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A monopropellant rocket (or "monochemical rocket") is a rocket that uses a single chemical as its propellant. [1] Monopropellant rockets are commonly used as small attitude and trajectory control rockets in satellites, rocket upper stages, manned spacecraft, and spaceplanes. [2]
The simplest monopropellant rockets depend on the chemical decomposition of a storable propellant after passing it over a catalyst bed. [3] The power for the thruster comes from the high pressure gas created during the decomposition reaction that allows a rocket nozzle to speed up the gas to create thrust.
The most commonly used monopropellant is hydrazine (N2H4, or H2N−NH2), a compound unstable in the presence of a catalyst and which is also a strong reducing agent. The most common catalyst is granular alumina (aluminum oxide, Al2O3) coated with iridium. These coated granules are usually under the commercial labels Aerojet S-405 (previously made by Shell) [4] or W.C. Heraeus H-KC 12 GA (previously made by Kali Chemie). [5] There is no igniter with hydrazine. Aerojet S-405 is a spontaneous catalyst, that is, hydrazine decomposes on contact with the catalyst. The decomposition is highly exothermic and produces a 1,000 °C (1,830 °F) gas that is a mixture of nitrogen, hydrogen and ammonia. The main limiting factor of the monopropellant rocket is its life, which mainly depends on the life of the catalyst. The catalyst may be subject to catalytic poisoning and catalytic attrition which results in the catalyst failure. Another monopropellant is hydrogen peroxide, which, when purified to 90% or higher concentration, is self-decomposing at high temperatures or when a catalyst is present.
Most chemical-reaction monopropellant rocket systems consist of a fuel tank, usually a titanium or aluminium sphere, with an ethylene-propylene rubber container or a surface tension propellant management device filled with the fuel. The tank is then pressurized with helium or nitrogen, which pushes the fuel out to the motors. A pipe leads from the tank to a poppet valve, and then to the decomposition chamber of the rocket motor. Typically, a satellite will have not just one motor, but two to twelve, each with its own valve.
The attitude control rocket motors for satellites and space probes are often very small, 25 mm (0.98 in) or so in diameter, and mounted in groups that point in four directions (within a plane).
The rocket is fired when the computer sends direct current through a small electromagnet that opens the poppet valve. The firing is often very brief, a few milliseconds, and — if operated in air — would sound like a pebble thrown against a metal trash can; if on for long, it would make a piercing hiss.
Chemical-reaction monopropellants are not as efficient as some other propulsion technologies. Engineers choose monopropellant systems when the need for simplicity and reliability outweigh the need for high delivered impulse. If the propulsion system must produce large amounts of thrust, or have a high specific impulse, as on the main motor of an interplanetary spacecraft, other technologies are used.
A concept to provide low Earth orbit (LEO) propellant depots that could be used as way-stations for other spacecraft to stop and refuel on the way to beyond-LEO missions has proposed that waste gaseous hydrogen—an inevitable byproduct of long-term liquid hydrogen storage in the radiative heat environment of space—would be usable as a monopropellant in a solar-thermal propulsion system. The waste hydrogen would be productively utilized for both orbital station-keeping and attitude control, as well as providing limited propellant and thrust to use for orbital maneuvers to better rendezvous with other spacecraft that would be inbound to receive fuel from the depot. [6]
Solar-thermal monopropellant thrusters are also integral to the design of a next-generation cryogenic upper stage rocket proposed by U.S. company United Launch Alliance (ULA). The Advanced Common Evolved Stage (ACES) is intended as a lower-cost, more-capable and more-flexible upper stage that would supplement, and perhaps replace, the existing ULA Centaur and ULA Delta Cryogenic Second Stage (DCSS) upper stage vehicles. The ACES Integrated Vehicle Fluids option eliminates all hydrazine and helium from the space vehicle—normally used for attitude control and station keeping—and depends instead on solar-thermal monopropellant thrusters using waste hydrogen. [7]
Soviet designers had begun experimenting with monopropellant rockets as early as 1933. [8] They believed their monopropellant mixes of nitrogen tetroxide with gasoline, or toluene, and kerosene would lead to an overall simpler system; however, they ran into problems with violent explosions with pre-mixed fuel and oxidizer serving as a monopropellant that led the designers to abandon this approach. [8]
Helmuth Walter was a German engineer an early pioneer of monopropellant rockets using hydrogen peroxide as fuel. [9] Although his initial work was on submarine propulsion the same jets of oxygen produced by for combustion in gas turbines could be directed through a nozzle to generate thrust. [9] The rocket Walter developed was used in the German ME-163 fighter aircraft in 1944, the first aircraft to break the 1000 km/h (635 mph). [9]
After World War Two the British would continue to experiment with hydrogen peroxide monopropellants. [9] They would develop the de Havilland Sprite a hydrogen peroxide rocket that could produce 5000lbf of thrust over 16 seconds. Not intended for space flight the rocket would provide hot and high takeoff capability to the de Havilland Comet 1 the first commercial jet airliner. [9]
In the United States, when NASA began studying monopropellants at the Jet Propulsion Laboratory (JPL) the properties of the existing propellants demanded that the thrusters be impractically large. [10] The addition of a catalyst and pre-heating propellant made them more efficient, but raised concerns over safety and handling of hazardous propellants like anhydrous hydrazine. [10] However the simplicity of the thrusters designed around early monopropellants offered many simplicities and were first tested in 1959 on the Able-4 mission. [11] This test allowed for the Ranger and Mariner missions to use a similar thruster for correction maneuvers [11] and in the orbital insertion of Telstar, considered by the National Air and Space Museum to be the most significant communications satellite in the beginning of the space race. [12]
In 1964, NASA began use of the Lunar Landing Research Vehicle to train Apollo astronauts in piloting the Lunar Excursion Module (LEM) using an attitude control system consisting of 16 hydrogen peroxide monopropellant thrusters to steer the LEM to the lunar surface. [13]
Upper stage vehicles began using monopropellant thrusters as a convenient control device in the early 1960s when General Dynamics proposed the Centaur upper stage to the United States Airforce [14] of which versions are still in use in United Launch Alliance's Atlas and Vulcan rockets. [15]
NASA is developing a new monopropellant propulsion system for small, cost-driven spacecraft with delta-v requirements in the range of 10–150 m/s. This system is based on a hydroxylammonium nitrate (HAN)/water/fuel monopropellant blend which is extremely dense, environmentally benign, and promises good performance and simplicity. [16]
The EURENCO Bofors company produced LMP-103S as a 1-to-1 substitute for hydrazine by dissolving 65% ammonium dinitramide, NH4N(NO2)2, in 35% water solution of methanol and ammonia. LMP-103S has 6% higher specific impulse and 30% higher impulse density than hydrazine monopropellant. Additionally, hydrazine is highly toxic and carcinogenic, while LMP-103S is only moderately toxic. LMP-103S is UN Class 1.4S allowing for transport on commercial aircraft, and was demonstrated on the Prisma satellite in 2010. Special handling is not required. LMP-103S could replace hydrazine as the most commonly used monopropellant. [17] [18]
Spacecraft propulsion is any method used to accelerate spacecraft and artificial satellites. In-space propulsion exclusively deals with propulsion systems used in the vacuum of space and should not be confused with space launch or atmospheric entry.
A resistojet is a method of spacecraft propulsion that provides thrust by heating a typically non-reactive fluid. Heating is usually achieved by sending electricity through a resistor consisting of a hot incandescent filament, with the expanded gas expelled through a conventional nozzle.
An arcjet rocket or arcjet thruster is a form of electrically powered spacecraft propulsion, in which an electrical discharge (arc) is created in a flow of propellant. This imparts additional energy to the propellant, so that one can extract more work out of each kilogram of propellant, at the expense of increased power consumption and (usually) higher cost. Also, the thrust levels available from typically used arcjet engines are very low compared with chemical engines.
A hypergolic propellant is a rocket propellant combination used in a rocket engine, whose components spontaneously ignite when they come into contact with each other.
The Centaur is a family of rocket propelled upper stages that has been in use since 1962. It is currently produced by U.S. launch service provider United Launch Alliance, with one main active version and one version under development. The 3.05 m (10.0 ft) diameter Common Centaur/Centaur III flies as the upper stage of the Atlas V launch vehicle, and the 5.4 m (18 ft) diameter Centaur V has been developed as the upper stage of ULA's new Vulcan rocket. Centaur was the first rocket stage to use liquid hydrogen (LH2) and liquid oxygen (LOX) propellants, a high-energy combination that is ideal for upper stages but has significant handling difficulties.
Monopropellants are propellants consisting of chemicals that release energy through exothermic chemical decomposition. The molecular bond energy of the monopropellant is released usually through use of a catalyst. This can be contrasted with bipropellants that release energy through the chemical reaction between an oxidizer and a fuel. While stable under defined storage conditions, monopropellants decompose very rapidly under certain other conditions to produce a large volume of its own energetic (hot) gases for the performance of mechanical work. Although solid deflagrants such as nitrocellulose, the most commonly used propellant in firearms, could be thought of as monopropellants, the term is usually reserved for liquids in engineering literature.
A propellant is a mass that is expelled or expanded in such a way as to create a thrust or another motive force in accordance with Newton's third law of motion, and "propel" a vehicle, projectile, or fluid payload. In vehicles, the engine that expels the propellant is called a reaction engine. Although technically a propellant is the reaction mass used to create thrust, the term "propellant" is often used to describe a substance which contains both the reaction mass and the fuel that holds the energy used to accelerate the reaction mass. For example, the term "propellant" is often used in chemical rocket design to describe a combined fuel/propellant, although the propellants should not be confused with the fuel that is used by an engine to produce the energy that expels the propellant. Even though the byproducts of substances used as fuel are also often used as a reaction mass to create the thrust, such as with a chemical rocket engine, propellant and fuel are two distinct concepts.
A solar thermal rocket is a theoretical spacecraft propulsion system that would make use of solar power to directly heat reaction mass, and therefore would not require an electrical generator, like most other forms of solar-powered propulsion do. The rocket would only have to carry the means of capturing solar energy, such as concentrators and mirrors. The heated propellant would be fed through a conventional rocket nozzle to produce thrust. Its engine thrust would be directly related to the surface area of the solar collector and to the local intensity of the solar radiation.
Aerozine 50 is a 50:50 mix by weight of hydrazine and unsymmetrical dimethylhydrazine (UDMH), developed in the late 1950s by Aerojet General Corporation as a storable, high-energy, hypergolic fuel for the Titan II ICBM rocket engines. Aerozine continues in wide use as a rocket fuel, typically with dinitrogen tetroxide as the oxidizer, with which it is hypergolic. Aerozine 50 is more stable than hydrazine alone, and has a higher density and boiling point than UDMH alone.
High-test peroxide (HTP) is a highly concentrated solution of hydrogen peroxide, with the remainder consisting predominantly of water. In contact with a catalyst, it decomposes into a high-temperature mixture of steam and oxygen, with no remaining liquid water. It was used as a propellant of HTP rockets and torpedoes, and has been used for high-performance vernier engines.
A reaction control system (RCS) is a spacecraft system that uses thrusters to provide attitude control and translation. Alternatively, reaction wheels can be used for attitude control. Use of diverted engine thrust to provide stable attitude control of a short-or-vertical takeoff and landing aircraft below conventional winged flight speeds, such as with the Harrier "jump jet", may also be referred to as a reaction control system.
The highest specific impulse chemical rockets use liquid propellants. They can consist of a single chemical or a mix of two chemicals, called bipropellants. Bipropellants can further be divided into two categories; hypergolic propellants, which ignite when the fuel and oxidizer make contact, and non-hypergolic propellants which require an ignition source.
Hydroxylammonium nitrate or hydroxylamine nitrate (HAN) is an inorganic compound with the chemical formula [NH3OH]+[NO3]−. It is a salt derived from hydroxylamine and nitric acid. In its pure form, it is a colourless hygroscopic solid. It has potential to be used as a rocket propellant either as a solution in monopropellants or bipropellants. Hydroxylammonium nitrate (HAN)-based propellants are a viable and effective solution for future green propellant-based missions, as it offers 50% higher performance for a given propellant tank compared to commercially used hydrazine.
Spacecraft electric propulsion is a type of spacecraft propulsion technique that uses electrostatic or electromagnetic fields to accelerate mass to high speed and thus generating thrust to modify the velocity of a spacecraft in orbit. The propulsion system is controlled by power electronics.
Ammonium dinitramide (ADN) is an inorganic compound with the chemical formula [NH4][N(NO2)2]. It is the ammonium salt of dinitraminic acid HN(NO2)2. It consists of ammonium cations [NH4]+ and dinitramide anions −N(NO2)2. ADN decomposes under heat to leave only nitrogen, oxygen, and water.
ECAPS AB is a Swedish spacecraft propulsion company, established in 2000 as a joint venture between the Swedish Space Corporation (SSC) and Volvo Aero with the goal of developing and commercializing in-space thruster technology using a low toxicity Ammonium dinitramide (ADN) based liquid monopropellant called LMP-103S.
Nitrous oxide fuel blend propellants are a class of liquid rocket propellants that were intended in the early 2010s to be able to replace hydrazine as the standard storable rocket propellent in some applications.
Rocket propellant is used as reaction mass ejected from a rocket engine to produce thrust. The energy required can either come from the propellants themselves, as with a chemical rocket, or from an external source, as with ion engines.
The Green Propellant Infusion Mission (GPIM) was a NASA technology demonstrator project that tested a less toxic and higher performance/efficiency chemical propellant for next-generation launch vehicles and CubeSat spacecraft. When compared to the present high-thrust and high-performance industry standard for orbital maneuvering systems, which for decades, have exclusively been reliant upon toxic hydrazine based propellant formulations, the "greener" hydroxylammonium nitrate (HAN) monopropellant offers many advantages for future satellites, including longer mission durations, additional maneuverability, increased payload space and simplified launch processing. The GPIM was managed by NASA's Marshall Space Flight Center in Huntsville, Alabama, and was part of NASA's Technology Demonstration Mission Program within the Space Technology Mission Directorate.
Cavea-B is a mixture of 1,4-Diaza-1,2,4-trimethyl bicyclo[2.2.2]octane dinitrate, dissolved in white fuming nitric acid. It was researched during the 1960s by teams associated with NASA as an alternative to the more commonly used hydrazine monopropellant for use in spacecraft's attitude control and thruster systems. It was derived from an earlier, similar formulation which came to be called Cavea-A, which showed less promise due to its excessively high melting point.
{{cite book}}: CS1 maint: date and year (link)the waste hydrogen that has boiled off happens to be the best known propellant (as a monopropellant in a basic solar-thermal propulsion system) for this task. A practical depot must evolve hydrogen at a minimum rate that matches the station keeping demands.
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