arsenate arsenites.

List

nameformularatio

PO4:PO3

 mw system space group unit cell Åvolumedensitypropertiesreferences
1,4-diammoniumbutane[(H3N(CH2)4NH3)2][Sc5F4(HPO3)6(H2PO3)2(PO4)]1:81300.8monoclinicC2/ma=12.888 b=14.835 c=10.531 β=103.093 Z=2 @93K1961.2 [2]
imidazole[C3N2H5]2[VIII4(H2O)3(HPO3)4(HPO4)3]3:41003.766trigonalP3c1a=13.499 c=18.120 Z=122280.352.143green [3]
(C3H10NO)6[V8(H2O)6(PO4)2(HPO3)12]2:12P3c1a=13.5393 c=18.22832893.8green [4]
(C4H8N2)3[V8(H2O)6(PO4)2(HPO3)12]2:12P3c1a=13.4922 c=18.35892894.3green [4]
Mn5(μ-OH2)2(PO4)2(HPO3)2·2H2O2:2 [5]
Iron(III) 2,2'-bipyridine Phosphite−Phosphate[FeIII(2,2'-bipyridine)(HPO3)(H2PO4)]1:1monoclinica=10.5407 b=6.4298 c=10.6172 β=113.890 Z=21.878colourless [6]
FeIII(1,10-phenanthroline)(HPO3)(H2PO3)1:1monoclinicP21/ma = 10.180, b = 6.424, c = 11.6668, β = 115.59°, Z = 4,668.21.880yellow [7]
{[C3H4N2]2[C5NH5]14[H15(Mo2O4)8Co16(PO4)14(HPO3)10(OH)3]}·5H2O14:106685.09monoclinicC2/ma=29.724 b=24.623 c=20.687 β=126.760 Z=2121301.830red [8]
tris (4-pyridyl) triazine zinc phosphate–phosphiteC54 H60 N18 O42 P10 Zn9?2531.23hexagonalP63a=15.6464 c=19.788 Z=24195.2yellow [9]
1-(2-Aminoethyl) piperazine tetrazinc diphosphate diphosphite(C6H17N3)[Zn4(PO4)2(HPO3)2]2:2monoclinicCca=5.327, b=17.146, c=22.071, β=94.58°, Z=42009.5 [10]
Zinc Phosphate-phosphite (trans-C6H15N2)2Zn4(PO4)2(HPO3)2(C6H15N2)2Zn4(PO4)2(HPO3)22:2841.78monoclinicP21/na=9.706 b=9.993 c=27.557 β=96.795 Z=42654.02.107 [11]
1,3-cyclohexanebis(methylamine);[H2CHBMA][Zn1.5Mn(HPO3)2.5(PO4)]•5H2O1:5monoclinicC2/ca=33.929, b=13.045, c=8.971, β=104.37°, Z=23846.5 [12]
2-hydroxypropylammonium dizinc hydrogenphosphite phosphate[C3H6(OH)NH3][Zn2(HPO3)(PO4)]1:1triclinicP1a =5.302 b =8.934 c =12.686, α =74.35° β =88.54° γ =73.94° [13]
TJPU-3Mn

(bis(Cyclohexane-1,3-bis(methylammonium)) bis(μ4-phosphato)-tetrakis(μ3-hydrogen phosphito)-manganese-tetra-zinc dihydrate)

[H2CHBMA][Zn2Mn0.5(PO4)(HPO3)2]·H2O1:2monoclinicC2/ca = 33.929, b = 13.045, c = 8.971, β = 104.37°, Z = 43846 [14]
triethylenetetramine[C6N4H22]0.5[Zn3(PO4)2(HPO3)]2:1 [15]
zinc potassium phosphitephosphate [16]
N,N,N′,N′-tetramethylenediamine (TMEDA)(C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O14:6P3a = 19.046, c = 8.331, Z = 12617.1 [17]
Zirconium phosphate phosphiteγ-ZrPO4·HPO2(OH)·2H2O1:1layered [18]
phen = 1,10-phenanthrolineCd2(phen)2(H2PO4)(H2PO3)(C2O4)1:1chains [19]
catena-(tris(hexane-1,6-diaminium) octakis(μ3-phosphonato)-hexakis(μ3-phosphato)-tris(μ2-hydrogen phosphato)-hexa-aqua-nona-indium[In9(H2O)6(HPO3)13(H2PO3)2(PO4)(HPO4)][(C6N2H18)3]2:15hexagonalP63/ma=13.7676 c=28.062 [20]
4-bipyridine(C10H10N2)1.5(H3O)3[In18(H2O)12(HPO4)12(HPO3)16(H2PO3)6]12:16hexagonalP63/ma = 13.784, c = 28.0584617 [21]
catena-(bis(propane-1,3-diammonium) octakis(μ3-phosphito)-pentakis(μ2-hydrogen phosphito)-(μ2-dihydrogen phosphato)-hexa-indium)[In6(HPO3)8(H2PO3)5(H2PO4)]·(C3N2H12)21:11orthorhombicPna21a = 26.7974, b = 9.8459, c = 18.5441, Z = 44892.8 [22]
Pb2Al(HPO3)3(H2PO4)1:3orthorhombicCmcm [23]
Pb2Ga(HPO3)3(H2PO4)1:3orthorhombicCmcm
Pb2Al(HPO3)2(HPO4)(H2PO4)2:2orthorhombicCmcm
Rubidium Uranium(VI/IV) Phosphate-PhosphiteRb2[(UO2)2(UIV)(PO4)2(HPO3)2(H2O)]2:21316.94monoclinicC2/ca=16.2421 b=10.5049 c=11.0936 β=98.7451870.84.702orange-yellow [24]
Cesium Uranium(IV) Phosphate-PhosphiteCs2[UIV3(PO4)2(HPO3)4]2:41489.76monoclinicC2/ma=25.7396 b=5.5906 c=7.6334 β=98.964 Z=21085.034.560blue-green [24]
Cesium Uranium(VI/IV) Phosphate-PhosphiteCs2[(UO2)(UIV)(HPO4)2(HPO3)2]2:21123.78triclinicP1a=6.8571 b=11.1190 c=12.0391 alpha=63.861 beta=77.481 gamma=79.331 Z=2800.224.664Yellow-Orange [24]
Cs4[(UO2)8(HPO4)5(HPO3)5]·4H2O5:5monoclinicC2/ca 18.5005Å b 10.971 c 14.4752, β 104.513°yellow [25]
Cs4[UIV6(PO4)8(HPO4)(HPO3)]9:1orthorhombicPmmna 6.9321 b 26.935 c 10.9137pale green [25]
Cs10[UIV10(PO4)4(HPO4)14(HPO3)5]·H2O15:5monoclinicC2/ma 19.2966 b 20.2914 c 13.9293 β 126.839°green [25]
Tl3[(UO2)2(H1.5PO4)(H0.5PO4)(H1.5PO3)2]2:21503.07tetragonalP42/mbca=13.5382 c=19.4008 Z=83555.85.615Yellow-green [26]
Tl2[(UO2)2(UIV)(H2O)(PO4)2(HPO3)2]2:21550.71monoclinicC2/ca=16.2360 b=10.4995 c=11.0003 β=99.027 Z=41851.995.562light green [26]

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References

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  2. ↑ Miller, Stuart R. (2007-12-17). Scandium bearing open framework materials (Thesis thesis). University of St Andrews. hdl:10023/570.
  3. ↑ Ramaswamy, Padmini; Mandal, Sukhendu; Hegde, Nayana N; Prabhu, Ramanath; Banerjee, Debmalya; Bhat, S. V.; Natarajan, Srinivasan (April 2010). "Synthesis, Structure, and Magnetic Properties of Amine-Templated Transition-Metal Phosphites". European Journal of Inorganic Chemistry. 2010 (12): 1829–1838. doi:10.1002/ejic.200901206.
  4. 1 2 曉文, 鄭 (18 July 1991). "亞磷酸釩及磷酸鉬的合成,結構鑑定及性質研究". p. 28.
  5. ↑ "Mn（II）取代磷酸铝和磷酸锰微孔化合物的水热合成与表征--《吉林大学》2005年博士论文". cdmd.cnki.com.cn. Retrieved 2021-08-25.
  6. ↑ Mandal, Sukhendu; Pati, Swapan K.; Green, Mark A.; Natarajan, Srinivasan (February 2005). "The First One-Dimensional Iron Phosphite−Phosphate, [Fe III (2,2'-bipyridine)(HPO 3 )(H 2 PO 4 )]: Synthesis, Structure, and Magnetic Properties". Chemistry of Materials. 17 (3): 638–643. doi:10.1021/cm049064p. ISSN   0897-4756.
  7. ↑ Mandal, Sukhendu; Green, Mark A.; Natarajan, Srinivasan (2005-12-10). "Synthesis, structure and magnetic properties of a new one-dimensional iron phosphite, [FeIII(1,10-phenanthroline)(HPO3)(H2PO3)]" (PDF). Current Science. 89 (11): 1899–1903. ISSN   0011-3891.
  8. ↑ Miao, Hao; Wan, Hong-Xiang; Liu, Ming; Zhang, Yu; Xu, Xiao; Ju, Wei-Wei; Zhu, Dun-ru; Xu, Yan (2014). "Two novel organic–inorganic hybrid molybdenum( v ) cobalt/nickel phosphate compounds based on isolated nanosized Mo/Co(Ni)/P cluster wheels". J. Mater. Chem. C. 2 (32): 6554–6560. doi:10.1039/C4TC00944D. ISSN   2050-7526.
  9. ↑ Zhang, Jie; Yao, Zhenguo; Liao, Shijun; Dai, Jingcao; Fu, Zhiyong (2013). "A hybrid metal phosphate–phosphite material grafted with electron deficient organic components showing interesting fluorescent and photosensitive properties". Journal of Materials Chemistry A. 1 (16): 4945. doi:10.1039/c3ta10478h. ISSN   2050-7488.
  10. ↑ Chen, Xiaoxin; Wang, Yu; Yu, Jihong; Zou, Yongchun; Xu, Ruren (July 2004). "(C6H17N3)[Zn4(PO4)2(HPO3)2]: a new layered zinc phosphate–phosphite templated by 1-(2-Aminoethyl) piperazine". Journal of Solid State Chemistry. 177 (7): 2518–2522. Bibcode:2004JSSCh.177.2518C. doi:10.1016/j.jssc.2004.03.039.
  11. ↑ Wang, Yu; Yu, Jihong; Du, Yu; Shi, Zhan; Zou, Yongcun; Xu, Ruren (2002). "Hydrothermal synthesis and characterization of a new inorganic–organic hybrid layered zinc phosphate–phosphite (C 6 H 15 N 2 ) 2 Zn 4 (PO 4 ) 2 (HPO 3 ) 2". J. Chem. Soc., Dalton Trans. (21): 4060–4063. doi:10.1039/B204876K. ISSN   1472-7773.
  12. ↑ "Synthesis and Structure of Manganese Zinc Phosphate-phosphite with Extra Large Twenty-membered Ring Channels--《Chemical Journal of Chinese Universities》2007年12期". en.cnki.com.cn. Retrieved 2021-08-23.
  13. ↑ Fu, Zhiyong; Zhang, Jie; Tan, Yi; Song, Desheng; Liu, Changchun; Wu, Jiaqi (2011-11-10). "Synthesis, structure, and base-catalytic performance of a laminar zinc phosphite-phosphate". Journal of Coordination Chemistry. 64 (21): 3808–3816. doi:10.1080/00958972.2011.631533. ISSN   0095-8972. S2CID   98042559.
  14. ↑ Chen, Guangyan; Su, Hao; Yu, Jianguo; Yang, Yang; Zhao, Yongnan; Fu, Zhifeng (July 2009). "Separation of 1,3-Cyclohexanebis(methylamine) Isomers by Template Synthesis of Open-Framework Bimetallic Phosphites". Zeitschrift für anorganische und allgemeine Chemie. 635 (9–10): 1463–1469. doi: 10.1002/zaac.200801317 .
  15. ↑ Rao, C. N. R. (2003-09-12). Advances In Chemistry: A Selection Of C N R Rao's Publications (1994–2003). World Scientific. p. 478. ISBN   978-981-4485-05-0.
  16. ↑ "Studies on polymerization of zinc potassium phosphite-phosphate the non-toxic anticorrosive pigment--《JOURNAL OF SHANTOU UNIVERSITY(NATURAL SCIENCE EDITION)》1995年01期". en.cnki.com.cn. Retrieved 2021-08-24.
  17. ↑ Zhou, Guangpeng; Yang, Yulin; Fan, Ruiqing; Liu, Xinrong; Hong, Hengwu; Wang, Fuping (July 2010). "Hydrothermal synthesis and characterization of a new organically templated three-dimensional open-framework gallium phosphate–phosphite (C6N2H18)2(C6N2H17)Ga15(OH)8(PO4)2(HPO4)12(HPO3)6·2H2O". Solid State Sciences. 12 (7): 1103–1106. Bibcode:2010SSSci..12.1103Z. doi:10.1016/j.solidstatesciences.2010.04.013.
  18. ↑ Alberti, G.; Costantino, U.; Vivani, R.; Biswas, R.K. (June 1992). "Preparation and some preliminary investigations of ion exchange and intercalation properties of γ-zirconium phosphate phosphite". Reactive Polymers. 17 (3): 245–253. doi:10.1016/0923-1137(92)90271-3.
  19. ↑ Li, Jing; Li, Ting; Zeng, Hongmei; Zou, Guohong; Lin, Zhien (September 2018). "Solvent-free synthesis of inorganic-organic hybrid solids with chainlike, layered, and open-framework structures". Inorganic Chemistry Communications. 95: 8–11. doi:10.1016/j.inoche.2018.06.022. S2CID   103213780.
  20. ↑ Dong, Zhaojun; Yan, Yan; Li, Yi; Li, Jiyang; Yu, Jihong; Xu, Ruren (May 2011). "A new open-framework indium phosphate–phosphite containing intersecting extra-large 16-ring channels". Inorganic Chemistry Communications. 14 (5): 727–730. doi:10.1016/j.inoche.2011.02.019.
  21. ↑ Li, Hui Duan (June 2014). "Construction of a Novel 3D Indium Phosphate–Phosphite with Extra-Large 16-MRs Channels: Synthesis, Structure and Fluorescence Property". Advanced Materials Research. 936: 901–904. doi:10.4028/www.scientific.net/AMR.936.901. ISSN   1662-8985. S2CID   94181154.
  22. ↑ Huang, Liangliang; Song, Tianyou; Fan, Yong; Yang, Lei; Wang, Liping; Zhang, Hua; Wang, Li; Xu, Jianing (August 2010). "Hydrothermal syntheses, characterizations of novel three-dimensional indium phosphite and indium phosphite–phosphate with intersecting 8-membered ring channels: [In3(H2PO3)3(HPO3)4]·(trans-C6N2H16) and [In6(HPO3)8(H2PO3)5(H2PO4)]·(C3N2H12)2". Microporous and Mesoporous Materials. 132 (3): 409–413. doi:10.1016/j.micromeso.2010.03.020.
  23. ↑ 李, 天予 (2020-07-17). "含鉛離子和三價金屬陽離子之混亞磷酸 -磷酸鹽化合物合成及結構和性質探討".
  24. 1 2 3 Villa, Eric M.; Marr, Connor J.; Jouffret, Laurent J.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2012-06-18). "Systematic Evolution from Uranyl(VI) Phosphites to Uranium(IV) Phosphates". Inorganic Chemistry. 51 (12): 6548–6558. doi:10.1021/ic3000735. ISSN   0020-1669. PMID   22646238.
  25. 1 2 3 Villa, Eric M.; Marr, Connor J.; Diwu, Juan; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-01-18). "From Order to Disorder and Back Again: In Situ Hydrothermal Redox Reactions of Uranium Phosphites and Phosphates". Inorganic Chemistry. 52 (2): 965–973. doi:10.1021/ic302198w. ISSN   0020-1669. PMID   23301654.
  26. 1 2 Villa, Eric M.; Alekseev, Evgeny V.; Depmeier, Wulf; Albrecht-Schmitt, Thomas E. (2013-04-03). "Syntheses, Structures, and Comparisons of Thallium Uranium Phosphites, Mixed Phosphate-Phosphites, and Phosphate". Crystal Growth & Design. 13 (4): 1721–1729. doi:10.1021/cg400046a. ISSN   1528-7483.
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